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Developments of new structural analysis methods on solution structure by means of high-performance neutron spectrometer

Research Project

Project/Area Number 26390110
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Quantum beam science
Research InstitutionYamagata University

Principal Investigator

Kameda Yasuo  山形大学, 理学部, 教授 (60202024)

Co-Investigator(Kenkyū-buntansha) 天羽 優子  山形大学, 理学部, 准教授 (20363038)
臼杵 毅  山形大学, 理学部, 教授 (70250909)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords中性子回折 / 同位体置換法 / 溶液構造 / 溶媒和構造 / 非弾性散乱補正 / 有機溶液 / 動径分布関数 / 接触イオン対 / 非弾性散乱 / 構造解析 / 非晶質
Outline of Final Research Achievements

Neutron diffraction measurements were carried out by employing newly constructed high-intensity high-performance neutron spectrometer NOVA installed at the J-PARC. New scientific insights on the solution structure in the atomic level were obtained for I. Hydration structure of Li+ in diluted aqueous LiNO3, LiCl and LiClO4 solutions. II. Concentration dependence of Na+ hydration structure by means of neutron-X-ray simultaneous analyses of interference terms obtained from H-rich sample solutions. A new method for the inelasticity correction for the Time-of-Flight neutron diffraction was developed. III. Details of the solvation structure of Li+ were determined for concentrated LiPF6-dimethylcarbonate, LiCl and LiClO4-tetrahydrofuran, and LiTFSA-tetraglyme solutions.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (20 results)

All 2017 2016 2015 2014

All Journal Article (7 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 7 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (13 results) (of which Invited: 1 results)

  • [Journal Article] Analysis of Prepeak Structure of Concentrated Organic Lithium Electrolyte by Means of Neutron Diffraction with Isotopic Substitution and Molecular Dynamics Simulation2017

    • Author(s)
      T. Yamaguchi, K. Yoshida, T. Yamaguchi, Y. Kameda, K. Ikeda, T. Otomo
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 印刷中

    • NAID

      120006337730

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Local Structure of Li+ in Concentrated LiPF6-Dimethylcarbonate Solutions2016

    • Author(s)
      Y. Kameda, S. Saito, Y. Umebayashi, K. Fujii, Y. Amo, T. Usuki
    • Journal Title

      Journal of Molecular Liquids

      Volume: 217 Pages: 17-22

    • DOI

      10.1016/j.molliq.2015.07.004

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] So-called ‘relaxation’ Mode Located at 0.1 cm-1 in the Low-frequency Raman Spectra of Ethylene Glycol-Acetone Mixtures2016

    • Author(s)
      Y. Amo, Y. Kameda, T. Usuki
    • Journal Title

      AIP Advances

      Volume: 6 Issue: 5

    • DOI

      10.1063/1.4952588

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Microscopic Structure of Contact Ion Pair in Concentrated LiCl- and LiClO4-Tetrahydrofuran Solutions Studies by Low-frequency Isotropic Raman Scattering and Neutron Diffraction with 6Li/7Li Isotopic Substitution Methods2016

    • Author(s)
      Y. Kameda, S. Ebina, Y. Amo, T. Usuki, T. Otomo
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 120 Issue: 20 Pages: 4668-4678

    • DOI

      10.1021/acs.jpcb.6b03550

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Li+ local structure in Li-tetraglyme solvate ionic liquid revealed by neutron total scattering experiments with the 6/7Li isotopic substitution technique2016

    • Author(s)
      Soshi Saito, Hikari Watanabe, Yutaka Hayashi, Masaru Matsugami, Seiji Tsuzuki, Shiro Seki, Jose N Canongia Lopes, Rob Atkin, Kazuhide Ueno, Kaoru Dokko, Masayoshi Watanabe, Yasuo Kameda, Yasuhiro Umebayashi
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 120 Issue: 14 Pages: 2832-2837

    • DOI

      10.1021/acs.jpclett.6b01266

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 6Li/7Li and 14N/15N isotopic substitution experiments using NOVA spectrometer at J-PARC2016

    • Author(s)
      Y. Kameda, T. Miyazaki, Y. Amo, T. Usuki, T. Otomo
    • Journal Title

      JAEA-Conf 2015-002

      Volume: 2015-002 Pages: 517-523

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Neutron diffraction study on the structure of aqueous LiNO3 solutions2014

    • Author(s)
      Yasuo Kameda, Takuya Miyazaki, Toshiya Otomo, Yuko Amo, Takeshi Usuki
    • Journal Title

      Journal of Solution Chemistry

      Volume: 43 Issue: 9-10 Pages: 158801600-158801600

    • DOI

      10.1007/s10953-014-0223-y

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 中性子回折による25mol% LiTFSA水溶液中におけるLi+の溶媒和構造2017

    • Author(s)
      亀田恭男、天羽優子、臼杵毅、渡辺日香里、梅林泰宏、上野和英、関志朗、都築誠二、獨古薫、渡邉正義
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      東京都八王子市
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 6Li/7Li、H/D同位体置換法中性子回折による25mol% LiTFSA水溶液の構造2016

    • Author(s)
      亀田恭男, 天羽優子, 臼杵毅, 渡辺日香里, 梅林泰宏, 上野和英, 関志朗,
    • Organizer
      第39回溶液化学シンポジウム
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] 濃厚有機リチウム電解液のプレピーク構造:MDシミュレーションと中性子散乱による研究2016

    • Author(s)
      山口 毅、吉田亨次、山口敏男、亀田恭男、池田一貴、大友季哉
    • Organizer
      第39回溶液化学シンポジウム
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] リチウムーグライム錯体系溶媒和イオン液体の輸送特性に及ぼすグライム鎖長依存性2016

    • Author(s)
      梅林泰宏, 齊藤蒼思, 渡辺日香里, 松上 優, 山口毅, Andreas Nazet, Thomas Sonnleitner, Richard Buchner, 藤井健太, 亀田恭男, 関 志朗, 獨古 薫, 渡邉正義
    • Organizer
      第39回溶液化学シンポジウム
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] エチレングリコール・アセトン混合系の低振動ラマン散乱2016

    • Author(s)
      天羽優子、久道阿南、野川春香、亀田恭男、臼杵毅
    • Organizer
      第39回溶液化学シンポジウム
    • Place of Presentation
      茨城県つくば市
    • Year and Date
      2016-11-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] 低振動数偏光Ramanスペクトルおよび同位体置換法中性子回折によるテトラ2016

    • Author(s)
      亀田恭男、天羽優子、臼杵毅
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] 6Li/7Li同位体置換法中性子回折によるTHF中におけるLi+の溶媒和構造2015

    • Author(s)
      亀田恭男、天羽優子、臼杵毅
    • Organizer
      第38回溶液化学シンポジウム
    • Place of Presentation
      高知カルポート
    • Year and Date
      2015-10-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 同位体置換中性子回折法およびMDシミュレーションによる[Li(G4)][TFSA]2015

    • Author(s)
      齊藤蒼思、松上優、都築誠二、渡辺日香里、上野和英、関志朗、獨古薫、
    • Organizer
      第38回溶液化学シンポジウム
    • Place of Presentation
      高知カルポート
    • Year and Date
      2015-10-21
    • Related Report
      2015 Research-status Report
  • [Presentation] Solvation Structure of Lithium Ion in Various Organic Solvents2015

    • Author(s)
      Y. Kameda
    • Organizer
      平成27年度化学系学協会東北大会
    • Place of Presentation
      弘前大学
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Hydration Structure of Na+ and K+ Determined by Simultaneous Fitting Analyses of X-ray and Neutron Diffraction Data2015

    • Author(s)
      M. Sato, Y. Kameda, Y. Amo, T. Usuki
    • Organizer
      平成27年度化学系学協会東北大会
    • Place of Presentation
      弘前大学
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Presentation] 中性子・X線回折データの同時解析によるNa+の水和構造解析2015

    • Author(s)
      亀田恭男、後藤麗樺、天羽優子、臼杵毅
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 軽水素を多量に含む溶液の中性子非弾性散乱補正2014

    • Author(s)
      亀田恭男、天羽優子、臼杵毅、大友季哉
    • Organizer
      第37回溶液化学シンポジウム
    • Place of Presentation
      佐賀アバンセ
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 6Li/7Li and 14N/15N Isotopic Substitution Experiments eith NOVA Spectrometer at J-PARC2014

    • Author(s)
      Y. Kameda, T. Miyazaki, Y. Amo, T. Usuki, T. Otomo
    • Organizer
      21st International Collaboration on Advanced Neutron Sources, (ICANS XXI)
    • Place of Presentation
      茨城県文化センター
    • Year and Date
      2014-09-29 – 2014-10-03
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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