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Development of Various Electric Energy Storage Devices based on Halogen Redox Reactions

Research Project

Project/Area Number 26288112
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Device related chemistry
Research InstitutionKansai University

Principal Investigator

ISHIKAWA Masashi  関西大学, 化学生命工学部, 教授 (30212856)

Co-Investigator(Kenkyū-buntansha) 山縣 雅紀  関西大学, 化学生命工学部, 准教授 (80527119)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Keywords電池 / キャパシタ / ハロゲン / 炭素電極 / 蓄電 / マグネシウム負極 / マグネシウム電解液 / マグネシウム空気電池
Outline of Final Research Achievements

We applied halogen (e.g., bromine)-redox systems to charge-storage electrode reactions. Activated carbon was utilized to keep reversible reactions of halogens in its micropores. An electric double layer capacitor (EDLC) was designed with a positive electrode based on such redox reactions involved mainly by bromide. Furthermore, a hybrid capacitor with a lithium metal anode and a lithium-ion battery with a graphite anode were proposed by combining bromine redox-based positive. Optimum electrolytes were investigated for the various cell systems. We have also developed reversible battery systems with a magnesium metal anode with bromide-based electrolytes. We attempt to apply such novel magnesium-bromine systems to usual, closed rechargeable magnesium batteries as well as magnesium air batteries. Our new projects will focus on these novel systems.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (38 results)

All 2018 2017 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Open Access: 4 results,  Acknowledgement Compliant: 2 results) Presentation (30 results) (of which Int'l Joint Research: 7 results,  Invited: 9 results) Book (2 results) Remarks (1 results)

  • [Int'l Joint Research] Lomonosov Moscow State University(ロシア連邦)

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Preparation of Micropore-rich High Surface Area Activated Carbon from N-doped Carbon Precursor and its Application to Positive Electrode in Lithium-sulfur Battery2017

    • Author(s)
      USUKI Shinya、UCHIDA Satoshi、MATSUI Yukiko、YAMAGATA Masaki、HINAGO Hidenori、ISHIKAWA Masashi
    • Journal Title

      Electrochemistry

      Volume: 85 Issue: 10 Pages: 650-655

    • DOI

      10.5796/electrochemistry.85.650

    • NAID

      130006138819

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Performance Enhancement of Rechargeable Sulfur Cathode Utilizing Microporous Activated Carbon Composite2017

    • Author(s)
      OKABE Sota、UCHIDA Satoshi、MATSUI Yukiko、YAMAGATA Masaki、ISHIKAWA Masashi
    • Journal Title

      Electrochemistry

      Volume: 85 Issue: 10 Pages: 671-674

    • DOI

      10.5796/electrochemistry.85.671

    • NAID

      130006138818

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Hybrid Capacitors Utilizing Halogen-based Redox Reactions at Interface between Carbon Positive Electrode and Aqueous Electrolytes2016

    • Author(s)
      S. Yamazaki, T. Ito, Y. Murakumo, T. Shimooka, M. Yamagata, and M. Ishikawa
    • Journal Title

      Journal of Power Sources

      Volume: 326 Pages: 580-586

    • DOI

      10.1016/j.jpowsour.2016.04.021

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Electrochemical Energy Storage Device with a Lewis Acidic AlBr3-1-Ethyl-3-methylimidazolioum Bromide Room-Temperature Ionic Liquid2014

    • Author(s)
      Tetsuya Tsuda, Itsuki Kokubo, Masakatsu Kawabata, Masaki Yamagata, Masashi Ishikawa, Shohei Kusumoto, Akihito Imanishi, and Susumu Kuwabata
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 161(6) Issue: 6 Pages: A908-A914

    • DOI

      10.1149/2.029406jes

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] キャパシタを高性能化する新規材料の開発2018

    • Author(s)
      廣田 尚也, 宮藤 和也, 山崎 晃治, 内田 悟史, 石川 正司
    • Organizer
      第22回関西大学先端科学技術シンポジウム
    • Related Report
      2017 Annual Research Report
  • [Presentation] FSI(FSA)アニオンが寄与するLIB電解液の特性と充放電性能2018

    • Author(s)
      石川 正司
    • Organizer
      文部科学省元素戦略プロジェクト研究拠点形成型実験と理論計算科学のインタープレイによる触媒・電池の元素戦略研究拠点「触媒・電池元素戦略研究拠点12回公開シンポジウム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] ハイパワー・長寿命なキャパシタとさらなる性能向上への技術2017

    • Author(s)
      石川 正司
    • Organizer
      革新型蓄電池セミナー、-エネルギー有効利用の基盤技術 ~蓄電池技術の最新動向-
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Preparation and Characterizations of Gelatin Electrospinning for Used as Nonaqueous Electrolyte in Electric Double-Layer Capacitor2017

    • Author(s)
      Ditpon Kotatha, Masaharu Hirata, Satoshi Uchida, Mayuko Ogino, Masashi Ishikawa, Tetsuya Furuike, Hiroshi Tamura
    • Organizer
      2nd International Conference on Engineering and Technology for Sustainable Development (ICET4SD)
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Lithium-ion Capacitor Utilizing 3-D Current Collector with Bis(fluorosulfonyl)Imide-based Electrolyte2017

    • Author(s)
      Masashi Ishikawa, Naoya Hirota, Satoshi Uchida, Masaki Yamagata, Kazuki Okuno, Masatoshi Majima, Akihisa Hosoe
    • Organizer
      232nd ECS Meeting
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] スルホン系電解液を使用したマグネシウム空気二次電池における正負極での反応機構の検討2017

    • Author(s)
      小長谷 健太, 副田 和位, 石川 正司
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 臭化物イオンのレドックス反応を利用したキャパシタにおける高濃度電解液の適用2017

    • Author(s)
      上野 浩明, 内田 悟史, 山縣 雅紀, 石川 正司
    • Organizer
      第58回電池討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] スルホン系電解液を使用したマグネシウム空気二次電池の実現可能性の検討2017

    • Author(s)
      小長谷 健太, 副田 和位, Alina Belova, Tatiana Zakharchenko, Daniil Itkis, 住友 俊介, 塚田 佳子, 石川 正司
    • Organizer
      2017年度第3回関西電気化学研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高濃度電解液を用いた臭化物イオンレドックスキャパシタの電気化学特性2017

    • Author(s)
      上野 浩明, 内田 悟史, 石川 正司
    • Organizer
      2017年度第3回関西電気化学研究会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 臭化物イオンを用いた非水系レドックスキャパシタ安定化を可能にする正極材料及び作動条件の最適化2016

    • Author(s)
      槇 綾子, 内田 悟史, 山縣 雅紀, 石川 正司
    • Organizer
      2016年度第3回関西電気化学研究会
    • Place of Presentation
      大阪府立大学, 大阪府堺市中区
    • Year and Date
      2016-12-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Important Technical Elements to Enhance Electrochemical Capacitor Performance2016

    • Author(s)
      M. Ishikawa, M. Yamagata, K. Soeda, and S. Uchida
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-state Science (PRiME 2016)
    • Place of Presentation
      Hawaii Convention Center & Hilton Hawaiian Village, Honolulu, Hawaii, USA
    • Year and Date
      2016-10-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Novel Electrochemical Capacitors Based on Tailoring Materials to Enhance Power and Energy2016

    • Author(s)
      M. Ishikawa, M. Yamagata, K. Soeda, and S. Uchida
    • Organizer
      67th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      The World Forum, The Hague, The Netherlands
    • Year and Date
      2016-08-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ハロゲン化物のレドックス反応を利用した新規二次電池の開発2016

    • Author(s)
      三宅 智也, 内田 悟史, 山縣 雅紀, 石川 正司
    • Organizer
      第5回JACI/GSCシンポジウム
    • Place of Presentation
      ANAクラウンプラザホテル神戸, 兵庫県神戸市中央区
    • Year and Date
      2016-06-03
    • Related Report
      2016 Annual Research Report
  • [Presentation] New Material Design for Enhancing Performance beyond Conventional EDLC Technology2016

    • Author(s)
      M. Ishikawa, M. Yamagata, K. Soeda, and S. Uchida
    • Organizer
      2016 International Conference on Advanced Capacitors (ICAC2016)
    • Place of Presentation
      Otsu Prince Hotel, Otsu, Shiga, Japan
    • Year and Date
      2016-05-27
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Influence of Activated Carbon Properties on Positive Electrode Performance for Non-aqueous Redox Capacitor utilizing Bromide Reactions2016

    • Author(s)
      A. Maki, S. Uchida, M. Yamagata, and M. Ishikawa
    • Organizer
      2016 International Conference on Advanced Capacitors (ICAC2016)
    • Place of Presentation
      Otsu Prince Hotel, Otsu, Shiga, Japan
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ヨウ化物レドックス正極と炭素負極を用いたナトリウムイオン電池の開発2016

    • Author(s)
      濵上 弘行 他
    • Organizer
      電気化学会第83回大会, 3T27
    • Place of Presentation
      大阪大学吹田キャンパス, 大阪府吹田市
    • Year and Date
      2016-03-31
    • Related Report
      2015 Annual Research Report
  • [Presentation] 非水系臭化物イオンレドックスキャパシタの高容量化を可能にする正極構成材料およびその作動条件の検討2016

    • Author(s)
      槇 綾子 他
    • Organizer
      電気化学会第83回大会, 2I06
    • Place of Presentation
      大阪大学吹田キャンパス, 大阪府吹田市
    • Year and Date
      2016-03-30
    • Related Report
      2015 Annual Research Report
  • [Presentation] 蓄電デバイス用材料技術とキャパシタへの展開2016

    • Author(s)
      石川 正司
    • Organizer
      第7回[国際]二次電池展~バッテリー ジャパン~, 専門技術セミナー, BJ-8
    • Place of Presentation
      東京ビッグサイト,東京都江東区
    • Year and Date
      2016-03-03
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ハロゲン化物のレドックス反応を用いた二次電池における電解液組成の検討2015

    • Author(s)
      三宅 智也 他
    • Organizer
      2015年度第3回関西電気化学研究会, P058
    • Place of Presentation
      同志社大学今出川キャンパス至誠館, 京都市上京区
    • Year and Date
      2015-12-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] ヨウ化物レドックス正極を用いた新規ナトリウムイオン電池の開発2015

    • Author(s)
      濵上 弘行 他
    • Organizer
      日本化学会秋季事業第5回CSJ化学フェスタ2015, P5-013
    • Place of Presentation
      タワーホール船堀, 東京都江戸川区
    • Year and Date
      2015-10-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] 臭素のレドックス反応を利用した二次電池における電解液系の検討2015

    • Author(s)
      三宅 智也 他
    • Organizer
      2015年電気化学秋季大会, 1C08
    • Place of Presentation
      埼玉工業大学, 埼玉県深谷市
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] マグネシウム負極を可逆化する非エーテル系電解液の構築2015

    • Author(s)
      副田 和位 他
    • Organizer
      JST戦略的創造研究推進事業先端的低炭素化技術開発次世代蓄電池PJ(ALCA-SPRING)マグネシウム電池用電解液ワークショップ
    • Place of Presentation
      日本科学未来館, 東京都江東区
    • Year and Date
      2015-08-04
    • Related Report
      2015 Annual Research Report
  • [Presentation] Reversible Deposition and Dissolution of Mg Negative in Non-Ethereal Electrolyte2015

    • Author(s)
      K. Soeda et al.
    • Organizer
      The 227th ECS Meeting, A02-0321
    • Place of Presentation
      The Hilton Chicago, Chicago, Illinois, USA
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 多価金属イオン蓄電池としてのアルミニウム利用の可能性の追求2015

    • Author(s)
      桑畑 進 他
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学, 神奈川県横浜市保土ヶ谷区
    • Year and Date
      2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] 臭化物イオンのレドックス反応を適用した非水系レドックスキャパシタの可能性2014

    • Author(s)
      谷口 隆基 他
    • Organizer
      2014年度第3回関西電気化学研究会
    • Place of Presentation
      関西大学千里山キャンパス新関大会館北館, 大阪府吹田市
    • Year and Date
      2014-12-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] アルミニウム二次電池用グラファイト正極の電極挙動2014

    • Author(s)
      小久保 樹 他
    • Organizer
      第55回電池討論会
    • Place of Presentation
      国立京都国際会館, 京都市左京区
    • Year and Date
      2014-11-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Use of a Biopolymer-based Binder for High-voltage Operation of Positive Electrode in Lithium-ion Battery2014

    • Author(s)
      M. Yamagata et al.
    • Organizer
      65th Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Ecole Polytechnique Federale de Lausanne (EPF), Lausanne, Canton de Vaud, Switzerland
    • Year and Date
      2014-09-02
    • Related Report
      2014 Annual Research Report
  • [Presentation] リチウムイオン電池とキャパシタ 新しい高性能化コンセプトの探求2014

    • Author(s)
      石川 正司
    • Organizer
      平成26年度第1回カーボンナノ材料研究会
    • Place of Presentation
      大阪科学技術センター4階404号室, 大阪市西区
    • Year and Date
      2014-08-07
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 活性炭をベースとしたキャパシタ電極のための新しい性能向上技術2014

    • Author(s)
      石川 正司
    • Organizer
      活性炭技術研究会第152回講演会
    • Place of Presentation
      大阪市立工業研究所4階小講堂, 大阪市城東区
    • Year and Date
      2014-06-19
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Novel Electrode Material Design for Advanced Supercapacitors2014

    • Author(s)
      M. Ishikawa et al.
    • Organizer
      International Unions of Materials Research Societies - International Conference on Electronic Materials 2014 (IURMS-ICEM 2014)
    • Place of Presentation
      TWCT Nangang Exhibition Hall, Taipei, Taiwan
    • Year and Date
      2014-06-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Book] Encyclopedia of Applied Electrochemistry2014

    • Author(s)
      Masashi Ishikawa et al.
    • Total Pages
      2178
    • Publisher
      Springer
    • Related Report
      2014 Annual Research Report
  • [Book] エレクトロニクスシリーズ 太陽熱発電の最新動向2014

    • Author(s)
      石川 正司
    • Total Pages
      219
    • Publisher
      シーエムシー出版
    • Related Report
      2014 Annual Research Report
  • [Remarks] 関西大学学術情報システム(石川正司)

    • URL

      http://gakujo.kansai-u.ac.jp/profile/ja/da93ad8rb8c00fa7HW7f16kobc.html

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report 2015 Annual Research Report 2014 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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