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Two-photo absorption switching based on reversible interconversion of biradical species

Research Project

Project/Area Number 26410034
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionTohoku University

Principal Investigator

Takeda Takashi  東北大学, 多元物質科学研究所, 助教 (80625038)

Co-Investigator(Renkei-kenkyūsha) AKUTAGAWA Tomoyuki  東北大学, 多元物質科学研究所, 教授 (60271631)
KAWAMATA Jun  山口大学, 創成科学研究科, 教授 (40214689)
SUZUKI Yasutaka  山口大学, 創成科学研究科, 准教授 (30634753)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords酸化還元対 / エレクトロクロミズム / 動的挙動 / サーモサリエント効果 / 動的平衡 / 二光子吸収 / チオフェン / キナクリドン
Outline of Final Research Achievements

In this research, we attempted to prepare two-photon absorption switching system based on redox reaction. To achieve this, we focused on quinoidal molecules and prepared those with redox units. Specifically, dicyanomethylenated quinacridone and diarylmethylene substituted thiophene derivatives were prepared and their redox, photophysical properties were examined. During the course of this project, we found some crystal jumping behavior, which mechanism was also examined.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (25 results)

All 2017 2016 2015 2014

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 11 results,  Open Access: 4 results) Presentation (14 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Electronic and Crystal Structures of 1,2,3-Triazole-Fused p-Benzoquinone Derivatives2017

    • Author(s)
      Masahiro Sato, Takashi Takeda, Norihisa Hoshino, Tomoyuki Akutagawa
    • Journal Title

      CrystEngComm

      Volume: 19 Issue: 6 Pages: 910-917

    • DOI

      10.1039/c6ce02167k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Anisotropic Dissociation of π-π Stacking and Flipping Motion Induce Crystal Jumping in Alkylacridones and their Dicyanomethylene Derivatives2016

    • Author(s)
      Takashi Takeda, Tomoyuki Akutagawa
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 23 Pages: 7763-7770

    • DOI

      10.1002/chem.201600794

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electron-Deficient Anthraquinone Derivatives as Cathodic Material for Lithium Ion Batteries2016

    • Author(s)
      Takashi Takeda, Ryosuke Taniki, Asuna Masuda, Itaru Honma, Tomoyuki Akutagawa
    • Journal Title

      Journal of Power Sources

      Volume: 328 Pages: 228-234

    • DOI

      10.1016/j.jpowsour.2016.08.022

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Alkylamide-Substituted Tetraphenylethylene: Three Modes of Fluorescence Based on a Hydrogen-Bonded Excimer2016

    • Author(s)
      Takashi Takeda, Shunsuke Yamamoto, Masaya Mitsuishi, and Tomoyuki Akutagawa
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 14 Issue: 38 Pages: 8922-8926

    • DOI

      10.1039/c6ob01110a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation, Structure and Redox Behavior of Bis(diarylmethylene)dihydrothiophene and Its p-Extended Analogues2015

    • Author(s)
      Takeda Takashi, Tomoyuki Akutagawa
    • Journal Title

      J. Org. Chem.

      Volume: 80 Issue: 4 Pages: 2455-2462

    • DOI

      10.1021/acs.joc.5b00021

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] New Insights into the Hexaphenylethane Riddle: Formation of an α,o-Dimer2015

    • Author(s)
      Y. Uchimura, T. Takeda, R. Katoono, K. Fujiwara, and T. Suzuki
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 54 Issue: 13 Pages: 4010-4013

    • DOI

      10.1002/anie.201500122

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electron-deficient Acene-based Liquid Crystals: Dialkoxydicyanopyrazinoquinoxalines2015

    • Author(s)
      Takashi Takeda, Jun’ya Tsutsumi, Tatsuo Hasegawa, Shin-ichiro Noro, Takayoshi Nakamura, and Tomoyuki Akutagawa
    • Journal Title

      J. Mater. Chem. C.

      Volume: 3 Issue: 13 Pages: 3016-3022

    • DOI

      10.1039/c5tc00022j

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Fluorescent Ferroelectrics of Hydrogen-Bonding Pyrene Derivative2015

    • Author(s)
      Hayato Anetai, Yoshifumi Wada, Takashi Takeda, Norihisa Hoshino, Shunsuke Yamamoto, Masaya Mitsuishi, Taishi Takenobu, Tomoyuki Akutagawa
    • Journal Title

      The Journal of Physical Chemistry Letters

      Volume: 6 Issue: 10 Pages: 1813-1818

    • DOI

      10.1021/acs.jpclett.5b00703

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Dynamic Behavior, Electrochromism, and Two-Photon Absorption of Dicyanomethylated Quinacridone2014

    • Author(s)
      Takashi Takeda, Hiroyuki Sugihara, Yasutaka Suzuki, Jun Kawamata, and Tomoyuki Akutagawa
    • Journal Title

      J. Org. Chem.

      Volume: 79 Issue: 20 Pages: 9669-9677

    • DOI

      10.1021/jo501800g

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Molecular Assembly and Ferroelectric Response of Benzenecarboxamides Bearing Multiple -CONHC14H29 Chains2014

    • Author(s)
      Yuta Shishido, Hayato Anetai, Takashi Takeda, Norihisa Hoshino, Shin-ichiro Noro, Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      J. Phys. Chem. C.

      Volume: 118 Issue: 36 Pages: 21204-21214

    • DOI

      10.1021/jp506035h

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] The Formation of Organogels and Helical Nanofibers from Simple Organic Salts2014

    • Author(s)
      Yuya Yoshii, Norihisa Hoshino, Takashi Takeda, Hiroki Moritomo, Jun Kawamata,Takayoshi Nakamura, Tomoyuki Akutagawa
    • Journal Title

      Chemistry - A European Journal

      Volume: 20 Issue: 49 Pages: 16279-16285

    • DOI

      10.1002/chem.201404043

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ジアルコキシピラジノキノキサリンジオンの合成と物性2017

    • Author(s)
      武田 貴志、池元 智拾、星野 哲久、芥川 智行
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] アリールスルホンアミド基を有するアントラキノン:特異な電子状態と溶媒吸着能を有する結晶構造2016

    • Author(s)
      武田 貴志、野呂 真一郎、鈴木 康孝、川俣 純、中村 貴義、芥川 智行
    • Organizer
      第10回分子科学討論会
    • Place of Presentation
      神戸ファッションマート(神戸)
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 分子運動と分子間相互作用の変調に基づくアクリドン誘導体の結晶ジャンプ2016

    • Author(s)
      武田 貴志、芥川 智行
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場(広島)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] アリールスルホンアミド基を有するアントラキノン:特異な電子状態と溶媒吸着能を有する結晶構造2016

    • Author(s)
      武田 貴志、芥川 智行
    • Organizer
      第27回基礎有機化学討論会
    • Place of Presentation
      広島国際会議場(広島)
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] スルホンアミド基を有するアントラキノンの電子物性、結晶構造と溶媒吸着挙動2016

    • Author(s)
      武田 貴志、芥川 智行
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学 (京田辺)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Development of Functional Materials Based on Simple Aromatic Compounds: Fluorescent Ferroelectrics and Crystal Jumping2016

    • Author(s)
      Takashi Takeda
    • Organizer
      Workshop on New π-Electronic Systems: Theory and Experiments
    • Place of Presentation
      大阪大学(豊中)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シンプルな縮環芳香族化合物を基盤とした電子材料の開発2015

    • Author(s)
      武田 貴志
    • Organizer
      附置研究所間アライアンス第三回若手研究交流会
    • Place of Presentation
      九州大学 (春日)
    • Year and Date
      2015-11-16
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] ジアルコキシジシアノピラジノキノキサリン誘導体の液晶性と電子物性2015

    • Author(s)
      武田 貴志、芥川 智行
    • Organizer
      第26回基礎有機化学討論会
    • Place of Presentation
      愛媛大学・松山大学 (松山)
    • Year and Date
      2015-09-24
    • Related Report
      2015 Research-status Report
  • [Presentation] Electron-deficient Acene-based Liquid Crystal: Dialkoxydicyanopyrazinoquinoxalines2015

    • Author(s)
      Takashi Takeda, Jun'ya Tsutsumi, Tatsuo Hasegawa, Shin-ichiro Noro, Takayoshi Nakamura, Tomoyukiakutagawa
    • Organizer
      16th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      Madrid (Spain)
    • Year and Date
      2015-07-05
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 長鎖アミド基を有するテトラフェニルエチレンの液晶性・光物性・誘電物性2015

    • Author(s)
      武田 貴志、姉帯 勇人、芥川 智行
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学 (船橋)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 強誘電性および電子活性を有する液晶性化合物の創製2014

    • Author(s)
      武田 貴志
    • Organizer
      構造有機化学若手研究者 研究会・ミニシンポジウム2014
    • Place of Presentation
      北海道大学 (札幌)
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Research-status Report
  • [Presentation] キノイド構造を有する電子受容体及び電子供与体の合成・構造とエレクトロクロミズム2014

    • Author(s)
      武田 貴志、芥川 智行
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学 (東広島)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] アレーンオリゴアミドが示す自己集積挙動と強誘電体物性2014

    • Author(s)
      武田 貴志、姉帯 勇人、宍戸 勇太、星野 哲久、芥川 智行
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学 (仙台)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Structure, dynamic behavior, and electrochromism of quinacridone derivatives2014

    • Author(s)
      Takashi Takeda, Tomoyuki Akutagawa
    • Organizer
      nternational Conference on Science and Technology of Synthetic Metals 2014
    • Place of Presentation
      Turku (Finland)
    • Year and Date
      2014-06-30 – 2014-07-05
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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