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Single-molecule detection of photoinduced electron transfer and its application to photovoltaic devices

Research Project

Project/Area Number 26288070
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Analytical chemistry
Research InstitutionTokyo Institute of Technology (2015-2016)
Osaka Prefecture University (2014)

Principal Investigator

Nishino Tomoaki  東京工業大学, 理学院化学系, 准教授 (80372415)

Co-Investigator(Kenkyū-buntansha) 椎木 弘  大阪府立大学, 工学(系)研究科(研究院), 准教授 (70335769)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2014: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywords界面・微粒子分析 / 分析化学 / 生体機能利用 / 1分子計測(SMD) / 原子・分子物理 / 表面・界面物性 / 分子探針 / 分析科学
Outline of Final Research Achievements

Recently, vast effort has been devoted to the development of photovoltaic devices by mimicking charge-separation process in natural photosynthetic systems. Improving the energy conversion efficiency of these devices is one of the most urgent social challenges. To achieve this, it is vital to understand the mechanism behind the high energy conversion efficiency of the natural photosynthetic system at the molecular level. In this study, we developed a novel methodology to quantify photoindiced electron transfer on a single molecule basis. Specifically, this method allows us to measure photoinduced electron transfer from a single electron-donating molecule to adjacent single electron-accepting molecule. The present study opens up a way for exploring the charge-separation process in the photosynthetic system at the single molecule level.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (42 results)

All 2017 2016 2015 2014

All Journal Article (30 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 30 results,  Open Access: 4 results,  Acknowledgement Compliant: 12 results) Presentation (12 results) (of which Invited: 1 results)

  • [Journal Article] Specific single-molecule detection of glucose in a supramolecularly designed tunnel junction2017

    • Author(s)
      T. Nishino, H. Shiigi, M. Kiguchi, T. Nagaoka
    • Journal Title

      Chem. Comm.

      Volume: 印刷中 Issue: 37 Pages: 5212-5215

    • DOI

      10.1039/c6cc09932g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Gap Width-independent Spectra in ATP Surface Enhanced Raman Scattering stimulated in Au-gap Array2017

    • Author(s)
      S. Watanabe, S. Kaneko, S. Fujii, T. Nishino, S. Kasai, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Process and Atomic Structures of Single Pyrazine Molecular Junction by Tuning the Strength of the Metal-Molecule Interaction2017

    • Author(s)
      S. Kaneko, R. Takahashi, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 15 Pages: 9843-9848

    • DOI

      10.1039/c6cp08862g

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of Electronic Structure of the Single-molecule Junction Based on Current-Voltage Measurement and Thermopower Measurement-Application to C60 Single-molecule Junction2017

    • Author(s)
      Y. Komoto, Y. Isshiki, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Chem. Asian J.

      Volume: 12 Issue: 4 Pages: 440-445

    • DOI

      10.1002/asia.201601392

    • NAID

      130006710283

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] In-situ Observation of Formation Process of Free Standing Au Nano Wire with Scanning Electron Microscope2017

    • Author(s)
      A. Aiba, S. Kaneko, S. Fujii, T. Nishino, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      Nanotechnology

      Volume: 28 Issue: 10 Pages: 105707-105707

    • DOI

      10.1088/1361-6528/aa59f0

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic structure of water/Au, Ag, Cu and Pt atomic junction2017

    • Author(s)
      Y. Li, S. Kaneko, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 19 Issue: 6 Pages: 4673-4677

    • DOI

      10.1039/c6cp07549e

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of the energy barrier for failure of Au atomic contact based on temperature dependent current-voltage characteristics2016

    • Author(s)
      A. Aiba S. Kaneko, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 31 Pages: 21586-21589

    • DOI

      10.1039/c6cp03437c

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic and Electronic Structures of Single Oxygen Molecular Junction with Au, Ag and Cu Electrodes2016

    • Author(s)
      Y. Li, S. Kaneko, Y. Komoto, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Phys. Chem. C

      Volume: 120 Issue: 29 Pages: 16254-16258

    • DOI

      10.1021/acs.jpcc.6b04862

    • NAID

      130006245143

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Discrete Self-Assembly and Functionality of Guest Molecules in an Organic Framework2016

    • Author(s)
      S. Ando, T. Fukushima, T. Yamaguchi
    • Journal Title

      Chemistry of Materials

      Volume: 28 Issue: 61 Pages: 5847-5854

    • DOI

      10.1039/c6ra07173b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Determination of the number of atoms present in nano contact based on shot noise measurements with highly stable nano fabricated electrodes2016

    • Author(s)
      R. Takahashi, S. Kaneko, S. M. Gonzaez, S. Fujii, T. Nishino, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      Nanotechnology

      Volume: 27 Issue: 29 Pages: 295203-295203

    • DOI

      10.1088/0957-4484/27/29/295203

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Resolving metal-molecule interfaces at single-molecule junctions2016

    • Author(s)
      Y. Komoto, S. Fujii, H. Nakamura, T. Tada, T. Nishino, M. Kiguchi
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1 Pages: 26606-26606

    • DOI

      10.1038/srep26606

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effect of the Ag Ion Insertion on Electron Transport through Au Ion Wires2016

    • Author(s)
      S. Fujii, S. Kanae, M. Iwane, T. Nishino, T. Osuga, T. Murase, M. Fujita, M. Kiguchi
    • Journal Title

      Chem. Lett.

      Volume: 45 Issue: 7 Pages: 764-766

    • DOI

      10.1246/cl.160286

    • NAID

      130005253025

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single Tripyridyl-Triazine Molecular Junction with Multiple Binding Sites2016

    • Author(s)
      M. Iwane, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 16 Pages: 8936-8940

    • DOI

      10.1021/acs.jpcc.5b12728

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Site selection in single-molecule junction for highly reproducible molecular electronics2016

    • Author(s)
      S. Kaneko, D. Murai, S. Marques-Gonzalez, H. Nakamura, Y. Komoto, S. Fujii, T. Nishino, K. Ikeda, K. Tsukagoshi, M. Kiguchi
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 138 Issue: 4 Pages: 1294-1300

    • DOI

      10.1021/jacs.5b11559

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of the Molecule-Metal Interface on Surface Enhanced Raman Scattering of 1,4-Benzenedithiol Molecule2016

    • Author(s)
      S. Suzuki, S. Kaneko, S. Fujii, S. Marques-Gonzalez, T. Nishino, M. Kiguchi
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 2 Pages: 1038-1042

    • DOI

      10.1021/acs.jpcc.5b10385

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] One-by-one single-molecule detection of mutated nucleobases by monitoring tunneling current using a DNA tip2015

    • Author(s)
      P. T. Bui, T. Nishino, H. Shiigi, T. Nagaoka
    • Journal Title

      Chem. Commun.,

      Volume: 51 Issue: 9 Pages: 1666-1669

    • DOI

      10.1039/c4cc08227c

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single-biomolecule Sensing Based on Molecular Conductance Measurements2015

    • Author(s)
      西野 智昭,椎木 弘,長岡 勉
    • Journal Title

      BUNSEKI KAGAKU

      Volume: 64 Issue: 7 Pages: 481-491

    • DOI

      10.2116/bunsekikagaku.64.481

    • NAID

      130005091795

    • ISSN
      0525-1931
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High electronic couplings of single mesitylene molecular junctions2015

    • Author(s)
      Y. Komoto, S. Fujii, T. Nishino, M. Kiguchi
    • Journal Title

      Beilstein J. Nanotech.

      Volume: 6 Pages: 2431-2437

    • DOI

      10.3762/bjnano.6.251

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electrical conduction and structure of copper atomic junctions in the presence of water molecules2015

    • Author(s)
      Y. Li, F. Demir, S. Kaneko, S. Fujii, T. Nishino, A. Saffarzadeh, G. Kirczenow, M. Kiguchi
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 48 Pages: 32436-32442

    • DOI

      10.1039/c5cp05227k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Voltammetric Detection and Profiling of Isoprenoid Quinones Hydrophobically Transferred From Bacterial Cells2015

    • Author(s)
      D. Q. Le, A. Morishita, S. Tokonami, T. Nishino, H. Shiigi, M. Miyake, T. Nagaoka
    • Journal Title

      Anal. Chem.

      Volume: 87(16) Issue: 16 Pages: 8416-8423

    • DOI

      10.1021/acs.analchem.5b01772

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Nanoantennas as biomarkers for bacterial detection2015

    • Author(s)
      H. Shiigi, T. Kinoshita, M. Fukuda, D. Q. Le, T. Nishino, and T. Nagaoka
    • Journal Title

      Anal. Chem.

      Volume: 87 Issue: 7 Pages: 4042-4046

    • DOI

      10.1021/acs.analchem.5b00415

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of an Observation Platform for Bacterial Activity Using Polypyrrole Films Doped with Bacteria2015

    • Author(s)
      L.Q. Dung, M. Takai, S. Suekuni, S. Tokonami, T. Nishino, H. Shiigi, T. Nagaoka
    • Journal Title

      Analytical Chemistry

      Volume: 87 Issue: 7 Pages: 4047-4052

    • DOI

      10.1021/acs.analchem.5b00544

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Evaluation of Poly(3,4-ethylenedioxythiophene) Films Doped with Bacteria Based on Viability Analysis2015

    • Author(s)
      D. Q. Le, S. Tokonami, T. Nishino H. Shiigi, T. Nagaoka*
    • Journal Title

      Bioelectrochem

      Volume: 105 Pages: 50-55

    • DOI

      10.1016/j.bioelechem.2015.05.003

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fluorescence Enhancement of Nanoraspberry Hot-spot Source Composed of Gold Nanoparticles and Aniline Oligomers2015

    • Author(s)
      T. Kinoshita, N. Q. Dung, T. Nishino, H. Nakao, H. Shiigi, T. Nagaoka
    • Journal Title

      Analytical Sciences

      Volume: 31 Issue: 6 Pages: 487-493

    • DOI

      10.2116/analsci.31.487

    • NAID

      130005075718

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Efficient Collection and Sensitive Detection using Conducting Magnetic Microbeads2014

    • Author(s)
      H. Shiigi, T. Kinoshita, N. Shibutani, T. Nishino, T. Nagaoka
    • Journal Title

      Anal. Chem.

      Volume: 86 Issue: 10 Pages: 4977-4981

    • DOI

      10.1021/ac500452w

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Construction of nanoantennas on the bacterial outer membrane2014

    • Author(s)
      H. Shiigi, M. Fukuda, T. Tono, K. Takada, T. Okada, L. Q. Dung, Y. Hatsuoka, T. Kinoshita, M. Takai, S. Tokonami, H. Nakao, T. Nishino, Y. Yamamoto. T. Nagaoka
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 47 Pages: 6252-6255

    • DOI

      10.1039/c4cc01204f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tracking the Growth of Tadpole-shaped Aggregates by Scanning Electron Microscopy2014

    • Author(s)
      T. Kinoshita, H. Murakami, Y. Muranaka, Y. Yamamoto, T. Nishino, H. Shiigi, and T. Nagaoka
    • Journal Title

      Analytical Sciences

      Volume: 30 Issue: 3 Pages: 319-322

    • DOI

      10.2116/analsci.30.319

    • NAID

      130004827414

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron transfer through coordination bond interaction between single molecules: conductance switching by metal ion2014

    • Author(s)
      P. T. Bui, T. Nishino
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 16 Issue: 12 Pages: 5490-5494

    • DOI

      10.1039/c4cp00051j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible switching of charge injection barriers at metal/organic-semiconductor contacts modified with structurally disordered molecular monolayers2014

    • Author(s)
      R. Nouchi, M. Shigeno, N. Yamada, T. Nishino, K. Tanigaki, M. Yamaguchi
    • Journal Title

      Appl. Phys. Lett.

      Volume: 104 Issue: 1 Pages: 13308-13308

    • DOI

      10.1063/1.4861164

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular Tips for Scanning Tunneling Microscopy: Intermolecular Electron Tunneling for Single-molecule Recognition and Electronics2014

    • Author(s)
      T. Nishino
    • Journal Title

      Analytical Sciences

      Volume: 30 Issue: 1 Pages: 81-88

    • DOI

      10.2116/analsci.30.81

    • NAID

      130004442250

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] インターカレーションによるDNA単分子の電気伝導特性の制御2017

    • Author(s)
      原島 崇徳・西野 智昭
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電子デバイス応用を指向した高分子のナノスケール電気伝導特性の計測2017

    • Author(s)
      村上 諒・西野 智昭
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] STM分子探針を用いた生体分子の単分子電気伝導度測定2017

    • Author(s)
      小堺 隆史・西野 智昭
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電気伝導度計測に基づくグルコースの特異的単分子検出2016

    • Author(s)
      西野 智昭
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 単分子-単分子間電子移動の計測のセンサ応用2015

    • Author(s)
      西野 智昭,岩田 陸, Bui Tan Phuc
    • Organizer
      分子アークテクトニクス研究会第6回研究会
    • Place of Presentation
      京都大学桂キャンパス
    • Year and Date
      2015-10-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] トンネル電流計測に基づくグルコースの特異的単分子検出2015

    • Author(s)
      西野智昭
    • Organizer
      新領域創成研究会2015
    • Place of Presentation
      鈴鹿工業高等専門学校
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] DNAプローブを用いた電子輸送計測によるDNA単分子検出2015

    • Author(s)
      西野 智昭,Bui Phuc,木口 学
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 単分子間電子移動の計測と単分子検出への応用2014

    • Author(s)
      西野智昭
    • Organizer
      第5回真空・表面科学若手勉強会
    • Place of Presentation
      東京大学柏キャンパス
    • Year and Date
      2014-11-15
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Direct Single-molecule Detection of DNA through Electron Transfer Induced by Hybridization2014

    • Author(s)
      T. Nishino, P. T. Bui, H. Shiigi, T. Nagaoka
    • Organizer
      The 7th International Symposium on Surface Science
    • Place of Presentation
      くにびきメッセ(島根)
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] DNA探針を用いたトンネル電流計測に基づく遺伝子変異の単分子検出2014

    • Author(s)
      西野智昭,椎木弘,長岡勉
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 分子探針を用いたSTMによるポルフィリンを介した電子移動の単分子計測2014

    • Author(s)
      岩田陸,西野智昭,椎木弘,長岡勉
    • Organizer
      日本分析化学会第63年会
    • Place of Presentation
      広島大学東広島キャンパス
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] EXPLORING ELECTRON TRANSFER THROUGH NONCOVALENT INTERACTIONS BETWEEN SINGLE MOLECULES2014

    • Author(s)
      T. Nishino, H. Shiigi, T. Nagaoka
    • Organizer
      13th European Vacuum Conference
    • Place of Presentation
      Aveiro, Portugal
    • Year and Date
      2014-09-08 – 2014-09-12
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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