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Role of Sulfur as Dominant Element to Regulate Behavior of Metals in Freshwater Environment

Research Project

Project/Area Number 26340008
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental dynamic analysis
Research InstitutionThe University of Shiga Prefecture

Principal Investigator

MARUO MASAHIRO  滋賀県立大学, 環境科学部, 教授 (80275156)

Co-Investigator(Renkei-kenkyūsha) MITAMURA Osamu  滋賀大学, 教育学部, 特任教授 (50030458)
Research Collaborator SEIKE Yasushi  島根大学, 大学院・総合理工学研究科, 教授
SUGAHARA Shogo  島根大学, 大学院・総合理工学研究科, 助教
Md. Rasheduzzaman  滋賀県立大学, 大学院・環境科学研究科
OYAMA Waka  滋賀県立大学, 大学院・環境科学研究科
KAWAGUCHI Mai  滋賀県立大学, 環境科学部
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords淡水域 / 硫黄 / 錯生成 / スペシエーション / 配位子
Outline of Final Research Achievements

Existence of sulfur containing compounds as ligands for essential trace metals (Fe, Cu) was investigated. Existence of ligands which form highly stable complexes with copper was assured by pseudopolarography for all sampled waters including Lake Biwa (freshwater lake) and Lake Shinji (brackish lake). Determination of sulfur containing compounds in suspended fraction of the samples of Lake Biwa showed the concentration of cysteine in the order of some micromole per liter and that of glutathione in the order of some hundreds nanomole per liter. In the concentration of these two compounds in the samples of Lake Shinji, the order was reversed. From this result, detection of these compounds in dissolved fraction of lake water was expected.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (12 results)

All 2017 2016 2015 2014

All Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 6 results) Presentation (5 results)

  • [Journal Article] Assessment of the Status of Groundwater Arsenic at Singair Upazila, Manikganj Bangladesh; Exploring the Correlation with Other Metals and Ions2017

    • Author(s)
      Rahman MM, Sultana R, Shammi M, Bikash J, Ahmed T, Maruo M, Kurasaki M, Uddin MK
    • Journal Title

      Exposure and Health

      Volume: 8 Issue: 2 Pages: 217-225

    • DOI

      10.1007/s12403-016-0196-8

    • NAID

      120006220009

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Trace elements influenced by environmental changes in Lake Biwa: (I) Seasonal variations under suboxic hypolimnion conditions during 2007 and 20092016

    • Author(s)
      Nakashima Y, Shimizu A, Maruo M, Sohrin Y
    • Journal Title

      Limnology

      Volume: 17 Issue: 2 Pages: 151-162

    • DOI

      10.1007/s10201-015-0474-3

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Trace elements influenced by environmental changes in Lake Biwa: (II) Regime shifts in the hypolimnion over the last half-century2016

    • Author(s)
      Sohrin Y, Nakashima Y, Maruo M
    • Journal Title

      Limnology

      Volume: 17 Issue: 2 Pages: 163-173

    • DOI

      10.1007/s10201-015-0477-0

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Determination of aquatic humic substances in Japanese lakes and wetlands by the carbon concentration-based resin isolation technique2016

    • Author(s)
      Tsuda K, Kida M, Aso S, Kato T, Fujitake N, Maruo M, Hayakawa K, Hirota M
    • Journal Title

      Limnology

      Volume: 17 Issue: 1 Pages: 1-6

    • DOI

      10.1007/s10201-015-0455-6

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Comparison of soluble reactive phosphorus and orthophosphate concentrations in river waters2016

    • Author(s)
      Maruo M, Ishimaru M, Azumi Y, Kawasumi Y, Nagafuchi O, Obata H
    • Journal Title

      Limnology

      Volume: 17 Issue: 1 Pages: 7-12

    • DOI

      10.1007/s10201-015-0463-6

    • NAID

      40020699448

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] 淡水における金属の化学スペシエーション2015

    • Author(s)
      丸尾雅啓
    • Journal Title

      海洋化学研究

      Volume: 28 Pages: 2-9

    • Related Report
      2014 Research-status Report
  • [Journal Article] びわ湖内湖・西の湖における水環境教育2014

    • Author(s)
      三田村緒佐武、石川聡子、石田典子、後藤直成、橘淳治、丸尾雅啓
    • Journal Title

      陸水研究

      Volume: 1 Pages: 5-15

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 琵琶湖における正リン酸とSRP定量値の乖離2016

    • Author(s)
      丸尾雅啓、宮下治希、石丸真菜、山本麻由佳、小畑元
    • Organizer
      日本陸水学会第81回大会
    • Place of Presentation
      琉球大学農学部、沖縄県西原町
    • Year and Date
      2016-11-03
    • Related Report
      2016 Annual Research Report
  • [Presentation] Determination of nanomolar levels of phosphate in water of P-limited Lake in Japan (Lake Biwa) by ion chromatography2016

    • Author(s)
      Maruo M, Miyashita H, Ishimaru M, Obata H
    • Organizer
      SIL2016
    • Place of Presentation
      Lingotto, Torino, Italy
    • Year and Date
      2016-07-31
    • Related Report
      2016 Annual Research Report
  • [Presentation] 琵琶湖における溶存態鉄(II)・有機物の動態と光反応2015

    • Author(s)
      丸尾雅啓、大田啓一、早川和秀
    • Organizer
      2015年度日本地球化学会第62年会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 好気的水中における溶存Fe(Ⅱ)の安定化に寄与する配位子の定量2014

    • Author(s)
      小山和香、小畑元、丸尾雅啓
    • Organizer
      日本分析化学会第63年会
    • Place of Presentation
      広島大学
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Characterization of highly strong metal binding ligands in waters of natural lakes in Japan and Korea by electroanalysis2014

    • Author(s)
      Masahiro, Maruo, Hajime Obata, Osamu Mitamura, Tetsuji Akatsuka, Nozomi Amahashi, Hisayuki Azumi, Hyun-Seon Shin, Yasushi Seike, Shogo Sugahara, Akihiko Yagi, Maki Oyagi, Noriko Ishida, Rei Somiya, Jun Kil Choi
    • Organizer
      The 16th International Symposium on River and Lake Environments
    • Place of Presentation
      LADENA Resort, Chuncheon, KOREA
    • Year and Date
      2014-08-24 – 2014-08-27
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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