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Synthesis of Various Well-Defined Stimuli-Responsive Polymers via Living/Controlled Cationic Polymerization

Research Project

Project/Area Number 26288063
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionOsaka University

Principal Investigator

Aoshima Sadahito  大阪大学, 理学(系)研究科(研究院), 教授 (50183728)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2016: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2015: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2014: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords高分子合成 / リビングカチオン重合 / 立体特異性重合 / 刺激応答性ポリマー / ブロックコポリマー / タンデム重合 / 精密分解型ポリマー / グラフトコポリマー / 高分子設計 / 高分子分解 / リビング重合 / カチオン重合 / 刺激応答性 / 構造制御 / 交互共重合 / ポリ乳酸 / グラフトポリマー
Outline of Final Research Achievements

To prepare various stimuli-responsive block or alternating polymer materials, the authors developed new methods via living/controlled cationic polymerization such as base-assisting living cationic polymerization and the alternating cationic copolymerization of vinyl ethers with conjugated/aromatic aldehydes as follows; (1) highly stereospecific living cationic polymerization of N-vinylcarbazole as a result of the elaborate design of counteranions using an initiating system, (2) sequence-controlled polymers with precisely placed breakable bonds in the main chain, and unique tandem reactions of sequence-controlled cationic copolymerization and site-specific hetero Diels-Alder reaction, (3) synthesis of various stimuli-responsive block or star-shaped copolymers: block copolymers with UCST-type segment and LCST-type segment exhibiting shape-switching self-assembly in water, quantitative and ultrafast synthesis of well-defined star-shaped polystyrenes.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (77 results)

All 2017 2016 2015 2014 Other

All Journal Article (33 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 33 results,  Acknowledgement Compliant: 20 results,  Open Access: 2 results) Presentation (40 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results) Book (2 results) Remarks (2 results)

  • [Journal Article] Concurrent Cationic Vinyl-Addition and Coordination Ring-Opening Copolymerization via Orthogonal Propagation and Transient Merging at the Propagating Chain End2017

    • Author(s)
      Higuchi, M.; Kanazawa, A.; Aoshima, S.
    • Journal Title

      ACS Macro Lett.

      Volume: 6 Issue: 4 Pages: 365-369

    • DOI

      10.1021/acsmacrolett.7b00095

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stereospecific Living Cationic Polymerization of N-Vinylcarbazole through the Design of ZnCl2 Derived Counteranions2017

    • Author(s)
      Watanabe, H.; Kanazawa, A.; Aoshima, S.
    • Journal Title

      ACS Macro Lett.

      Volume: 6 Issue: 4 Pages: 463-467

    • DOI

      10.1021/acsmacrolett.7b00175

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] カチオン重合2017

    • Author(s)
      青島 貞人, 金澤 有紘, 金岡 鐘局
    • Journal Title

      ネットワークポリマー

      Volume: 38 Pages: 21-27

    • NAID

      10024765434

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] リビングカチオン重合のキャッピング反応によるマクロモノマーの精密合成および選択的カチオン共重合2017

    • Author(s)
      横山 憲文、金澤 有紘、青島 貞人
    • Journal Title

      高分子論文集

      Volume: 74

    • NAID

      130005858723

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cationic Polymerization of Vinyl Ethers with Alkyl or Ionic Side Groups in Ionic Liquids2016

    • Author(s)
      Yoshimitsu, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    • Journal Title

      J. Polym. Sci., Part A: Polym. Chem.

      Volume: 54 Issue: 12 Pages: 1774-1784

    • DOI

      10.1002/pola.28039

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shape-switching self-assembly in water of new diblock copolymers with UCST-type and LCST-type segments2016

    • Author(s)
      Yoshimitsu, H.; Korchagiva, E.; Kanazawa, A.; Kanaoka, S.; Winnik, F.; Aoshima, S.
    • Journal Title

      Polym. Chem.

      Volume: 7 Issue: 11 Pages: 2062-2068

    • DOI

      10.1039/c5py01976a

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Cationic Polymerization of p-Methylstyrene Using Various Metal Chlorides: Design Rationale of Initiating Systems for Controlled Polymerization of Styrenes2016

    • Author(s)
      Saitoh, R.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    • Journal Title

      Polym. J.

      Volume: 48 Issue: 9 Pages: 933-940

    • DOI

      10.1038/pj.2016.43

    • NAID

      40020949896

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Design of Blood-Compatible Interfaces with Poly(vinyl ether)s2016

    • Author(s)
      Y. Oda, C. Zhang, D. Kawaguchi, H. Matsuno, S. Kanaoka, S. Aoshima, and K. Tanaka
    • Journal Title

      Advanced Materials Interfaces

      Volume: 3 Issue: 12 Pages: 1600034-1600034

    • DOI

      10.1002/admi.201600034

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Enantio- and diastereoselective polymerization: asymmetric allylic alkylation catalyzed by a planar-chiral Cp'Ru complex2016

    • Author(s)
      Kanbayashi, N.; Hosoda, K.; Okamura, T.; Aoshima, S.; Onitsuka, K.
    • Journal Title

      Polym. Chem.

      Volume: 7 Issue: 22 Pages: 3691-3699

    • DOI

      10.1039/c6py00484a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Biphasic Synthesis of "Block" Copolymers and Star-Shaped Polymers via Monomer-Selective Cationic Copolymerization in Organic/Fluorinated Solvents2016

    • Author(s)
      Yamada, M.; Nishikawa, T.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    • Journal Title

      J. Polym. Sci., Part A: Polym. Chem.

      Volume: 54 Issue: 17 Pages: 2656-2661

    • DOI

      10.1002/pola.28161

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Controlled Cationic Copolymerization of Vinyl Monomers and Cyclic Acetals via Concurrent Vinyl-Addition and Ring-Opening Mechanisms2016

    • Author(s)
      Shirouchi, T.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    • Journal Title

      Macromolecules

      Volume: 49 Issue: 19 Pages: 7184-7195

    • DOI

      10.1021/acs.macromol.6b01565

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Concurrent cationic vinyl-addition and ring-opening copolymerization of vinyl ethers and oxiranes2016

    • Author(s)
      Arihiro Kanazawa and Sadahito Aoshima
    • Journal Title

      Polymer Journal

      Volume: 48 Issue: 6 Pages: 679-687

    • DOI

      10.1038/pj.2016.27

    • NAID

      40020837274

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ルイス酸触媒系によるビニルエーテルの精密リビングカチオン重合2016

    • Author(s)
      青島 貞人, 金澤 有紘, 金岡 鐘局
    • Journal Title

      触媒

      Volume: 58 Pages: 20-26

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Quantitative and Ultrafast Synthesis of Well-Defined Star-Shaped Poly(p-Methoxystyrene) via One-Pot Living Cationic Polymerization2016

    • Author(s)
      Yoshizaki, T.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    • Journal Title

      Macromolecules

      Volume: 49 Issue: 1 Pages: 71-79

    • DOI

      10.1021/acs.macromol.5b02223

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of Block or Graft Copolymers Containing Poly(Styrene Derivatives) Segments by Living Cationic Polymerization Using Acetal Moieties as Latent Initiating Sites2015

    • Author(s)
      Yokoyama, N.; Yoshida, H.; Kanazawa, A.; Kanaoka, S.; Aoshima, S.
    • Journal Title

      Polym. Chem.

      Volume: 6 Issue: 35 Pages: 6316-6324

    • DOI

      10.1039/c5py00736d

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Sequence-Controlled Degradable Polymers by Controlled Cationic Copolymerization of Vinyl Ethers and Aldehydes: Precise Placement of Cleavable Units at Predetermined Positions2015

    • Author(s)
      Marie Kawamura, Arihiro Kanazawa, Shokyoku Kanaoka and Sadahito Aoshima
    • Journal Title

      Polym. Chem.

      Volume: 6 Issue: 22 Pages: 4102-4108

    • DOI

      10.1039/c5py00493d

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Controlled radical polymerization of styrene with magnetic iron oxides prepared through hydrothermal, bioinspired, and bacterial processes2015

    • Author(s)
      Kanazawa, A.; Satoh, K.; Kanaoka, S.; Kakihana, M.; Kobayashi, M.; Sato, J.; Imai, H.; Oaki, Y.; Arakaki, A.; Katagiri, K.; Kamigaito, M.; Aoshima, S.
    • Journal Title

      RSC Adv.

      Volume: 5 Issue: 63 Pages: 51122-51129

    • DOI

      10.1039/c5ra09149g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Exclusive One-Way Cycle Sequence Control in Cationic Terpolymerization of General-Purpose Monomers via Concurrent Vinyl-Addition, Ring-Opening, and Carbonyl-Addition Mechanisms2015

    • Author(s)
      Kanazawa, A.; Aoshima, S.
    • Journal Title

      ACS Macro Lett.

      Volume: 4 Issue: 7 Pages: 783-787

    • DOI

      10.1021/acsmacrolett.5b00365

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermoactivatable polymer-grafted liposomes for low-invasive image-guided chemotherapy2015

    • Author(s)
      I. Aoki, M. Yoneyama, J. Hirose, Y. Minemoto, T. Koyama, D. Kokuryo, R. Bakalova, S. Murayama, T. Saga, S. Aoshima, Y. Ishizaka, K. Kono,
    • Journal Title

      Translational Research

      Volume: 166 Issue: 6 Pages: 660-673

    • DOI

      10.1016/j.trsl.2015.07.009

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Frequency Control of Crossover Reactions in Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization of Vinyl Ethers and Oxiranes: Specific Roles of Weak Lewis Bases and Solvent Polarity2015

    • Author(s)
      Arihiro Kanazawa and Sadahito Aoshima
    • Journal Title

      Polym. Chem.

      Volume: 6 Issue: 31 Pages: 5675-5682

    • DOI

      10.1039/c5py00152h

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Switchable Dispersivity and Molecular-Trapping Performance of Mesostructured CaCO3/Thermosensitive Polymer Composite Microspheres2015

    • Author(s)
      Astuharu Inoue, Hitoshi Tamagawa, Yuya Oaki, Sadahito Aoshima, and Hiroaki Imai
    • Journal Title

      J. Materials Chemistry B

      Volume: 3 Issue: 17 Pages: 3604-3608

    • DOI

      10.1039/c5tb00342c

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Precise Synthesis of Fluorine-Containing Block Copolymers for the Creation of Micelles that Reversibly Transfer between Aqueous and Organic Phases2015

    • Author(s)
      山中悠司、金澤有紘、金岡鐘局、青島貞人
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 72 Issue: 7 Pages: 480-485

    • DOI

      10.1295/koron.2014-0087

    • NAID

      130005088931

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Precision Synthesis of Block Copolymers of 2-Methoxyethyl Vinyl Ether with Styrene Derivatives and Preparation of Highly Thermosensitive Films2015

    • Author(s)
      吉﨑 友哉; 金澤 有紘; 金岡 鐘局; 青島 貞人
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 72 Issue: 7 Pages: 486-490

    • DOI

      10.1295/koron.2015-0012

    • NAID

      130005088935

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In Situ and Readily Prepared Metal Catalysts and Initiator for Living Cationic Polymerization of Isobutyl Vinyl Ether: Dual-Purpose Salphen as a Ligand Framework for ZrCl4 and an Initiating Proton Source2015

    • Author(s)
      Sensho Kigoshi, Arihiro Kanazawa, Shokyoku Kanaoka, and Sadahito Aoshima
    • Journal Title

      Polym. Chem.

      Volume: 6 Issue: 1 Pages: 30-34

    • DOI

      10.1039/c4py01012d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] New Initiating Systems for Cationic Polymerization of Plant-Derived Monomers: GaCl3/Alkylbenzene-Induced Controlled Cationic Polymerization of β-Pinene2015

    • Author(s)
      Yukari Karasawa, Madoka Kimura, Arihiro Kanazawa, Shokyoku Kanaoka, and Sadahito Aoshima
    • Journal Title

      Polym. J.

      Volume: 47 Issue: 2 Pages: 152-157

    • DOI

      10.1038/pj.2014.108

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ビニルエーテルとスチレン類を有する新規ブロックポリマーの精密合成および高感度温度応答性フィルムの創製2015

    • Author(s)
      吉﨑友哉、金澤有紘、金岡鐘局、青島貞人
    • Journal Title

      高分子論文集

      Volume: 72

    • NAID

      130005088935

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Density Profiles of Well-defined Poly(methyl 2-propenyl ether) (PMPE) near Water Interface2015

    • Author(s)
      Yukari Oda, Daisuke Kawaguchi, Toyoaki Hirata, Norifumi L. Yamada, Shokyoku Kanaoka, Sadahito Aoshima, Keiji Tanaka
    • Journal Title

      Macromol. Symp.

      Volume: 350 Issue: 1 Pages: 99-104

    • DOI

      10.1002/masy.201400031

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dynamic-driven Surface Segregation of a Hydrophilic Component in Diblock Copolymer Films2015

    • Author(s)
      Cui Zhang, Yukari Oda, Daisuke Kawaguchi, Shokyoku Kanaoka, Sadahito Aoshima, and Keiji Tanaka
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 2 Pages: 166-168

    • DOI

      10.1246/cl.140924

    • NAID

      130004868347

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Ring Assembly of Silica Nanospheres Mediated by Amphiphilic Block Copolymers with Oxyethylene Moieties2015

    • Author(s)
      Shujun Zhou, Yukari Oda, Atsushi Shimojima, Tatsuya Okubo, Sadahito Aoshima, Ayae Sugawara-Narutaki
    • Journal Title

      Polymer Journal

      Volume: 47 Issue: 2 Pages: 128-135

    • DOI

      10.1038/pj.2014.115

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Evaluation of Thermo-triggered Drug Release in Intramuscular-transplanted Tumors using Thermosensitive Polymer-modified Liposomes and MRI2015

    • Author(s)
      Daisuke Kokuryo, Seiji Nakashima, Fuminori Ozaki, Kai-Hsiang Chuang, Sadahito Aoshima, Yukihito Ishizaka, Tsuneo Saga, Kenji Kono, and Ichio Aoki
    • Journal Title

      Nanomedicine

      Volume: 11 Issue: 1 Pages: 229-238

    • DOI

      10.1016/j.nano.2014.09.001

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rational Design of Oxirane Monomers for Efficient Crossover Reactions in Concurrent Cationic Vinyl-Addition and Ring-Opening Copolymerization with Vinyl Ethers2014

    • Author(s)
      Arihiro Kanazawa, Shokyoku Kanaoka, and Sadahito Aoshima
    • Journal Title

      Macromolecules

      Volume: 47 Issue: 19 Pages: 6635-6644

    • DOI

      10.1021/ma501707a

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Alkoxyoxirane, a Unique Cyclic Monomer: Controlled Cationic Homopolymerization Mediated by Long-Lived Species and Copolymerization with Vinyl Ether via Alkoxy Group Transfer2014

    • Author(s)
      Arihiro Kanazawa, Shungo Kanda, Shokyoku Kanaoka, and Sadahito Aoshima
    • Journal Title

      Macromolecules

      Volume: 47 Issue: 24 Pages: 8531-8540

    • DOI

      10.1021/ma502151q

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Controlled Cationic Alternating Copolymerization of Various Enol Ethers and Benzaldehyde Derivatives: Effects of Enol Ether Structures2014

    • Author(s)
      Yasushi Ishido, Arihiro Kanazawa, Shokyoku Kanaoka, and Sadahito Aoshima
    • Journal Title

      J. Polym. Sci., Part A: Polym. Chem.

      Volume: 52 Issue: 9 Pages: 1334-1343

    • DOI

      10.1002/pola.27122

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Precision Synthesis of Various Stimuli-Responsive Polymers via Living/Controlled Cationic Polymerization2017

    • Author(s)
      Aoshima, S.; Kanazawa, A.; Kanaoka, S.
    • Organizer
      10th International Gel Symposium
    • Place of Presentation
      日本大学
    • Year and Date
      2017-03-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] イオン重合の基礎と最近の展開2016

    • Author(s)
      青島貞人
    • Organizer
      第1回ポリマーカレッジ
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] パーフルオロポリエーテル鎖を有するビニルエーテルマクロモノマーの制御カチオン共重合およびブロックコポリマーの自己集合挙動2016

    • Author(s)
      立野 良樹, 澁谷 祥太, 金澤 有紘, 青島 貞人
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] リビングカチオン重合による種々の両親媒性ビニルエーテルコポリマーの精密合成:無機ナノ粒子の精密配列制御のための新規テンプレートポリマー合成2016

    • Author(s)
      荒岡 伸太郎, 渥美 知里, 鳴瀧 彩絵, 大槻 主税, 金澤 有紘, 青島 貞人
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ジフェニルヨードニウム塩を光開始剤として用いたメタルフリー制御カチオン重合系の設計2016

    • Author(s)
      西川 毅, 金澤 有紘, 青島 貞人
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] N-ビニルカルバゾールの新規リビングカチオン重合系の設計およびルイス酸触媒を用いた立体特異性重合2016

    • Author(s)
      渡辺 大展, 金澤 有紘, 青島 貞人
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ビニル付加カチオン・配位開環同時共重合:アセタール生長末端でのアルコキシ基交換反応を利用したビニルエーテル―ε-カプロラクトンのグラフト共重合体合成2016

    • Author(s)
      樋口 元樹, 金澤 有紘, 青島 貞人
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] 一方向の交差生長反応からなるビニルエーテル,オキセタン,ケトンのビニル付加・開環・カルボニル付加同時カチオン三元共重合:長寿命生長種生成の可能性2016

    • Author(s)
      金澤 有紘, 青島 貞人
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリ乳酸鎖を有するビニルエーテルマクロモノマーの合成および種々の機能性ビニルエーテルとの制御カチオン共重合2016

    • Author(s)
      古賀 史奈, 金澤 有紘, 金岡 鐘局, 青島 貞人
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学 横浜キャンパス
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Precision Synthesis of Alternating, Block, Star, or Random Copolymers via Living/Controlled Cationic Polymerization2016

    • Author(s)
      Aoshima, S.; Kanazawa, A.; Kanaoka, S.
    • Organizer
      252th ACS National Meeting
    • Place of Presentation
      Philadelphia, USA
    • Year and Date
      2016-08-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 潜在型二段式開始点を用いた特殊構造高分子の精密合成:アセタール活性化反応によるリビングカチオン重合を利用した設計2016

    • Author(s)
      横山 憲文・金澤 有紘・金岡 鐘局・青島 貞人
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリ乳酸マクロモノマーと種々のビニルエーテルの制御カチオン共重合によるグラフトコポリマーの精密合成2016

    • Author(s)
      古賀 史奈・金澤 有紘・金岡 鐘局・青島 貞人
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 二官能性芳香族アルデヒドとビニルエーテルあるいはスチレン類との環状三量化反応を用いた新規酸分解型鎖状ポリマーの合成2016

    • Author(s)
      内藤 理・金澤 有紘・金岡 鐘局・青島 貞人
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] フッ素系溶媒/イオン液体/有機溶媒三相系を用いたモノマー選択的カチオン共重合によるブロックおよび星形ポリマーのワンショット合成2016

    • Author(s)
      西川 毅・金澤 有紘・金岡 鐘局・青島 貞人
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 種々のフェノキシイミン配位子と金属塩化物を用いた開始剤系による制御カチオン重合:錯体触媒の構造と重合活性の相関2016

    • Author(s)
      木越 宣正・金澤 有紘・金岡 鐘局・青島 貞人
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] Precision synthesis of stimuli-responsive polymers via living/controlled cationic polymerization2015

    • Author(s)
      Sadahito Aoshima, Arihiro Kanazawa, Shokyoku Kanaoka
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Hawaii Convention Center
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthesis of Stimuli-Responsive Polymers via Controlled Cationic Polymerization2015

    • Author(s)
      Sadahito Aoshima, Arihiro Kanazawa, Shokyoku Kanaoka
    • Organizer
      APME2015 (IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering)
    • Place of Presentation
      Pacifico Yokohama, Yokohama
    • Year and Date
      2015-10-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポリ乳酸および刺激応答性ポリビニルエーテルセグメントを有する新規機能性ブロックコポリマーの精密合成と生体適合性評価2015

    • Author(s)
      関 有希子, 金澤 有紘, 金岡 鐘局, 藤原 知子, 小椋 景子, 田中 賢, 青島 貞人
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 二相系を用いたモノマー選択的リビングカチオン共重合による星型およびブロックポリマーの新規合成法の開発2015

    • Author(s)
      西川 毅, 山田 麻友香, 金澤 有紘, 金岡 鐘局, 青島 貞人
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 種々のシッフ塩基配位子と金属塩化物を用いた開始剤系による制御カチオン重合:中心金属及び配位子構造が重合挙動に及ぼす影響2015

    • Author(s)
      木越 宣正, 金澤 有紘, 金岡 鐘局, 青島 貞人
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 長鎖アルキル基を持つ第四級アンモニウム塩を用いたビニルエーテルのリビングカチオン重合:逆ミセル生成とそれに基づく特異的な重合挙動2015

    • Author(s)
      藤原 滉太, 金澤 有紘, 金岡 鐘局, 青島 貞人
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] アセタール構造を潜在型二段式重合開始点に用いたリビングカチオン重合によるブロックコポリマー合成2015

    • Author(s)
      横山 憲文, 金澤 有紘, 金岡 鐘局, 青島 貞人
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] フルフラールとVE類のカチオン共重合:特異的配列を有する交互共重合体生成の可能性2015

    • Author(s)
      松本 涼香, 金澤 有紘, 金岡 鐘局, 青島 貞人
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 温度および光に対する二重刺激応答性星型ポリマーの合成と性質2015

    • Author(s)
      ランデンベーガー キラ, 金澤 有紘, 金岡 鐘局, 山口 浩靖, 青島 貞人
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水/有機溶媒中での2種の温度応答性を利用した星型ポリマーおよび高分子ミセルの層間移動2015

    • Author(s)
      戸出 吉樹,金澤 有紘,金岡 鐘局,青島 貞人
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] 単一のルテニウム錯体触媒によるカチオン重合と他の反応を組み合わせた新規高分子合成・反応系の設計2015

    • Author(s)
      瀧井 浩一郎,金澤 有紘,金岡 鐘局,青島 貞人
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] 二相系を用いたモノマー選択的カチオン共重合による星型およびブロックポリマーのワンショット精密合成2015

    • Author(s)
      西川 毅,山田 麻友香,金澤 有紘,金岡 鐘局,青島 貞人
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] シッフ塩基配位子を用いたカチオン重合触媒系の設計:配位子の構造が重合挙動に及ぼす影響2015

    • Author(s)
      木越 宣正,金澤 有紘,金岡 鐘局,青島 貞人
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] アセタール活性化反応を利用した潜在型二段式重合開始点の開発:リビングカチオン重合による特殊構造高分子設計2015

    • Author(s)
      横山 憲文,金澤 有紘,金岡 鐘局,青島 貞人
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリ乳酸および刺激応答性ポリビニルエーテルセグメントを有するブロックコポリマーの精密合成とその特性評価2015

    • Author(s)
      関 有希子,新家 雄,金澤 有紘,金岡 鐘局,藤原 知子,青島 貞人
    • Organizer
      第64回高分子年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] リビングカチオン重合と機能性ポリマーの創製2015

    • Author(s)
      青島 貞人, 金岡 鐘局, 金澤 有紘
    • Organizer
      2014年度Webinar 8回講演会
    • Place of Presentation
      高分子学会,東京
    • Year and Date
      2015-01-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Design of Poly(vinyl ether)s for Control of their Interfacial Structures and Blood-Compatibility2014

    • Author(s)
      Yukari Oda, Cui Zhang, Hisao Matsuno, Norifumi L. Yamada, Shokyoku Kanaoka, Sadahito Aoshima, and Keiji Tanaka
    • Organizer
      The 10th SPSJ International Polymer Conference (IPC 2014)
    • Place of Presentation
      Tsukuba
    • Year and Date
      2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] Ever-Evolving Star Polymer Synthesis by Living Cationic Polymerization2014

    • Author(s)
      Shokyoku Kanaoka, Arihiro Kanazawa, and Sadahito Aoshima
    • Organizer
      The 10th SPSJ International Polymer Conference (IPC 2014)
    • Place of Presentation
      Tsukuba
    • Year and Date
      2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] ルイス酸/芳香族化合物開始剤系によるβ-ピネンとスチレン類のカチオン共重合2014

    • Author(s)
      土方舞, 金澤有紘, 金岡鐘局, 青島貞人
    • Organizer
      第45回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      春日井
    • Year and Date
      2014-11-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 一次構造の制御されたポリビニルエーテルの水界面における凝集状態と血液適合性2014

    • Author(s)
      張翠, 織田ゆか里, 松野寿生, 山田悟史, 金岡鐘局, 田中 敬二, 青島貞人
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 切断/分解ユニットが精密に組み込まれた反応性共重合体:外部刺激により完全に“変容”するポリマーの精密合成2014

    • Author(s)
      川村茉莉絵, 金澤有紘, 金岡鐘局, 青島貞人
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] モノマーまたはポリマーに導入したアセタールを選択的重合開始点としたリビングカチオン重合による分岐型ポリマーの精密合成2014

    • Author(s)
      横山憲文, 金澤有紘, 金岡鐘局, 青島貞人
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 完全分解型刺激応答性セグメントをもつ種々の形態のポリマー:機能性ビニルエーテルと共役アルデヒドの制御カチオン交互共重合に基づく精密合成および刺激応答挙動2014

    • Author(s)
      松本涼香, 金澤有紘, 金岡鐘局, 青島貞人
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 特定位置に反応性ユニットをもつシーケンス制御ポリマーの精密合成: 切断点/分解ユニット、分岐点の導入を精密に制御する“分子クラフト”を目指して2014

    • Author(s)
      川村茉莉絵, 金澤有紘, 金岡鐘局, 青島貞人
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] ポリ乳酸およびポリビニルエーテルセグメントを有する刺激応答性ブロックコポリマーの精密合成2014

    • Author(s)
      関有希子, 新家雄, 金澤有紘, 金岡鐘局, 藤原知子, 青島貞人
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋
    • Year and Date
      2014-05-28
    • Related Report
      2014 Annual Research Report
  • [Book] 精密重合が拓く高分子合成(CSJカレントレビュー20)2016

    • Author(s)
      青島 貞人, 金澤 有紘
    • Total Pages
      13
    • Publisher
      カチオン重合
    • Related Report
      2015 Annual Research Report
  • [Book] 高分子ナノテクノロジーハンドブック(分担執筆:リビングカチオン重合)2014

    • Author(s)
      青島貞人, 金岡鐘局
    • Total Pages
      1096
    • Publisher
      NTS
    • Related Report
      2014 Annual Research Report
  • [Remarks] 青島研究室HP

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/aoshima/index.html

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
  • [Remarks] 青島研究室ホームページ

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/aoshima/index.html

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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