Spectroscopic study on photo-reaction of active oxygen comlex
| Project/Area Number |
26410006
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Physical chemistry
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
SHIBUYA KAZUHIKO 東京農工大学, 大学院生物システム応用科学府, 客員教授 (30126320)
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| Research Collaborator |
NAKATA Munetaka 東京農工大学, 大学院工学研究院, 教授
AKAI Nobuyuki 東京農工大学, 大学院工学研究院, 准教授
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| Project Period (FY) |
2014-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
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| Keywords | 活性酸素 / 一重項酸素 / 衝突錯体 / 二電子同時遷移 / 可視紫外分光 / 衝突錯体形成 / 錯体形成 / 可視光吸収 / りん光 / 電子遷移 / 消光 / 光反応 |
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| Outline of Final Research Achievements |
I constructed a spectroscopic chamber which could be cooled down to -195℃ and analyzed quantitatively the absorption spectra of liquid oxygen. Two oxygen molecules in the excited singlet states were generated simultaneously by single photon absorption through the collision-induced light absorption (CIA). The CIA bands measured in the 200-800 nm region were studied. The light absorption cross sections (σ values) at the peaks of the CIA bands were determined in pure oxygen and oxygen/rare gas mixture liquid systems. The σ values accord with the corresponding values determined in the gas system. The CIA cross sections in both the liquid and gas phases could be expressed by an identical analytical equation, though the physical environments are quite different and the number densities in the systems changes in three orders of magnitude. One could estimate the absorbance through the equation by introducing the number density of oxygen molecules in both the liquid and gas systems.
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Report
(5 results)
Research Products
(9 results)
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[Journal Article] Reassessing the atmospheric oxidation mechanism of toluene2017
Author(s)
Y. Ji, J. Zhao, H. Terazono, K. Misawa, N. P. Levitt, Y. Li, Y. Lin, J. Peng, Y. Wang, L. Duan, B. Pan, F. Zhang, X. Feng, T. An, W. Marrero-Ortiz, J. Secrest, A. L. Zhang, K. Shibuya, M. J. Molina and R. Zhang
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Journal Title
PNAS (Proceedings of the National Academy of Sciences of the United States of America)
Volume: 114
Issue: 31
Pages: 8169-8174
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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