New molecular transformations via radical species based on photoredox catalysis
| Project/Area Number |
26288045
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
Akita Munetaka 東京工業大学, 科学技術創成研究院, 教授 (50167839)
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| Co-Investigator(Kenkyū-buntansha) |
小池 隆司 東京工業大学, 資源化学研究所, 助教 (30451991)
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| Project Period (FY) |
2014-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥16,640,000 (Direct Cost: ¥12,800,000、Indirect Cost: ¥3,840,000)
Fiscal Year 2017: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2016: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2014: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
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| Keywords | フォトレドックス触媒反応 / ラジカル反応光反応 / 可視光 / フッ素化反応 / フォトレドックス触媒 / 二官能基化 / 合成化学 / フルオロアルキル化 / 光化学 / 触媒反応 / ラジカル反応 / 光反応 / 有機フッ素化合物 |
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| Outline of Final Research Achievements |
“Photoredox catalysis”, where versatile organic radicals species are generated by the action of one-electron transfer processes mediated by photo-activated catalysts, has attracted much attention from the viewpoint of “Green Chemistry” but much room remains to be studied such as development of new transformations, new precursors, and various types of catalysts. Our attention has been paid to the following aspects, which have been solved by the present study: development of i) regiospecific olefin difunctionalization, ii) design and synthesis of new precursors for various organic radicals, and iii) organic catalysts.
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Report
(5 results)
Research Products
(51 results)
