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Development of highly sensitive gas sensing interfaces based on semiconductor nanocrystal pn junction

Research Project

Project/Area Number 26288107
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionKumamoto University

Principal Investigator

Kida Tetsuya  熊本大学, 大学院先端科学研究部(工), 教授 (70363421)

Co-Investigator(Kenkyū-buntansha) キタイン アルマンド  熊本大学, グローバル教育カレッジ, 教授 (50504693)
石渡 洋一  佐賀大学, 工学(系)研究科(研究院), 准教授 (00373267)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Fiscal Year 2017: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2016: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2015: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsガスセンサ / ナノ結晶 / ナノロッド / 半導体 / 半導体ナノ結晶 / pn接合 / ナノ材料 / 先端機能デバイス / 量子ドット / モニタリング / ナノ粒子
Outline of Final Research Achievements

Microstructure control of n- and p-type semiconductor materials was studied to drastically improve their gas sensing properties. SnO2 nanorods that were synthesized by a hydrothermal method showed significantly high sensor responses to combustible gases including CO, ethanol, and acetone. The enhancement in the sensor response is due to improved gas diffusivity in porous films made of anisotropic SnO2 nanorods. ZnO nanorods also showed good sensitivity to combustible gases. For p-type materials, Cu2O nanocrystals were synthesized by a hot-soap method. They can sensitively detect H2S even at low temperatures when loaded with Pd. The diode composed of n-type ZnO nanorods and p-type Cu2O nanocrystals showed a good rectification behavior and responded to combustible gases.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (21 results)

All 2017 2016 2015 2014

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (18 results) (of which Int'l Joint Research: 1 results,  Invited: 4 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Ultrasensitive Detection of Volatile Organic Compounds by a Pore Tuning Approach Using Anisotropically Shaped SnO2 Nanocrystals2016

    • Author(s)
      Tetsuya Kida, Koichi Suematsu, Kazuyoshi Hara, Kiyoshi Kanie, Atsushi Muramatsu
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 8 Issue: 51 Pages: 35485-35495

    • DOI

      10.1021/acsami.6b13006

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of Processing Conditions on the Performance of Cu2ZnSnS4 Nanocrystal Solar Cells2016

    • Author(s)
      Tetsuya Kida, Keisuke Horita, Satoshi Suehiro, Masayosh Yuasa, Armando T. Quitain, Tooru Tanaka, Katsuhiko Fujita, Yoichi Ishiwata, Kengo Shimanoe
    • Journal Title

      ChemistrySelect

      Volume: 1 Issue: 1 Pages: 86-92

    • DOI

      10.1002/slct.201500004

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 半導体ナノロッド/ナノ結晶pn接合膜の作製と光電効果特性2017

    • Author(s)
      木戸悠太,木田徹也
    • Organizer
      化学関連支部合同九州大会, 福岡県小倉市
    • Related Report
      2017 Annual Research Report
  • [Presentation] ZnOナノロッドを用いた半導体ナノ結晶pn接合膜の作製2017

    • Author(s)
      木戸 悠太,木田徹也
    • Organizer
      第28回九州地区若手ケミカルエンジニアリング討論会,熊本県水俣市
    • Related Report
      2017 Annual Research Report
  • [Presentation] Cu2Oナノ結晶/ZnOナノロッド膜を用いたグルコースの光酸化2017

    • Author(s)
      上野和華子,木戸悠大,キタインアルマンド,佐々木満,木田徹也
    • Organizer
      平成29年度セラミック協会九州支部秋季合同研究発表会, 北九州市
    • Related Report
      2017 Annual Research Report
  • [Presentation] Synthesis of Cu2O/ZnO colloidal nanocrystals for H2S sensing2017

    • Author(s)
      三上一輝,上野和華子,Quitain Armando,佐々木満,木田徹也
    • Organizer
      The 18th International Symposium on Eco-materials Processing and Design
    • Place of Presentation
      Okinawa
    • Related Report
      2016 Annual Research Report
  • [Presentation] 水素検知における酸化タングステンナノ結晶への酸素欠陥導入効果2017

    • Author(s)
      松本 和也,橋新 剛,三上 一輝,木田 徹也,松田 元秀,久保田 弘
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京
    • Related Report
      2016 Annual Research Report
  • [Presentation] SnO2ナノ結晶の合成とそのガスセンシング特性2016

    • Author(s)
      宮部恵太朗、キタインアルマンド、佐々木満、木田徹也
    • Organizer
      第18回化学工学会学生発表会 福岡大会
    • Place of Presentation
      福岡市
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 半導体ナノ結晶を用いたpn接合膜の作製とその光電極への応用2016

    • Author(s)
      上野和華子、三上一輝、キタインアルマンド、佐々木満、木田徹也
    • Organizer
      第18回化学工学会学生発表会 福岡大会
    • Place of Presentation
      福岡市
    • Year and Date
      2016-03-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Cu2O/CuO colloidal nanocrystals for H2S sensing2016

    • Author(s)
      三上一輝,上野和華子,Quitain Armando,佐々木満,木田徹也
    • Organizer
      The 29th International Symposium on Chemical Engineering
    • Place of Presentation
      Miyazaki
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fabrication of gas sensing films using p-type Cu2O/CuO semiconductor nanocrystals2016

    • Author(s)
      三上一輝,上野和華子,Quitain Armando,佐々木満,木田徹也
    • Organizer
      The 11th International Student Conference on Advanced Science and Technology (ICAST)
    • Place of Presentation
      Kumamoto
    • Related Report
      2016 Annual Research Report
  • [Presentation] Strategies for Pore Size Control of Gas Sensing Films to Improve the Sensor Performance2015

    • Author(s)
      Tetsuya Kida
    • Organizer
      11th-Asian Conference on Chemical Sensor (ACCS2015)
    • Place of Presentation
      Penang, Malyasia
    • Year and Date
      2015-11-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 酸化物ナノ結晶の精密合成とpn接合型ガスセンサの検討2015

    • Author(s)
      三上一輝、佐々木満、キタイン アルマンド、木田徹也
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州市
    • Year and Date
      2015-06-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] ナノギャップAu対向電極を用いた水素の低温検知2015

    • Author(s)
      平嶋 佳祐、村川 裕一、山脇 陽樹、三上 一輝、橋新 剛、木田 徹也
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Gas Sensor Technology -Metal Oxide Nanomaterials for Gas Detection-2015

    • Author(s)
      Tetsuya Kida, Kengo Shimanoe
    • Organizer
      76th PIChE (Philippines Institute of Chemical Engineers) National Convention
    • Place of Presentation
      Puerto Princesa City, Palawan, Philippines
    • Year and Date
      2015-02-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Oxide nanocrystal-based gas sensor2014

    • Author(s)
      Tetsuya Kida, Kengo Shimanoe
    • Organizer
      ICSS (International Conference on Small Science) Workshop on Micro/Nano Fabrication
    • Place of Presentation
      Hong Kong, China
    • Year and Date
      2014-12-08
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Effect of Water Vapor on Gas Sensing Properties for MEMS Type Sensor Using Pd-loaded SnO2 Nanoparticles2014

    • Author(s)
      Nan Ma、Koichi Suematsu、Masayoshi Yuasa、Tetsuya Kida、Kengo Shimanoe
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Sensing Behavior and Mechanism of Pd-loaded WO3 Sensors to Reducing Gases2014

    • Author(s)
      Zhongqiu Hua、Masayoshi Yuasa、Tetsuya Kida、Noboru Yamazoe、 Kengo Shimanoe
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 半導体ガスセンサの医療分野への応用2014

    • Author(s)
      島ノ江憲剛、末松昴一、湯浅雅賀、木田徹也
    • Organizer
      日本セラミックス協会第7回秋季シンポジウム
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2014-09-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Reducing gas sensing mechanism of Pd-loaded WO3 gas sensors2014

    • Author(s)
      Zhongqiu Hua, Masayoshi Yuasa, Tetsuya Kida, Noboru Yamazoe, Kengo Shimanoe
    • Organizer
      日本セラミックス協会第7回秋季シンポジウム
    • Place of Presentation
      鹿児島大学
    • Year and Date
      2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 新規な酸化第2スズ材料、及びその合成方法とガスセンサ材料2014

    • Inventor(s)
      村松淳司、蟹江澄志、木田徹也、末松昴一、島ノ江憲剛
    • Industrial Property Rights Holder
      村松淳司、蟹江澄志、木田徹也、末松昴一、島ノ江憲剛
    • Industrial Property Rights Type
      特許
    • Filing Date
      2014-07-18
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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