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NMR and molecular simulation study of structure and phase transition of water under pressure inside nanocarbon materials

Research Project

Project/Area Number 26400437
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Biological physics/Chemical physics/Soft matter physics
Research InstitutionKanagawa University

Principal Investigator

MATSUDA KAZUYUKI  神奈川大学, 工学部, 准教授 (60347268)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsナノカーボン / 分子内包 / 液体固体相転移 / 核磁気共鳴 / 分子動力学シミュレーション
Outline of Final Research Achievements

Water confined in a nanometer cavity shows unusual behavior that cannot occur in the bulk. Here we have studied the structure and dynamics of water confined in nanocavities of nanocarbon materials by several experimental methods, including nuclear magnetic resonance measurements and molecular dynamics simulations. As for water adsorbed on zeolite-templated carbons, we have observed that the rotational correlation time of nanoconfined water molecules become longer by applying pressure. Furthermore, we have revealed wet-dry transition of water-adsorbed single-walled carbon nanotubes (SWCNTs) and liquid-solid phase transition of confined water inside SWCNTs.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (11 results)

All 2017 2016 2015 2014

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (8 results)

  • [Journal Article] Intertube effects on one-dimensional correlated state of metallic single-wall carbon nanotubes probed by 13C NMR2017

    • Author(s)
      N. Serita, Y. Nakai, K. Matsuda, K. Yanagi, Y. Miyata, T. Saito, Y. Maniwa
    • Journal Title

      Phys. Rev. B

      Volume: 95 Issue: 3 Pages: 035128-035132

    • DOI

      10.1103/physrevb.95.035128

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Diameter-dependent hydrophobicity in carbon nanotubes2016

    • Author(s)
      Haruka Kyakuno, Mamoru Fukasawa, Ryota Ichimura, Kazuyuki Matsuda, Yusuke Nakai, Yasumitsu Miyata, Takeshi Saito, Yutaka Maniwa
    • Journal Title

      The Journal of Chemical Physics

      Volume: 145 Issue: 6 Pages: 064514-064514

    • DOI

      10.1063/1.4960609

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Haldane State Formed by Oxygen Molecules Encapsulated in Single-Walled Carbon Nanotubes2014

    • Author(s)
      M. Hagiwara, M. Ikeda, T. Kida, K. Matsuda, S. Tadera, H. Kyakuno, K. Yanagi, Y. Maniwa, and K. Okunishi
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 83 Issue: 11 Pages: 113706-113706

    • DOI

      10.7566/jpsj.83.113706

    • NAID

      40020264800

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] カーボンナノチューブ内包水のwet-dry転移:古典分子動力学法を用いた研究2017

    • Author(s)
      深澤衛, 客野遥, 市村遼太, 松田和之, 中井祐介, 宮田耕充, 斉藤毅, 真庭豊
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学(豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 単層カーボンナノチューブに内包された水のダイナミクスと相転移挙動2017

    • Author(s)
      客野遥, 松田和之, 中井祐介, 市村遼太, 斎藤毅, 宮田耕充, 真庭豊
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪大学(豊中市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] ナノ細孔を用いた新規アモルファス希ガス固体の作製2016

    • Author(s)
      客野遥, 光山遼, 高部陽介, 松田和之, 中井祐介, 宮田耕充, 西原洋知, 京谷隆, 真庭豊
    • Organizer
      日本物理学会 2016年秋季大会
    • Place of Presentation
      金沢大学(金沢市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 単層カーボンナノチューブに内包された水の研究VI2016

    • Author(s)
      客野遥, 深澤衛, 松田和之, 中井祐介, 宮田耕充, 斎藤毅, 真庭豊
    • Organizer
      日本物理学会 第71回年次大会
    • Place of Presentation
      東北学院大学(宮城県)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Research-status Report
  • [Presentation] 単層カーボンナノチューブに内包された水の研究V2015

    • Author(s)
      客野遥, 深澤衛, 松田和之, 中井祐介, 宮田耕充, 斎藤毅, 真庭豊
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2015-09-18
    • Related Report
      2015 Research-status Report
  • [Presentation] 単層カーボンナノチューブに内包された水の研究IV2015

    • Author(s)
      客野遥,市村遼太,深澤衛,松田和之,中井祐介,宮田耕充,斎藤毅,真庭豊
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2015-03-22
    • Related Report
      2014 Research-status Report
  • [Presentation] 単層カーボンナノチューブに内包された水の研究III2014

    • Author(s)
      客野遥,松田和之,市村遼太,中井祐介,宮田耕充,真庭豊,斎藤毅
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学(愛知県)
    • Year and Date
      2014-09-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 水・カーボンナノチューブ複合体の物性2014

    • Author(s)
      市村遼太,塚田諒,芹田昇,客野遥,中井祐介,宮田耕充,松田和之,斎藤毅,畠賢治,真庭豊
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学(愛知県)
    • Year and Date
      2014-09-07
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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