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Crystal growth of minerals as an indicator of climatic and environmental changes at lower and higher temperatures: In situ hot/cool stage AFM study at a nano level

Research Project

Project/Area Number 26400518
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Petrology/Mineralogy/Economic geology
Research InstitutionKyushu University

Principal Investigator

KUWAHARA Yoshihiro  九州大学, 比較社会文化研究院, 准教授 (90281196)

Co-Investigator(Kenkyū-buntansha) 石田 清隆  九州大学, 比較社会文化研究院, 准教授 (60108602)
上原 誠一郎  九州大学, 理学研究院, 助教 (70158773)
中牟田 義博  九州大学, 総合研究博物館, 准教授 (80128058)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
KeywordsAFM / 結晶成長 / 溶解 / 硫酸塩鉱物 / 炭酸塩鉱物 / 気候・環境変動 / 重晶石
Outline of Final Research Achievements

We examined the growth (and/or dissolution) behaviors of sulfate and carbonate minerals using in situ new hot/cool-stage AFM, to better understand for the microscopic growth and dissolution mechanisms and kinetics of the minerals in solutions at various temperatures (especially under room temperature). The kinetic laws of the crystal growth on the barite (001) surface differed among crystallographic directions and crystal growth mechanisms. Two critical supersaturation points corresponding to the changes in main crystal growth mechanisms from the spiral growth, via 2D nucleation, to adhesive growth tended to decrease with decreasing of solution temperature. On the calcite (10-14) surface, the advance rates of the steps during the growth tended to be faster than the retreat rates of those during the dissolution, while the growth rates of growth spirals toward the direction perpendicular to the (10-14) plane were slower than the retreat rates of (10-14) plane in etch pits.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (40 results)

All 2017 2016 2015 2014 Other

All Journal Article (10 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 6 results,  Open Access: 1 results) Presentation (27 results) (of which Int'l Joint Research: 7 results) Remarks (3 results)

  • [Journal Article] Effect of NaCrSi2O6 component on Lindsley’s pyroxene thermometer: An evaluation based on strongly metamorphosed LL chondrites2017

    • Author(s)
      Nakamuta,Y., Urata,K., Shibata,Y., and Kuwahara,Y.
    • Journal Title

      Meteoritic and Planetary Science

      Volume: 52 Issue: 3 Pages: 511-521

    • DOI

      10.1111/maps.12808

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] In situ AFM study of crystal growth on a barite (001) surface in BaSO4 solutions at 30°C2016

    • Author(s)
      Kuwahara,Y., Liu,W., Makio,M., and Otsuka,K.
    • Journal Title

      Minerals

      Volume: 6 Issue: 4 Pages: 1-18

    • DOI

      10.3390/min6040117

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Millennial-scale interaction between ice sheets and ocean circulation during Marin Isotope Stage 1002016

    • Author(s)
      Ohno,M., Hayashi,T., Sato,M., Kuwahara,Y., Mizuta,A., Kita,I., Sato,T., and Kano,A.
    • Journal Title

      Frontiers in Earth Science

      Volume: 4 Pages: 1-9

    • DOI

      10.3389/feart.2016.00055

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] In situ observation, X–ray diffraction and Raman analyses of carbon minerals in ureilites: Origin and formation mechanisms of diamond in ureilites2016

    • Author(s)
      Nakamuta,Y., Kitajima,F., and Shimada,S.
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 111 Issue: 4 Pages: 252-269

    • DOI

      10.2465/jmps.150906

    • NAID

      130005407264

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Investigation of hydrothermal alteration minerals from the Nagatare pegmatite2016

    • Author(s)
      Shirose,Y. and Uehara,Y.
    • Journal Title

      Annual Reports of the Ultramicroscopy Research Center Kyushu Univ

      Volume: 40 Pages: 92-93

    • Related Report
      2016 Annual Research Report
  • [Journal Article] In situ observation, X-ray diffraction and Raman analyses of carbon minerals in ureilites: Origin and formation mechanisms of diamond in ureilites2016

    • Author(s)
      Y.Nakamuta, F.Kitajima,and K.Shimada
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 111

    • NAID

      130005407264

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mercury content in Atlantic sediments as a new indicator of the enlargement and reduction of Northern Hemisphere ice sheet2016

    • Author(s)
      I.Kita, T.Yamashita, S.Chiyonobu, H.Hasegawa, T.Sato, and Y.Kuwahara
    • Journal Title

      Journal of Quaternary Science

      Volume: in press Issue: 3 Pages: 167-177

    • DOI

      10.1002/jqs.2854

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] In situ AFM study on barite (001) surface dissolution in NaCl solutions at 30°C2014

    • Author(s)
      Y. Kuwahara and M. Makio
    • Journal Title

      Applied Geochemistry

      Volume: 51 Pages: 246-254

    • DOI

      10.1016/j.apgeochem.2014.10.008

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Secondary phosphates in montebrasite and amblygonite from Nagatare, Fukuoka Prefecture, Japan2014

    • Author(s)
      Y. Shirase anf S. Uehara
    • Journal Title

      Journal of Mineralogical and Petrological Sciences

      Volume: 109 Issue: 2 Pages: 103-108

    • DOI

      10.2465/jmps.131022d

    • NAID

      130004462474

    • ISSN
      1345-6296, 1349-3825
    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] A TES microcalorimeter EDS-SEM system for silicates and other minerals2014

    • Author(s)
      S. Uehara and Y. Shirase
    • Journal Title

      21st General Meeting of the International Mineralogical Association (IMA2014)

      Volume: Supplement Pages: 314-314

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 大分県入蔵の蛇紋石の鉱物学的研究2016

    • Author(s)
      延寿里美・上原誠一郎
    • Organizer
      日本地球惑星科学連合2016年大会
    • Place of Presentation
      千葉県幕張メッセ
    • Related Report
      2016 Annual Research Report
  • [Presentation] 九州黒瀬川帯の蛇紋岩中のchrysotile 及びpolygonal serpentine の産状と分布2016

    • Author(s)
      延寿里美・猪尾晃生・上原 誠一郎
    • Organizer
      日本粘土学会第60回粘土科学討論会
    • Place of Presentation
      九州大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 原子間力顕微鏡によるバライトの結晶成長ナノスケール解析2016

    • Author(s)
      劉ブン・桑原義博
    • Organizer
      日本粘土学会第60回粘土科学討論会
    • Place of Presentation
      九州大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 2.9~2.4Maにおける氷期・間氷期サイクルと北大西洋海洋底堆積物の鉱物組成変化との関係2016

    • Author(s)
      桑原義博・槙尾雅人・劉ブン・大塚佳亮・丁斐・水田麻美・北逸郎・林辰弥・大野 正夫
    • Organizer
      日本粘土学会第60回粘土科学討論会
    • Place of Presentation
      九州大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 福岡県長垂産リシオフォライト2016

    • Author(s)
      白勢洋平・上原 誠一郎
    • Organizer
      日本粘土学会第60回粘土科学討論会
    • Place of Presentation
      九州大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] Lindsley輝石温度計によるLLコンドライトの変成温度2016

    • Author(s)
      中牟田義博・浦田佳奈・柴田葉子
    • Organizer
      日本鉱物科学会2016年年会
    • Place of Presentation
      金沢大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 福岡県長垂産リシオフォライトの産状及び微細構造観察2016

    • Author(s)
      白勢洋平・上原 誠一郎
    • Organizer
      日本鉱物科学会2016年年会
    • Place of Presentation
      金沢大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] 岩手県崎浜ペグマタイト産電気石について2016

    • Author(s)
      白勢洋平・上原 誠一郎
    • Organizer
      日本鉱物科学会2016年年会
    • Place of Presentation
      金沢大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] Hydrotalcite group minerals in serpentinite from Furuyashiki, Fukuoka prefecture, Kyushu, Japan2016

    • Author(s)
      Uehara,S. and Hashimoto, M.
    • Organizer
      Serpentine days 2016
    • Place of Presentation
      Sete France
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Chrysotile and polygonal serpentine in serpentinites from kurosegawa belt Kyushu Japan2016

    • Author(s)
      Enju,S. and Uehara,Y.
    • Organizer
      Serpentine days 2016
    • Place of Presentation
      Sete France
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 黒色頁岩の微化石・粘土鉱物組成に基づくOAE1b時の環境変動2016

    • Author(s)
      西弘嗣・高嶋礼詩・小川草平・桑原 義博
    • Organizer
      2016年度地球環境史学会年会
    • Place of Presentation
      早稲田大学
    • Related Report
      2016 Annual Research Report
  • [Presentation] Evaluation of Lindsley pyroxene thermometer for chondrites2015

    • Author(s)
      Y.Nakamuta, Y.Shibata, and K.Urata
    • Organizer
      The Sixth Symposium on Polar Science
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2015-11-16
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] コンドライト隕石のためのLindsley輝石温度計の評価: 回帰方程式の作成と微量成分補正の検討2015

    • Author(s)
      中牟田義博、柴田葉子、浦田佳奈
    • Organizer
      日本鉱物科学会2015年年会
    • Place of Presentation
      東京都
    • Year and Date
      2015-09-25
    • Related Report
      2015 Research-status Report
  • [Presentation] barite (001) 表面で起こる結晶成長の AFM その場観察2015

    • Author(s)
      桑原義博, 劉ブン
    • Organizer
      日本粘土学会第59回粘土科学討論会
    • Place of Presentation
      山口県山口市
    • Year and Date
      2015-09-03
    • Related Report
      2015 Research-status Report
  • [Presentation] Millennial scale linkage between iceberg collapse and ocean circulation after intensification of Northern Hemisphere glaciation2015

    • Author(s)
      M.Makio, M.Sato, T.Hayashi, Y.Kuwahara, M.Ohno, S.Fujita, S.Chiyonobu, and T.Sato
    • Organizer
      International Union for Quaternary Research XIX Congress
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2015-08-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Orbital- and millennial-scale change in the components of the North Atlantic sediments resolved by isothermal remanent magnetization acquisition experiments2015

    • Author(s)
      M.Makio, M.Sato, T.Hayashi, Y.Kuwahara, and M.Ohno
    • Organizer
      International Union for Quaternary Research XIX Congress
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2015-07-31
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Alteration of Li-tourmaline from Nagatare pegmatite, Fukuoka Prefecture, Japan2015

    • Author(s)
      Y.Shirase and S.Uehara
    • Organizer
      7th International Symposium on Granitic Pegmatites
    • Place of Presentation
      Ksiaz, Poland
    • Year and Date
      2015-06-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Fine texture of montebrasite-amblygonite series and lacroixite2015

    • Author(s)
      Y.Shirase and S.Uehara
    • Organizer
      7th International Symposium on Granitic Pegmatites
    • Place of Presentation
      Ksiaz, Poland
    • Year and Date
      2015-06-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 原子間力顕微鏡によるbarite の結晶成長その場観察2015

    • Author(s)
      桑原義博、槙尾雅人
    • Organizer
      日本地球惑星科学連合2015年大会
    • Place of Presentation
      千葉県幕張
    • Year and Date
      2015-05-28
    • Related Report
      2015 Research-status Report
  • [Presentation] 大陸氷床発達期(MIS100-104) における氷床崩壊に伴う北大西洋深層流の変動2015

    • Author(s)
      槙尾雅人、佐藤雅彦、林 辰弥、大野正夫、桑原義博
    • Organizer
      日本地球惑星科学連合2015年大会
    • Place of Presentation
      千葉県幕張
    • Year and Date
      2015-05-28
    • Related Report
      2015 Research-status Report
  • [Presentation] Amorphous carbon in the weakly shocked Y-8448 ureilite2014

    • Author(s)
      Y. Nakamuta
    • Organizer
      37th symposium on Antarctic Meteorites
    • Place of Presentation
      Tokyo
    • Year and Date
      2014-12-03
    • Related Report
      2014 Research-status Report
  • [Presentation] 水熱合成Li雲母のX線Rietveld解析および中・遠赤外分光分析2014

    • Author(s)
      槙尾雅人、石田清隆
    • Organizer
      日本鉱物科学会
    • Place of Presentation
      熊本
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] TESマイクロカロリメータEDS-SEMによる珪酸塩鉱物分析2014

    • Author(s)
      上原誠一郎、白勢洋平、山口海
    • Organizer
      日本鉱物科学会
    • Place of Presentation
      熊本
    • Year and Date
      2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] AFMによる30℃のNaCl溶液中でのbarite(001)表面の溶解その場観察2014

    • Author(s)
      桑原義博
    • Organizer
      日本鉱物科学会
    • Place of Presentation
      熊本
    • Year and Date
      2014-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] 220万年前から290万年前の堆積物に基づく北大西洋の環境変動とパナマ地峡の閉鎖2014

    • Author(s)
      藤田周、宮川千鶴、佐藤雅彦、北逸郎、大野正夫、桑原義博、佐藤時幸、林辰弥、齋藤めぐみ
    • Organizer
      日本地球化学会
    • Place of Presentation
      富山
    • Year and Date
      2014-09-18
    • Related Report
      2014 Research-status Report
  • [Presentation] A TES microcalorimeter EDS-SEMsystem for silicate and other minerals2014

    • Author(s)
      上原誠一郎、白勢洋平、山口海
    • Organizer
      IMA2014
    • Place of Presentation
      Johannesburg, South Africa
    • Year and Date
      2014-09-02
    • Related Report
      2014 Research-status Report
  • [Presentation] A rock-magnetic proxy of deep water circulation in the North Atlantic during the early Pleistocene2014

    • Author(s)
      M. OHNO, M. Sato, T. Hayashi, Y. Kuwahara, C. Miyagawa, S. Fujita, I. Kita
    • Organizer
      Asia Oceania Geoscience Society
    • Place of Presentation
      Sapporo
    • Year and Date
      2014-07-31
    • Related Report
      2014 Research-status Report
  • [Remarks] 九州大学 大学院比較社会文化研究院・地球社会統合科学府 桑原研究室HP

    • URL

      http://scs.kyushu-u.ac.jp/ykuwa/ykworld/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 九州大学大学院比較社会文化研究院・地球社会統合科学府 桑原研究室HP

    • URL

      http://www.scs.kyushu-u.ac.jp/~ykuwa/ykworld/index.html

    • Related Report
      2015 Research-status Report
  • [Remarks] 九州大学 大学院比較社会文化研究院・地球社会統合科学府 桑原研究室 HP

    • URL

      http://scs.kyushu-u.ac.jp/ykuwa/ykworld/index.html

    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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