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Development of solid-state NMR for measuring of all the atoms

Research Project

Project/Area Number 26410007
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionKochi University

Principal Investigator

Yamada Kazuhiko  高知大学, 教育研究部総合科学系複合領域科学部門, 准教授 (80373380)

Co-Investigator(Kenkyū-buntansha) 高橋 雅人  国立研究開発法人理化学研究所, その他, 研究員 (60392015)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywords固体NMR / 磁場掃引 / NMR / 硫黄 / 架橋構造 / ゴム / 臭素 / ゴムの架橋構造
Outline of Final Research Achievements

Field-stepwise-swept solid-state nuclear magnetic resonance (NMR) method combined with high-temperature superconducting (HTS) coil, which is expected to be a powerful tool for increasing the S/N ratio in an NMR measurement, is developed. In a conventional NMR method, there is limitation of measurable NMR nuclei, such as 1H, 13C, 15N, and so on, because of the two problems: one is horizontal problem, which mainly arises from quadrupolar interactions, in some cases, making the spectral width of NMR spectra more than several megahertz. The other problem is vertical problem, which comes from the fact that lower Lamour frequency and/or a small spin density in samples make signal intensity lower. The present method can potentially resolve the above two problems simultaneously, indicating that all nuclei in the periodic table become NMR accessible nuclei.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Research-status Report
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (22 results)

All 2018 2017 2016 2014

All Journal Article (10 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 8 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (10 results) (of which Int'l Joint Research: 1 results,  Invited: 5 results) Book (1 results) Patent(Industrial Property Rights) (1 results) (of which Overseas: 1 results)

  • [Journal Article] Development of field-stepwise-swept solid-state NMR of half-integer quadrupole towards high digital-resolution NMR spectra2017

    • Author(s)
      K. Yamada
    • Journal Title

      Bull. Chem. Soc. Japan

      Volume: 90 Pages: 1224-1229

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Understanding the symmetric line shape in the 17O MAS spectra for hexagonal ice,2016

    • Author(s)
      K. Yamada*, S. Oki, K. Deguchi, T. Shimizu,
    • Journal Title

      J. Mol. Struct.,

      Volume: 13 Pages: 108-111

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] Determination of nuclear quadrupolar parameters using singularities in field-swept NMR patterns,2016

    • Author(s)
      N. Ichijo, K. Takeda, K. Yamada, K. Takegoshi,
    • Journal Title

      J. Chem. Phys

      Volume: 145 Pages: 134201-134209

    • Related Report
      2016 Research-status Report
    • Peer Reviewed
  • [Journal Article] 可変型超伝導磁石による固体NMR測定の新展開 有機硫黄化合物を測定対象とする固体NMR法,2016

    • Author(s)
      山田和彦
    • Journal Title

      J. Cryo. Super. Soc. Jpn

      Volume: 51 Pages: 64-70

    • NAID

      130005147200

    • Related Report
      2016 Research-status Report
  • [Journal Article] 四極子核固体NMR法の基礎の基礎2016

    • Author(s)
      山田和彦
    • Journal Title

      Bulletin of Nuclear Magnetic Resonance Society of Japan

      Volume: 7 Pages: 77-84

    • Related Report
      2016 Research-status Report
  • [Journal Article] 可変型超伝導磁石による団体NMR測定の新展開2016

    • Author(s)
      山田 和彦
    • Journal Title

      低温工学

      Volume: 51 Pages: 64-70

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Recent Solid-State 13C NMR Studies of Liquid Crystals2016

    • Author(s)
      K. Yamada
    • Journal Title

      Annual Reports on NMR Spectroscopy

      Volume: 88 Pages: 245-305

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Line-Shape Analyses of Solid-State 17O NMR Spectra for Hexagonal Ice,2014

    • Author(s)
      K. Yamada,* K. Deguchi, T. Shimizu, J. Watanabe
    • Journal Title

      Verlag der Zeitschrift für Naturforschung B

      Volume: 69 Pages: 786-792

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Determination of the n-director direction of low bend-angle banana-shaped molecules by solid-state 13C NMR,2014

    • Author(s)
      K. Yamada,* E. W. Lee, M. Hattori, S. Kawauchi, E.-Joon Choi, J. Watanabe, S. Kang
    • Journal Title

      J. Mater. Chem. C

      Volume: 2 Pages: 10418-10427

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Rapid Exchange between Atmospheric CO2 and Carbonate Anion Intercalated within Magnesium Rich Layered Double Hydroxide,2014

    • Author(s)
      P. Sahoo, S. Ishihara, K. Yamada, K. Deguchi, S. Ohki, M. Tansho, T. Shimizu, N. Eisaku, R. Sasai, J. Labuta, D. Ishikawa, J. P. Hill, K. Ariga, B. P. Bastakoti, Y. Yamauchi, N. Iyi,
    • Journal Title

      ACS Appl. Mater. Interfaces

      Volume: 6 Pages: 18352-18359

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Sulfur-33 NMR of organosulfur compounds and polymers2018

    • Author(s)
      k. Yamada
    • Organizer
      ACS Spring National Meeting 2018
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ゴムの架橋構造解析を目的とする硫黄NMR法の開発2017

    • Author(s)
      山田和彦
    • Organizer
      第26回ポリマー材料フォーラム
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Sulfur-33 NMR of Organic Solids II、2017

    • Author(s)
      山田和彦
    • Organizer
      第56回NMR討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 可変型超伝導磁石を用いた固体硫黄NMR の新展開2016

    • Author(s)
      山田和彦
    • Organizer
      高分子学会NMR研究会16-2、
    • Place of Presentation
      積水化学京都事業所
    • Year and Date
      2016-12-02
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] ゴムの架橋構造解析を目的とする硫黄NMR法の開発2016

    • Author(s)
      山田和彦
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2016-09-16
    • Related Report
      2016 Research-status Report
  • [Presentation] 全原子を測定対象とする次世代型核磁気共鳴(NMR)装置の開発2016

    • Author(s)
      山田和彦
    • Organizer
      高分子分析研究懇談会 第384例会
    • Place of Presentation
      明治大学紫紺館
    • Year and Date
      2016-09-05
    • Related Report
      2016 Research-status Report
    • Invited
  • [Presentation] 全原子を測定対象とする次世代型NMRの開発2016

    • Author(s)
      山田和彦
    • Organizer
      第8回日本生物物理学会中国四国支部大会
    • Place of Presentation
      高松テレサ
    • Year and Date
      2016-06-28
    • Related Report
      2016 Research-status Report
  • [Presentation] 固体NMRの基礎2014

    • Author(s)
      山田 和彦
    • Organizer
      高分子NMR研究会 NMR講座
    • Place of Presentation
      つくばサイエンス・インフォメーションセンター(つくば市)
    • Year and Date
      2014-12-12
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Sulfur-33 NMR of Organic Solids2014

    • Author(s)
      K Yamada,* D. Aoki, K. Kitagawa, H. Sogawa, M. Takahashi, T. Takata
    • Organizer
      第53回NMR討論会
    • Place of Presentation
      大阪大学(大阪市)
    • Year and Date
      2014-11-04 – 2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] Solid-State 13C NMR Study of Cholesteric Liquid Crystals2014

    • Author(s)
      山田和彦、丸茂和博、姜聲敏、出口健三、中井利仁、清水禎、渡辺順次
    • Organizer
      第56回固体NMR・材料フォーラム研究会
    • Place of Presentation
      兵庫県立会館(神戸市)
    • Year and Date
      2014-10-24
    • Related Report
      2014 Research-status Report
  • [Book] Experimental approaches of NMR spectroscopy -Methodology and application to life science and materials science2017

    • Author(s)
      K. Yamada Ch19
    • Total Pages
      636
    • Publisher
      Springer
    • Related Report
      2017 Annual Research Report
  • [Patent(Industrial Property Rights)] 磁気共鳴装置および方法2017

    • Inventor(s)
      山田和彦、武田和行、他
    • Industrial Property Rights Holder
      山田和彦、武田和行、他
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017
    • Related Report
      2017 Annual Research Report
    • Overseas

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Published: 2014-04-04   Modified: 2021-01-27  

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