| Budget Amount *help |
¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2016: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2015: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2014: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
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| Outline of Final Research Achievements |
We have succeeded in stereocontrol in catalytic carbon-hydrogen bond activation reactions by using newly developed catalysts. We also investigated new catalysts that enable control of radical reactive species. Although asymmetric variants have not yet been succeeded, we realized acceptor-less dehydrogenation of tetrahydronaphthalenes and indolines under visible light irradiation at ambient temperature. Finally, we also developed a new chiral heterodinuclear Schiff base catalyst for asymmetric allylic C-H bond functionalization. There still remain rooms for improvement in the enantioselectivity with the heterodinuclear catalyst, but the preliminary results in this study clearly indicated the utility of the present strategy.
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