Development of an Efficient Carbon Dioxide Fixation Reaction by Taking Advantage of Cavity-shaped Ligand
| Project/Area Number |
26410038
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
Sase Shohei 東京工業大学, 理学院, 助教 (90515165)
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| Project Period (FY) |
2014-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | キャビティ型配位子 / 二酸化炭素 / N-複素環カルベン / ペルオキソカルボナート / 二酸化炭素固定 |
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| Outline of Final Research Achievements |
It was found that a Pd(II) peroxocarbonate complex bearing cavity-shaped carbene ligands, which is formed through carbon dioxide capture, undergo oxygen-atom transfer reaction toward a phosphine to afford a Pd(II) carbonate complex and the corresponding phosphine oxide. The oxygen-atom-transfer reaction was dramatically accelerated by lithium chloride, which plays a role of releasing the peroxocarbonate moiety from the Pd complex. In addition, it was shown that the peroxocarbonate complex reacts with a sulfoxide to form the Pd carbonate complex and a sulfone.
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Report
(5 results)
Research Products
(32 results)
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[Journal Article] Chloro-(η6-p-cymene)-{3-[3,5-bis(2,6-dimethylphenyl)-1,2-phenylene]-1-(2,6,2"6"-tetramethyl-1,1':3',1"-terphenyl-5'-yl)imidazol-2-ylidene}-ruthenium(II) benzene disolvate2014
Author(s)
Shohei Sase, Yuriko Ikehara, Kei Goto
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Journal Title
Acta Crystallographica, Section E
Volume: 70
Issue: 12
Pages: m394-m394
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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