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Research on biodegradation behavior of precursors of PFOS and PFOA in the aquatic environment

Research Project

Project/Area Number 26340088
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Environmental risk control and evaluation
Research InstitutionCenter for Environmental Science in Saitama

Principal Investigator

Motegi Mamoru  埼玉県環境科学国際センター, 化学物質担当, 担当部長 (10415391)

Co-Investigator(Kenkyū-buntansha) 野尻 喜好  埼玉県環境科学国際センター, 大気環境担当, 主任専門員 (70415389)
堀井 勇一  埼玉県環境科学国際センター, 化学物質担当, 専門研究員 (30509534)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords有機フッ素化合物 / PFOS / PFOA / 前駆物質 / 生分解 / 河川水 / 底質 / PFDA / 製品
Outline of Final Research Achievements

Concentrations of both perfluorooctane sulfonic acid (PFOS) and perfluorooctanoic acid (PFOA) showed decreasing tendencies in river waters in Saitama Prefecture. Fluorotelomer alcohols (8:2FTOH and 10:2FTOH) in a commercial product mainly biotransformed to PFOA and perfluorodecanoic acid (PFDA) in an aerobic water/sediment system by a shake flask batch test. The biotransformation rate from 10:2FTOH to PFDA was slower than that from 8:2FTOH to PFOA. After 336 days of aerobic water/sediment incubation, 73% of PFOS and 3% of PFOA were produced by biotransformation of N-Ethyl perfluorooctane sulfonamidoethanol (N-EtFOSE). The results suggest that these precursors can be considerable pollution sources of PFOS and PFOA in the aquatic environment.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (13 results)

All 2016 2015 2014 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 1 results) Remarks (2 results)

  • [Journal Article] Long term aerobic biotransformation of N-ethyl perfluorooctane sulfonamidoethanol in river water/sediment system by a shake flask batch test2016

    • Author(s)
      Motegi, M., Nojiri, K., Horii, Y.
    • Journal Title

      Organohalogen Compounds

      Volume: 78 Pages: 1091-1094

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Behaviors of 8:2 fluorotelomer alcohol and the biotransformation compounds in sewage treatment processes2014

    • Author(s)
      Motegi, M., Nojiri, K., Horii, Y.
    • Journal Title

      Organohalogen Compounds

      Volume: 76 Pages: 301-304

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 埼玉県の元小山川におけるペルフルオロオクタンスルホン酸(PFOS)高濃度の原因となる排出源調査2014

    • Author(s)
      茂木守、野尻喜好、細野繁雄、杉崎三男
    • Journal Title

      全国環境研会誌

      Volume: 39 Pages: 179-184

    • NAID

      40020537295

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Long term aerobic biotransformation of N-ethyl perfluorooctane sulfonamidoethanol in river water/sediment system by a shake-flask batch test2016

    • Author(s)
      Motegi, M., Nojiri, K., Horii, Y.
    • Organizer
      36th International Symposium on Halogenated Persistent Organic Pollutants
    • Place of Presentation
      Florence, Italy
    • Year and Date
      2016-08-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 河川水/底質系におけるN-エチルペルフルオロオクタンスルホンアミドエタノール(N-EtFOSE)の好気性長期生分解2016

    • Author(s)
      茂木守、野尻喜好、堀井勇一
    • Organizer
      第25回環境化学討論会
    • Place of Presentation
      新潟県新潟市
    • Year and Date
      2016-06-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] 誘導体化を用いたフッ素テロマーアルコールの高感度分析2016

    • Author(s)
      竹峰秀祐、茂木守
    • Organizer
      第64回質量分析総合討論会
    • Place of Presentation
      大阪府吹田市
    • Year and Date
      2016-05-18
    • Related Report
      2016 Annual Research Report
  • [Presentation] 河川水/底質系におけるN-EtFOSEの長期生分解試験の検討2015

    • Author(s)
      茂木守、野尻喜好、堀井勇一
    • Organizer
      第24回環境化学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道札幌市)
    • Year and Date
      2015-06-25
    • Related Report
      2015 Research-status Report
  • [Presentation] 河川水/底質系による市販製品中に含まれるフッ素テロマーアルコールの生分解2015

    • Author(s)
      野尻喜好、茂木守、堀井勇一
    • Organizer
      第24回環境化学討論会
    • Place of Presentation
      札幌コンベンションセンター(北海道札幌市)
    • Year and Date
      2015-06-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Behaviors of 8:2 fluorotelomer alcohol and the biotransformation compounds in sewage treatment processes2014

    • Author(s)
      Motegi, M., Nojiri, K., Horii, Y.
    • Organizer
      34th International Symposium on Halogenated Persistent Organic Pollutants
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2014-09-01
    • Related Report
      2014 Research-status Report
  • [Presentation] 下水処理場におけるフッ素テロマーアルコール類の挙動2014

    • Author(s)
      野尻喜好、茂木守、堀井勇一
    • Organizer
      第23回環境科学討論会
    • Place of Presentation
      京都大学(京都府京都市)
    • Year and Date
      2014-05-15
    • Related Report
      2014 Research-status Report
  • [Presentation] 河川水/底質系におけるN-MeFOSEとN-EtFOSEの生分解挙動の比較2014

    • Author(s)
      茂木守、野尻喜好、堀井勇一
    • Organizer
      第23回環境科学討論会
    • Place of Presentation
      京都大学(京都府京都市)
    • Year and Date
      2014-05-14
    • Related Report
      2014 Research-status Report
  • [Remarks] 外部資金研究概要

    • URL

      http://www.pref.saitama.lg.jp/cess/center/kokusai/docments/h26-2-7-2gaibusikin.pdf

    • Related Report
      2016 Annual Research Report
  • [Remarks] 外部資金研究概要

    • URL

      http://www.pref.saitama.lg.jp/cess/center/kokusai/docments/h27-7-2gaibukenkyuu.pdf

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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