Development of Novel Synthetic Reactions of Oligosilanes using Transition Metal Complexes
| Project/Area Number |
26410036
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gunma University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | オリゴシラン / ヒドロシラン / 遷移金属触媒 / 脱水素カップリング反応 / ヒドロシリル化反応 |
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| Outline of Final Research Achievements |
Reactions of hydrosilanes using transition metal catalysts are widely known, and various organosilicon compounds can be synthesized. Most of such catalytic reactions, however, could not be used for oligosilane synthesis because most of the transition metals cleave Si-Si bonds. In this study, we have investigated for novel catalytic reactions of hydrooligosilanes without Si-Si bond cleavage. As a result, we found that the alkoxylation reaction and the hydrosilylation reaction of hydrooligosilanes by the ruthenium catalysts proceed without breaking the Si-Si bonds.
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Report
(4 results)
Research Products
(24 results)
