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Synthesis of highly birefringence liquid crysalline polymers for optical materials

Research Project

Project/Area Number 26288058
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

Gen-ichi Konishi  東京工業大学, 物質理工学院, 准教授 (20324246)

Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥15,860,000 (Direct Cost: ¥12,200,000、Indirect Cost: ¥3,660,000)
Fiscal Year 2017: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2014: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywords高複屈折性液晶 / 液晶 / パイ電子系 / 高複屈折液晶 / 構造有機化学 / 光学 / 屈折率 / 複屈折 / 薗頭カップリング / 光学材料 / 高分子 / 縮合系高分子 / 液晶高分子 / 高複屈折
Outline of Final Research Achievements

We designed new bistolane nematic liquidc crystals with alkylsulfanyl groups for extraordinary birefringence materials. A symmetric derivative contains short terminal methylsulfanyl groups (SCH3) on both ends, while two asymmetric derivatives contain a methylsulfanyl group on one end, as well as a highly polarizable cyano (CN) or isothiocyanate (NCS) group on the other end. These materials exhibited a well-defined enantiotropic nematic phase, as well as an extremely high birefringence (Δn > 0.6). Most notably, the NCS derivative achieves an extremely high value of 0.77 at 550 nm.

Academic Significance and Societal Importance of the Research Achievements

高複屈折性液晶材料はLCDフィルム、レーザー発振用フィルム、光記憶デバイス等への応用されており、さらなる高複屈折化が求められている。高複屈折性液晶は、偏光板やLCDフィルムを単一成分で作製することができ、ディスプレイの性能向上、大画面化、製造コストの削減など、そのインパクトは計り知れない。今回、実用化にはいくつかの壁があるが、上記の条件を満たす、複屈折0.8に迫る液晶材料の開発に成功した。

Report

(5 results)
  • 2018 Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (12 results)

All 2018 2016 2015 2014

All Journal Article (12 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 12 results,  Open Access: 5 results,  Acknowledgement Compliant: 1 results)

  • [Journal Article] Development of High-Birefringence Liquid Crystals for Future Optical Materials2018

    • Author(s)
      Arakawa Yuki、Konishi Gen-ichi
    • Journal Title

      Journal of Synthetic Organic Chemistry, Japan

      Volume: 76 Issue: 10 Pages: 1076-1085

    • DOI

      10.5059/yukigoseikyokaishi.76.1076

    • NAID

      130007496415

    • ISSN
      0037-9980, 1883-6526
    • Year and Date
      2018-10-01
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] New fabrication approach to develop a high birefringence photo-crosslinked film based on a sulfur-containing liquid crystalline molecule with large temperature dependence of birefringence2018

    • Author(s)
      Arakawa Yuki、Kuwahara Hiroki、Tokita Masatoshi、Konishi Gen-ichi、Tsuji Hideto
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: 662 Issue: 1 Pages: 197-207

    • DOI

      10.1080/15421406.2018.1467619

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] The design of liquid crystalline bistolane-based materials with extremely high birefringence2016

    • Author(s)
      Y. Arakawa, S. Kang, H. Tsuji, J. Watanabe, G. Konishi
    • Journal Title

      RSC Adv.

      Volume: 6 Issue: 95 Pages: 92845-92851

    • DOI

      10.1039/c6ra14093a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Development of novel bistolane-based liquid crystalline molecules with an alkylsulfanyl group for highly birefringent materials2016

    • Author(s)
      Yuki Arakawa, Sungmin Kang, Hideto Tsuji, Junji Watanabe, Gen-ichi Konishi
    • Journal Title

      RSC Adv.

      Volume: 6 Issue: 20 Pages: 16568-16574

    • DOI

      10.1039/c5ra25122b

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Twisted N,N-Dialkylamines as a Design Strategy to Tune Simple Aromatic Hydrocarbons as Steric Environment-Sensitive Fluorophores2016

    • Author(s)
      Shunsuke Sasaki, Satoshi Suzuki, W. M. C. Sameera, Kazunobu Igawa, Keiji Morokuma Gen-ichi Konishi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 26 Pages: 8194-8206

    • DOI

      10.1021/jacs.6b03749

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Amphiphilic gels of solvatochromic fluorescent poly(2-oxazoline)s with a D-pi-A pyrene2016

    • Author(s)
      C.-H. Chen, Y. Niko, G. Konishi
    • Journal Title

      RSC Adv.

      Volume: 6 Issue: 49 Pages: 42962-42970

    • DOI

      10.1039/c6ra06251b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bright and photostable push-pull pyrene dye visualizes lipid order variation between plasma and intracellular membranes2016

    • Author(s)
      Y. Niko, P. Didier, I. Mely, G. Konishi, A. S. Klymchenko
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1 Pages: 18870-18870

    • DOI

      10.1038/srep18870

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Highly birefringent polymer films from the photo-crosslinking polymerisation of bistolane-based methacrylate monomers2015

    • Author(s)
      Yuki Arakawa, Hiroki Kuwahara, Koichi Sakajiri, Sungmin Kang, Masatoshi Tokita
    • Journal Title

      Liq. Cryst.

      Volume: 42 Issue: 10 Pages: 1419-1427

    • DOI

      10.1080/02678292.2015.1053542

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of novel fluorinated bis(biphenyl)diacetylene derivatives as highly birefringent nematic liquid crystalline materials2015

    • Author(s)
      Yuki Arakawa, Sungmin Kang, Junji Watanabe, Gen-ichi Konishi
    • Journal Title

      Phase Transitions

      Volume: 88 Issue: 12 Pages: 1181-1192

    • DOI

      10.1080/01411594.2015.1041952

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Assembly of thioether-containing rod-like liquid crystalline materials assisted by hydrogen-bonding terminal carboxyl groups2015

    • Author(s)
      Yuki Arakawa, Sungmin Kang, Junji Watanabe, Gen-ichi Konishi
    • Journal Title

      RSC Adv.

      Volume: 5 Issue: 11 Pages: 8056-8062

    • DOI

      10.1039/c4ra15300f

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, phase transition behaviors, and birefringence properties of fluorinated diphenyl-diacetylene derivatives2014

    • Author(s)
      Yuki Arakawa, Sungmin Kang, Junji Watanabe, Gen-ichi Konishi
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 12 Pages: 1853-1860

    • DOI

      10.1246/cl.140779

    • NAID

      130004687287

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Evaluation of optical parameters in side-chain LC polymethacrylate with a dinaphthyl-acetylene mesogenic unit2014

    • Author(s)
      Sungmin Kang, Shunpei Nakajima, Yuki Arakawa, Masatoshi Tokita, Gen-ichi Konishi and Junji Watanabe
    • Journal Title

      Polymer Chemistry

      Volume: 5(7) Issue: 1 Pages: 2253-2258

    • DOI

      10.1039/c2py90049a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed

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Published: 2014-04-04   Modified: 2020-03-30  

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