| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Outline of Final Research Achievements |
It was found that a Pd(II) peroxocarbonate complex bearing cavity-shaped carbene ligands, which is formed through carbon dioxide capture, undergo oxygen-atom transfer reaction toward a phosphine to afford a Pd(II) carbonate complex and the corresponding phosphine oxide. The oxygen-atom-transfer reaction was dramatically accelerated by lithium chloride, which plays a role of releasing the peroxocarbonate moiety from the Pd complex. In addition, it was shown that the peroxocarbonate complex reacts with a sulfoxide to form the Pd carbonate complex and a sulfone.
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