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Development of SNCR by photochemical reaction at room temperature

Research Project

Project/Area Number 26289375
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Energy engineering
Research InstitutionGifu University

Principal Investigator

KAMBARA Shinji  岐阜大学, 大学院工学研究科, 教授 (80362177)

Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
Fiscal Year 2017: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2016: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2015: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2014: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Keywords真空紫外線 / 光反応 / 無触媒脱硝 / 素反応モデル / 反応メカニズム / 大気汚染防止・浄化 / 反応・分離工学 / 脱硝反応 / 低温脱硝 / 脱硝 / 新規反応場 / 反応シミュレーション / 反応速度 / 硝酸 / 気相光反応
Outline of Final Research Achievements

Simulated flue gas was fed into a photochemical reactor with an excimer lamp generated 172 nm wavelength, which located at the center of the reactor. The de-NOx behavior was examined without any catalyst and no reducing agent at the room temperature. The de-NOx ratio was changed greatly with initial NO concentrations and gas residence time (SV). Although the partial pressure of water and the oxygen concentration slightly influence the de-NOx ratio, the effects of CO2, CO, SO2, and gas temperatures on de-NOx ratio were not affected.
The mechanism of de-NOx by photochemical reaction was examined by elementary reaction simulation. It was found that NO in the flue gas was reduced to molecular nitrogen at the long gas residence time. Co-products in the de-NOx reaction were HNO3 and NO2.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (20 results)

All 2017 2016 2015 2014 Other

All Journal Article (3 results) (of which Acknowledgement Compliant: 3 results) Presentation (13 results) (of which Int'l Joint Research: 5 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] 真空紫外線を利用する常温無触媒水素製造法の開発2016

    • Author(s)
      神原 信志
    • Journal Title

      ケミカルエンジニアリング

      Volume: 61 Pages: 338-343

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] グリーン&クリーンな光化学反応-環境・エネルギー分野への光化学反応の応用-2016

    • Author(s)
      神原 信志
    • Journal Title

      月刊化学

      Volume: 72 Pages: 66-67

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] 常温無触媒の脱硝・脱水銀光反応器の開発2015

    • Author(s)
      神原信志
    • Journal Title

      環境浄化技術

      Volume: 14 Pages: 66-71

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Acknowledgement Compliant
  • [Presentation] Reaction Mechanism of NO Removal by 172 nm irradiation2017

    • Author(s)
      S. Ebata, S. Kambara
    • Organizer
      23th Int. Conf. Advanced Oxidation Technologies for Treatment of Water, Air, and Soil
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characteristics of NO Oxidation by 172 nm VUV irradiation2017

    • Author(s)
      S. Kambara, T. Wakazono
    • Organizer
      23th Int. Conf. Advanced Oxidation Technologies for Treatment of Water, Air, and Soil
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 光反応による窒素酸化物から硝酸への転換機構2017

    • Author(s)
      若園智仁,江畑咲月,早川幸男,神原信志
    • Organizer
      日本エネルギー学会第54回石炭科学会議
    • Related Report
      2017 Annual Research Report
  • [Presentation] 常温無触媒光脱硝の光反応機構の解明2016

    • Author(s)
      渡邊 桃子・若園智仁・神原 信志
    • Organizer
      第54回燃焼シンポジウム
    • Place of Presentation
      仙台
    • Year and Date
      2016-11-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] Proposal of original hydrogen carrier system using NOx-HNO3-NH3 conversion2016

    • Author(s)
      T. Wakazono, S. Kambara, T. Miura, N. Hishinuma
    • Organizer
      The 5th Asian Conference on Innovative Energy and Environmental Chemical Engineering
    • Place of Presentation
      横浜
    • Year and Date
      2016-11-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] NOx Removal by 172 nm VUV Irradiation at Room Temperature2016

    • Author(s)
      S. Kambara, T. Kawaoka, M. Watanabe
    • Organizer
      The 11th Conference on Sustainable Development of Energy, Water and Environment Systems
    • Place of Presentation
      Lisbon
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen energy storage system originated from nitrogen oxides in flue gas2015

    • Author(s)
      Momoko Watanabe, Shinji Kambara
    • Organizer
      10th Conference on Sustainable Development of Energy, Water and Environment Systems
    • Place of Presentation
      Dubrobnik (Croatia)
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アンモニアレス常温無触媒光脱硝装置の開発2015

    • Author(s)
      伊藤裕貴, 神原信志, 菱沼宣是
    • Organizer
      第24回日本エネルギー学会大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-08-02
    • Related Report
      2015 Annual Research Report
  • [Presentation] 常温無触媒脱硝法の開発2015

    • Author(s)
      早川幸男, 神原信志, 菱沼宣是
    • Organizer
      日本機械学会第25回環境工学総合シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2015-07-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Removal of NOx at Low Temperatures by Photochemical Reaction without Catalysis and Ammonia2014

    • Author(s)
      早川幸男
    • Organizer
      International Workshop on Environment & Engineering 2014
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2014-11-19 – 2014-11-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 低温光脱硝反応器の開発2014

    • Author(s)
      神原信志
    • Organizer
      日本機械学会環境工学総合シンポジウム
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2014-11-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 真空紫外線を用いた光反応脱硝法の開発2014

    • Author(s)
      早川幸男
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 常温無触媒脱硝法の開発2014

    • Author(s)
      野村俊介
    • Organizer
      日本エネルギー学会大会
    • Place of Presentation
      九州大学箱崎キャンパス
    • Year and Date
      2014-07-19 – 2014-07-20
    • Related Report
      2014 Annual Research Report
  • [Book] 環境エネルギー2016

    • Author(s)
      化学工学会編
    • Total Pages
      220
    • Publisher
      共立出版
    • Related Report
      2015 Annual Research Report
  • [Remarks] 光反応による常温常圧無触媒脱硝

    • URL

      http://kambara.main.jp/2research/reserch2.html

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report 2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 硝酸製造方法および硝酸製造装置2015

    • Inventor(s)
      神原信志, 菱沼宣是
    • Industrial Property Rights Holder
      神原信志, 菱沼宣是
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015
    • Acquisition Date
      2017
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 硝酸の製造方法および硝酸製造装置2015

    • Inventor(s)
      神原信志, 菱沼宣是
    • Industrial Property Rights Holder
      岐阜大学,ウシオ電機(株)
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-030507
    • Filing Date
      2015-02-19
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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