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Elucidation of strong local optical activity and its application for chiral materials

Research Project

Project/Area Number 26410027
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

Narushima Tetsuya  分子科学研究所, 光分子科学研究領域, 助教 (50447314)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsキラリティ / 円二色性 / 近接場光 / ナノ構造体 / 光学活性 / 金属ナノ構造体
Outline of Final Research Achievements

Optical activity of nanostructured materials distinct from that observed in the molecular scale attracts a lot of interest. The unique optical activity originates from chiral electromagnetic interaction at nanometer spatial scales. To investigate and design optical activity, information on spatial features of optical activity must be useful. For this purpose, we developed near-field and far-field CD imaging systems. Near-field CD imaging of plasmonic nanostructures with chiral shapes revealed that both positive and negative CD signals were localized in the single chiral nanostructures. The local CD signals were two-orders of magnitude larger than macroscopically observed CD signal of the same sample. In the far-field CD imaging system, we developed a method that achieves detection of CD signals free from commingling linear dichroism signals in principle, and realized high-sensitivity CD imaging under nearly diffraction-limited spatial resolution.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (49 results)

All 2017 2016 2015 2014

All Journal Article (8 results) (of which Peer Reviewed: 7 results,  Open Access: 3 results,  Acknowledgement Compliant: 4 results) Presentation (37 results) (of which Int'l Joint Research: 10 results,  Invited: 8 results) Book (2 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Circular Dichroism Microscopy Free from Commingling Linear Dichroism via Discretely Modulated Circular Polarization2016

    • Author(s)
      Tetsuya Narushima, Hiromi Okamoto
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 35731-35731

    • DOI

      10.1038/srep35731

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Optical Activity Governed by Local Chiral Structures in Two-Dimensional Curved Metallic Nanostructures2016

    • Author(s)
      T. Narushima, S. Hashiyada, H. Okamoto
    • Journal Title

      Chirality

      Volume: 印刷中 Issue: 7 Pages: 540-544

    • DOI

      10.1002/chir.22611

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] プラズモニックナノ構造体のキラリティと局所円偏光二色性2015

    • Author(s)
      成島哲也,橋谷田俊,岡本裕巳
    • Journal Title

      プラズモニック化学研究会 News Letter

      Volume: 2 Pages: 2-2

    • Related Report
      2015 Research-status Report
    • Open Access
  • [Journal Article] Local Optical Responses of Plasmon Resonances Visualised by Near-Field Optical Imaging2015

    • Author(s)
      Hiromi Okamoto, Tetsuya Narushima, Yoshio Nishiyamaa, Kohei Imura
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 17 Issue: 9 Pages: 6192-6206

    • DOI

      10.1039/c4cp05951d

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Real space and real time observation of plasmon wavepacket dynamics in single gold nanorod2015

    • Author(s)
      Y. Nishiyama , T. Narushima, K. Imura and H. Okamoto
    • Journal Title

      Ultrafast Phenomena XIX, Springer Proceedings in Physics

      Volume: 162 Pages: 691-693

    • DOI

      10.1007/978-3-319-13242-6_170

    • ISBN
      9783319132419, 9783319132426
    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nanoscopic Study on Developing Optical Activity with Increasing Chirality for Two-Dimensional Metal Nanostructures2014

    • Author(s)
      Tetsuya Narushima, Shun Hashiyada, Hiromi Okamoto
    • Journal Title

      ACS Photonics

      Volume: 1 Issue: 8 Pages: 732-738

    • DOI

      10.1021/ph500171t

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Local Optical Activity in Achiral Two-Dimensional Gold Nanostructures2014

    • Author(s)
      Shun Hashiyada, Tetsuya Narushima, Hiromi Okamoto
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 38 Pages: 22229-22233

    • DOI

      10.1021/jp507168a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Strong Localized Optical Activity in Two-Dimensional Metal Nanostructures: Near-Field Circular Dichroism Imaging2014

    • Author(s)
      成島哲也,橋谷田俊,岡本裕巳
    • Journal Title

      Hyomen Kagaku

      Volume: 35 Issue: 6 Pages: 312-318

    • DOI

      10.1380/jsssj.35.312

    • NAID

      130004718848

    • ISSN
      0388-5321, 1881-4743
    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Generation of chiral optical near-fields with non-chiral metallic nanostructures and linearly polarized light2017

    • Author(s)
      Shun Hashiyada, T. Narushima, Hiromi Okamoto
    • Organizer
      The 4th Optical Manipulation Conference 2017 (OMC`17)
    • Place of Presentation
      Pacifico Yokohama, Yokohama, Kanagawa, Japan
    • Year and Date
      2017-04-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] キラル配位高分子への色素導入と誘起円二色性を利用したCDイメージング2017

    • Author(s)
      江口稔季,山田鉄兵,成島哲也,君塚信夫
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉キャンパス (神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] Circular Dichroism Imaging with Far- and Near-field Detection2017

    • Author(s)
      Tetsuya Narushima
    • Organizer
      Hiroshima International Workshop on Circular Dichroism Spectroscopy 2017
    • Place of Presentation
      HiSOR, Hiroshima University, Higashi-Hiroshima, Hiroshima, Japan
    • Year and Date
      2017-02-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 近接場CDナノイメージングによる局所キラリティ観察2017

    • Author(s)
      成島哲也
    • Organizer
      日本放射光学会 企画講演「キラリティ科学から次世代放射光光源への期待」
    • Place of Presentation
      神戸芸術センター (兵庫県神戸市)
    • Year and Date
      2017-01-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Near-field Circular Dichroism Microscopy for Chiral Nanostructures2016

    • Author(s)
      T. Narushima, Shun Hashiyada and Hiromi Okamoto
    • Organizer
      The 24th International Colloquium on Scanning Probe Microscopy (ICSPM24)
    • Place of Presentation
      Hawaii Convention Center, Hawaii, USA
    • Year and Date
      2016-12-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ナノマテリアルの光学活性を探る:円二色性イメージング2016

    • Author(s)
      成島哲也
    • Organizer
      第13回偏光計測研究会
    • Place of Presentation
      大阪府立大学 中百舌鳥キャンパス(大阪府堺市)
    • Year and Date
      2016-12-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] ナノマテリアルが示す光学活性の起源を探る: 円二色性ナノイメージング2016

    • Author(s)
      成島哲也
    • Organizer
      日本化学会 東海支部若手研究者フォーラム 「理論と実験から探る、マクロとミクロをつなぐケミストリー」
    • Place of Presentation
      名古屋大学・情報科学研究科(愛知県名古屋市)
    • Year and Date
      2016-11-17
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 2次元金ナノ構造体の局所円二色性測定2016

    • Author(s)
      成島哲也、岡本裕巳
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金ナノ長方形のプラズモン共鳴励起に伴う局所光学活性の偏光解析2016

    • Author(s)
      橋谷田俊,成島哲也、岡本裕巳
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(兵庫県神戸市)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Circular Dichroism Microscopy Free from Commingling Linear Dichroism to Analyze Chiroptical Properties of Materials2016

    • Author(s)
      T. Narushima, Hiromi Okamoto
    • Organizer
      The 14th international conference on Near-filed optics, Nanophotonics and related techniques (NFO14)
    • Place of Presentation
      Act City Hamamatsu Congress Center, Hamamatsu, Shizuoka, Japan
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Observation of Polarization States of Plasmonic Fields in Rectangular Gold Nanostructures Using Near-Field Polarimetry2016

    • Author(s)
      Shun Hashiyada, T. Narushima, and Hiromi Okamoto
    • Organizer
      The 14th international conference on Near-filed optics, Nanophotonics and related techniques (NFO14)
    • Place of Presentation
      Act City Hamamatsu Congress Center, Hamamatsu, Shizuoka, Japan
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金ナノ長方形の縦プラズモンモード励起に伴う局所光学活性2016

    • Author(s)
      橋谷田俊,成島哲也、岡本裕巳
    • Organizer
      平成28年度 日本分光学会年次講演会
    • Place of Presentation
      大阪大学豊中キャンパス(大阪府豊中市)
    • Year and Date
      2016-05-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] Near-Field Circular Dichroism Imaging to Design Optically Active Nanomaterials2016

    • Author(s)
      T. Narushima, S. Hashiyada, H. Okamoto
    • Organizer
      The 11th Annual IEEE International Conference on Nano/Micro Engineered and Molecular Systems (IEEE-NEMS 2016)
    • Place of Presentation
      L-Park Sendai & Hotel Matsushima Taikanso, Miyagi
    • Year and Date
      2016-04-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 離散的な円偏光変調方式による円二色性顕微鏡システム2016

    • Author(s)
      成島哲也、岡本裕巳
    • Organizer
      第63回 応用物理学関係連合講演会
    • Place of Presentation
      東工大大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] 長方形金ナノ構造体におけるプラズモン場の偏光状態マッピング2016

    • Author(s)
      橋谷田俊,成島哲也、岡本裕巳
    • Organizer
      第63回 応用物理学関係連合講演会
    • Place of Presentation
      東工大大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Research-status Report
  • [Presentation] キラル物質に都合の良い光電場の発生とその相互作用に関する研究2016

    • Author(s)
      成島哲也
    • Organizer
      公益財団法人 光科学技術研究振興財団研究助成金贈呈・研究表彰式(研究報告講演)
    • Place of Presentation
      ホテルクラウンパレス浜松(静岡県浜松市)
    • Year and Date
      2016-03-03
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] Nanoscopic Study on Local Optical Activity Caused by Two-Dimensional Metallic Nanostructures2015

    • Author(s)
      T. Narushima, Shun Hashiyada and Hiromi Okamoto
    • Organizer
      表面界面スペクトロスコピー 2015 (SIS2015)
    • Place of Presentation
      国立女性教育会館(埼玉県比企郡嵐山町)
    • Year and Date
      2015-11-27
    • Related Report
      2015 Research-status Report
  • [Presentation] ナノ構造物質に発現する強い局所光学活性2015

    • Author(s)
      成島哲也, 橋谷田俊, 岡本裕巳
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] 近接場非線形CDイメージングによる金ナノロッドにおける局所光学活性の観測2015

    • Author(s)
      西山嘉男, 成島哲也, 岡本裕巳
    • Organizer
      第9回分子科学討論会
    • Place of Presentation
      東工大大岡山キャンパス(東京都目黒区)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Research-status Report
  • [Presentation] Near-field Imaging for Nanoscale Local Circular Dichroism2015

    • Author(s)
      T. Narushima, Shun Hashiyada and Hiromi Okamoto
    • Organizer
      15th International Conference on Chiroptical Spectroscopy (CD2015)
    • Place of Presentation
      Conference Hall, Hokkaido University, Sapporo, Hokkaido, Japan
    • Year and Date
      2015-08-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Near-field nonlinear CD imaging of gold nanorods2015

    • Author(s)
      Y. Nishiyama, T. Narushima, H. Okamoto
    • Organizer
      15th International Conference on Chiroptical Spectroscopy (CD2015)
    • Place of Presentation
      Conference Hall, Hokkaido University, Sapporo, Hokkaido, Japan
    • Year and Date
      2015-08-30
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Ultrafast time-resolved near-field imaging of plasmon dynamics in single gold nanorods2015

    • Author(s)
      Y. Nishiyama, T. Narushima, K. Imura, H. Okamoto
    • Organizer
      The 10th Asia-Pacific Conference on Near-field Optics (APNFO10)
    • Place of Presentation
      Hakodate Research Center for Fisheries and Oceans, Hakodate, Hokkaido, Japan
    • Year and Date
      2015-07-07
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Locally Enhanced Optical Activity in Two-Dimensional Chiral Metal Nanostructures2015

    • Author(s)
      T. Narushima, Shun Hashiyada and Hiromi Okamoto
    • Organizer
      The 10th Asia-Pacific Conference on Near-field Optics (APNFO10)
    • Place of Presentation
      Hakodate Research Center for Fisheries and Oceans, Hakodate, Hokkaido, Japan
    • Year and Date
      2015-07-07
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金ナノロッドにおけるプラズモンダイナミクスの時間分解イメージング2015

    • Author(s)
      西山嘉男, 成島哲也, 井村考平, 岡本裕巳
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      本大学理工学部 船橋キャンパス/薬学部(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] ナノ構造物質に発現する強い局所光学活性の可視化とそれに基づくカイラル 相互作用光デバイスへの展開2014

    • Author(s)
      成島哲也
    • Organizer
      ISSPワークショップ 機能物質融合科学研究会シリーズ(1)「光機能」
    • Place of Presentation
      東京大学物性研究所(千葉県柏市)
    • Year and Date
      2014-12-04 – 2014-12-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Local optical activity caused by chirality of 2D plasmonic metal nanostructures2014

    • Author(s)
      T. Narushima, Shun Hashiyada and Hiromi Okamoto
    • Organizer
      The 7th International Symposium on Surface Science and Nanotechnology (ISSS-7)
    • Place of Presentation
      Kunibiki Messe, Matsue, Shimane, Japan
    • Year and Date
      2014-11-02 – 2014-11-06
    • Related Report
      2014 Research-status Report
  • [Presentation] 金属ナノ構造体のキラリティ獲得に伴うナノスケール局所光学活性の変化2014

    • Author(s)
      成島哲也, 橋谷田俊, 岡本裕巳
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学 東広島キャンパス(広島県東広島市)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 超高速時間分解近接場顕微測定による金ナノロッドにおけるプラズモン波ダイナミクスの時空間観測2014

    • Author(s)
      西山嘉男, 成島哲也, 井村考平, 岡本裕巳
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学 東広島キャンパス(広島県東広島市)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] アキラルな2次元金ナノ構造における局所光学活性2014

    • Author(s)
      橋谷田俊, 成島哲也, 岡本裕巳
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学 東広島キャンパス(広島県東広島市)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 金ナノディスク及びその一次元配列構造の分光特性2014

    • Author(s)
      小若泰之, 成島哲也, 西山嘉男, 岡本裕巳
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学 東広島キャンパス(広島県東広島市)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Prominent localized optical activities inherent in achiral and chiral metal nanostructures2014

    • Author(s)
      T. Narushima, Shun Hashiyada and Hiromi Okamoto
    • Organizer
      The international conference on Near-filed optics, Nanophotonics and related techniques (NFO13)
    • Place of Presentation
      Snow bird mountain resort, Salt lake city, Utah, USA
    • Year and Date
      2014-08-31 – 2014-09-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Local Optical Activity in Achiral 2D Gold Nanostructures2014

    • Author(s)
      Shun Hashiyada, T. Narushima, and Hiromi Okamoto
    • Organizer
      The international conference on Near-filed optics, Nanophotonics and related techniques (NFO13)
    • Place of Presentation
      Snow bird mountain resort, Salt lake city, Utah, USA
    • Year and Date
      2014-08-31 – 2014-09-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Ultrafast near-field imaging of plasmon wavepacket dynamics in single gold nanorod2014

    • Author(s)
      Y. Nishiyama, T. Narushima, K. Imura, H. Okamoto
    • Organizer
      The international conference on Near-filed optics, Nanophotonics and related techniques (NFO13)
    • Place of Presentation
      Snow bird mountain resort, Salt lake city, Utah, USA
    • Year and Date
      2014-08-31 – 2014-09-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Fabrication and evaluation of plasmonic nanopore towards single molecule DNA sequencing2014

    • Author(s)
      M. Tsukahara, S. Itoh, H. Yamazaki, K. Esashika, T. Narsushima, H. Okamoto, T. Saiki
    • Organizer
      The international conference on Near-filed optics, Nanophotonics and related techniques (NFO13)
    • Place of Presentation
      Snow bird mountain resort, Salt lake city, Utah, USA
    • Year and Date
      2014-08-31 – 2014-09-04
    • Related Report
      2014 Research-status Report
  • [Presentation] Real space and real time observation of plasmon wavepacket dynamics in single gold nanorod2014

    • Author(s)
      Y. Nishiyama, T. Narushima, K. Imura, H. Okamoto
    • Organizer
      19th International Conference on Ultrafast Phenomena (UP 2014)
    • Place of Presentation
      Okinawa Convention center, Ginowan City, Okinawa, Japan
    • Year and Date
      2014-07-07 – 2014-07-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 実験と電磁場シミュレーションの併用による金属ナノ構造体の光学活性現象の解明2014

    • Author(s)
      成島哲也
    • Organizer
      RSoft 特別セミナー 2014
    • Place of Presentation
      アキバプラザ(東京都千代田区)
    • Year and Date
      2014-06-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] ナノロッドにおけるプラズモン波束ダイナミクスの時間分解近接場イメージング2014

    • Author(s)
      西山嘉男, 成島哲也, 井村考平, 岡本裕巳
    • Organizer
      平成 26年度日本分光学会 年次講演会・国際シンポジウム
    • Place of Presentation
      理化学研究所和光キャンパス 鈴木梅太郎記念ホール(埼玉県和光市)
    • Year and Date
      2014-05-26 – 2014-05-28
    • Related Report
      2014 Research-status Report
  • [Book] Compendium of Surface and Interface Analysis(分担執筆,Molecular Technology for Chirality Control: From Structure to Circularly Polarizationの章を執筆)2017

    • Author(s)
      Tetsuya Narushima (分担執筆,Scanning Near-field Microscopy/Near-field Scanning Microscopyの章を執筆)
    • Total Pages
      500
    • Publisher
      Springer
    • Related Report
      2016 Annual Research Report
  • [Book] Molecular Technology. Energy Innovation2017

    • Author(s)
      Yoshiaki Uchida, Tetsuya Narushima, Junpei Yuasa
    • Total Pages
      500
    • Publisher
      Wiley-VCH
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 円偏光照射器,分析装置及び顕微鏡2016

    • Inventor(s)
      成島哲也,岡本裕巳
    • Industrial Property Rights Holder
      大学共同利用機関法人 自然科学研究機構
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-12-06
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 円偏光照射器,分析装置及び顕微鏡2015

    • Inventor(s)
      岡本裕巳,成島哲也
    • Industrial Property Rights Holder
      岡本裕巳,成島哲也
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-257226
    • Filing Date
      2015-12-28
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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