• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Electric double layer at high ionic concentrations: effects of ion-specific dielectric decrement and finite size

Research Project

Project/Area Number 26400433
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Biological physics/Chemical physics/Soft matter physics
Research InstitutionKyushu University

Principal Investigator

Nakayama Yasuya  九州大学, 工学研究院, 准教授 (10422982)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Keywords電解質溶液 / 電気二重層 / 対イオン飽和 / 微分静電容量 / 電気浸透流
Outline of Final Research Achievements

For understanding the nature of the electric double layer at high salt concentrations, we study the combined effects of ion finite size and dielectric decrement arising from the ionic solvation. Based on the model, the physical origin of non-monotonic variation of the differential capacitance of the electric double layer is discussed. The double-peak differential capacitance at low salinity as well as the single-peak differential capacitance at high salinity are reproduced by considering the ion finite size and the dielectric decrement, which depends on the ion types.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (32 results)

All 2017 2016 2015 2014

All Journal Article (9 results) (of which Peer Reviewed: 5 results,  Open Access: 3 results,  Acknowledgement Compliant: 3 results) Presentation (23 results) (of which Int'l Joint Research: 8 results,  Invited: 2 results)

  • [Journal Article] Effects of Pitched Tips of Novel Kneading Disks on Melt Mixing in Twin-Screw Extrusion2017

    • Author(s)
      Yasuya Namayama, Nariyoshi Nishihira, Toshihisa Kajiwara, Hideki Tomiyama, Takahide Takeuchi, Koichi Kimura,
    • Journal Title

      Nihon Reoroji Gakkaishi

      Volume: 44 Issue: 5 Pages: 281-288

    • DOI

      10.1678/rheology.44.281

    • NAID

      130005290725

    • ISSN
      0387-1533, 2186-4586
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Strain Mode of General Flow: Characterization and Implications for Flow Pattern Structures2016

    • Author(s)
      Yasuya Nakayama, Tatsunori Masaki, and Toshihisa Kajiwara
    • Journal Title

      AIChE J.

      Volume: . Issue: 7 Pages: 2563-2569

    • DOI

      10.1002/aic.15228

    • Related Report
      2016 Annual Research Report 2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Numerical study on mixing performance of glass fiber dispersion in a twin-screw extruder with backward-mixing elements2015

    • Author(s)
      Kunihiro Hirata, Hiroshi Ishida, Motohiro Hiragori, Yasuya Nakayama and Toshihisa Kajiwara
    • Journal Title

      AIP Conf. Proc.

      Volume: 1664 Pages: 20009-20009

    • DOI

      10.1063/1.4918389

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] [トピックス] スーパーキャパシタ:イオンをナノポアへ吸着させると…2015

    • Author(s)
      名嘉山 祥也
    • Journal Title

      化学工学

      Volume: 79 Pages: 578-579

    • Related Report
      2015 Research-status Report
  • [Journal Article] 力学的視点からのフィラー分散に関する基礎的理解2015

    • Author(s)
      正木辰典, 名嘉山祥也, 梶原稔尚
    • Journal Title

      Seikei-Kakou

      Volume: 27 Pages: 533-539

    • NAID

      130007947282

    • Related Report
      2015 Research-status Report
  • [Journal Article] [Interface] [若手注目研究] 電気二重層の微分容量:溶媒和による誘電率減少と排除体積の効果2015

    • Author(s)
      名嘉山 祥也
    • Journal Title

      Colloid & Interface Communication

      Volume: 40 Pages: 28-30

    • Related Report
      2015 Research-status Report
  • [Journal Article] Differential capacitance of the electric double layer: The interplay between ion finite size and dielectric decrement2015

    • Author(s)
      Yasuya Nakayama and David Andelman
    • Journal Title

      J. Chem. Phys.

      Volume: 142 Issue: 4 Pages: 44706-44706

    • DOI

      10.1063/1.4906319

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effectiveness of a backward mixing screw element for glass fiber dispersion in a twin-screw extruder2014

    • Author(s)
      Kunihiro Hirata, Hiroshi Ishida,Motohito Hiragohri, Yasuya Nakayama and Toshihisa Kajiwara
    • Journal Title

      Polymer Engineering & Science

      Volume: 54 Issue: 9 Pages: 2005-2012

    • DOI

      10.1002/pen.23752

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] 電気二重層キャパシタの変調と発電2014

    • Author(s)
      名嘉山 祥也
    • Journal Title

      化学工学会誌

      Volume: 78 Pages: 568-568

    • Related Report
      2014 Research-status Report
  • [Presentation] 二軸スクリュ溶融混練における傾斜チップの効果: 流動パターンのチュ ーニング2017

    • Author(s)
      名嘉山 祥也, 竹光洋樹, 梶原 稔尚, 木村公一, 竹内貴季, 富山秀樹
    • Organizer
      化学工学会 第82年会 (東京 2017)
    • Place of Presentation
      芝浦工業大学 豊洲キャンパス
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Strain Mode of General Flow: Characterization and Implications for Flow Pattern Structures2016

    • Author(s)
      Yasuya Namayama, Tatsunori Masaki, Toshihisa Kajiwara
    • Organizer
      The XVIIth International Congress on Rheology (ICR2016)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-08-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Differential capacitance of the electric double layer: The interplay between ion nite size and dielectric decrement2016

    • Author(s)
      Yasuya Namayama, David Andelman
    • Organizer
      The XVIIth International Congress on Rheology (ICR2016)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-08-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Melt-Mixing by Pitched-Tip Kneading Disks in a Twin-Screw Extruder - Experimental Verification -2016

    • Author(s)
      Toshihisa Kajiwara, Yasuya Namayama, Hiroki Takemitsu, Satoshi Esaki, Takahide Takeuchi, Koichi Kimura, Hideki Tomiyama
    • Organizer
      The XVIIth International Congress on Rheology (ICR2016)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2016-08-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Strain Mode of General Flow: Characterization and Implications for Flow Pattern Structures2016

    • Author(s)
      Yasuya Namayama
    • Organizer
      Collaborative Conference on 3D and Materials Research (CC3DMR) 2016
    • Place of Presentation
      Incheon/Seoul, South Korea
    • Year and Date
      2016-06-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 混練機形状による流動パターンと伸張流動の分布2016

    • Author(s)
      名嘉山 祥也, 正木 辰典, 梶原 稔尚
    • Organizer
      化学工学会 第81年会 (2016)
    • Place of Presentation
      関西大学 千里山キャンパス
    • Year and Date
      2016-03-13
    • Related Report
      2015 Research-status Report
  • [Presentation] Impacts of mixing elements on mixing characteristics in twin-screw extrusion2016

    • Author(s)
      Hiroki Takemitsu,Yasuya Nakayama,Toshihisa Kajiwara,Koichi Kimura,Takahide Takeuchi,Hideki Tomiyama
    • Organizer
      International Symposium on Chemical Engineering 2016
    • Place of Presentation
      SEAGAIA CONVENTION CENTER
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mixing characteristic of different kneading elements: An experimental study2016

    • Author(s)
      Satoshi Esaki, Kenta Nakao, Yasuya Nakayama, Toshihisa Kajiwara, Koichi Kimura, Takahide Takeuchi, Hideki Tomiyama
    • Organizer
      International Symposium on Chemical Engineering 2016
    • Place of Presentation
      SEAGAIA CONVENTION CENTER
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Differential capacitance of the electric double layer: The interplay between ion finite size and dielectric decrement2015

    • Author(s)
      Yasuya Nakayama, David Andelman
    • Organizer
      6th Asian Conference on Colloid and Interface Science (ACCIS 2015 Japan)
    • Place of Presentation
      Arkas Sasebo, Sasebo
    • Year and Date
      2015-11-24
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 混練過程の流動様式:局所的な定量化と大域的な混合への洞察2015

    • Author(s)
      名嘉山 祥也, 正木辰典, 梶原 稔尚
    • Organizer
      第63回レオロジー討論会
    • Place of Presentation
      神戸大学工学部
    • Year and Date
      2015-09-23
    • Related Report
      2015 Research-status Report
  • [Presentation] 電解質水溶液の誘電率:塩濃度への非線型依存性2015

    • Author(s)
      名嘉山 祥也, David Andelman
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学 千里山キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 電解質水溶液の誘電率:塩濃度への非線型依存性2015

    • Author(s)
      名嘉山 祥也, David Andelman
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] Strain mode of general flow: characterization and implication to mixing2015

    • Author(s)
      Yasuya Nakayama, Tatsunori Masaki, Toshihisa Kajiwara
    • Organizer
      31st International Conference of the POLYMER PROCESSING SOCIETY (PPS-31)
    • Place of Presentation
      Jeju Island, Republic of Korea
    • Year and Date
      2015-06-07
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 混練過程の流動様式・局所的な定量化と大域的な混合への洞察2015

    • Author(s)
      名嘉山 祥也, 正木辰典, 梶原 稔尚
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学 豊洲キャンパス
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Research-status Report
  • [Presentation] Prediction of Glass Fiber Dispersion in a Twin-Screw Extruder Using a Three-Dimensional Flow Simulation2014

    • Author(s)
      Kunihiro Hirata, Hiroshi Ishida, Motohiro Hiragori, Yasuya Namayama, Toshihisa Kajiwara
    • Organizer
      Asian Workshop on Polymer Processing (AWPP)2014
    • Place of Presentation
      台湾 Kenting
    • Year and Date
      2014-11-17 – 2014-11-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 流動様式の可視化:定量化と混練への寄与2014

    • Author(s)
      名嘉山 祥也, 正木辰典, 梶原 稔尚
    • Organizer
      プラスチック成形加工学会第22回秋季大会 成形加工シンポジア'14
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2014-11-14 – 2014-11-15
    • Related Report
      2014 Research-status Report
  • [Presentation] Differential capacitance of the electric double layer: the interplay between ion polarizability and finite size2014

    • Author(s)
      Yasuya Nakayama
    • Organizer
      The 2nd SKY Joint Symposium
    • Place of Presentation
      School of Chemical Engineering, Yeungnam University, R. of Korea
    • Year and Date
      2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 二軸スクリュ押出の混練エレメントによって異なる ABS の粘弾性2014

    • Author(s)
      Y. Nakayama, A. Naka, Y. Noguchi, T. Kajiwara, K. Kimura, T. Takeuchi, H. Tomiyama
    • Organizer
      第62回レオロジー討論会
    • Place of Presentation
      福井市地域交流プラザ(AOSSA)
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 電気二重層の微分容量:イオンの分極と排除体積の効果2014

    • Author(s)
      Yasuya Nakayama, David Andelman
    • Organizer
      日本物理学会 2014年秋季大会
    • Place of Presentation
      中部大学
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] 電気二重層の微分容量:イオンの分極と排除体積の効果2014

    • Author(s)
      Yasuya Nakayama, David Andelman
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学神楽坂校舎
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of Ion Polarizability on the Electric Double Layer Interaction at High Surface Charge Density2014

    • Author(s)
      Yasuya Nakayama, David Andelman
    • Organizer
      6th Pacific Rim Conference on Rheology
    • Place of Presentation
      The University of Melbourne, VIC, Australia
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of dielectric decrement on the electric double layer at high surface charge density2014

    • Author(s)
      Yasuya Nakayama, David Andelman
    • Organizer
      Collaborative Conference on Materials Research (CCMR) 2014
    • Place of Presentation
      Incheon/Seoul, South Korea
    • Year and Date
      2014-06-23 – 2014-06-27
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Numerical Study on Mixing Performance of Glass Fiber Dispersion in a Twin-Screw Extruder with Backward-Mixing Elements2014

    • Author(s)
      Toshihisa Kajiwara, Hirata Kunihiro, Ishida Hiroshi, Hiragohri Motohito, Yasuya Nakayama
    • Organizer
      30th International Conference of the Polymer Processing Society (PPS-30)
    • Place of Presentation
      Cleveland, Ohio, USA
    • Year and Date
      2014-06-08 – 2014-06-12
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi