Exploration of facile synthesis for functional porphyrinoids and investigation of their applications
| Project/Area Number |
26410042
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
JIYOUNG SHIN 名古屋大学, 工学研究科(国際), 特任准教授 (30622295)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 構造有機化学 / porphyrinoid / organic battery / bodily / porphyrin / porphyrinoide / electrochemistry |
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| Outline of Final Research Achievements |
Nickel(II) norcorrole (NiNC) which exhibits characteristic antiaromatic properties and a reasonable chemical-stabiltiy has been synthesised in our research group, and further investigated to study its interesting magnetic features created by molecular stacking. The molecular staking induces aromaticity on antiaromatic molecules was experimentally proved.
NiNC was also applied for an active electrode material of Li-organic and Li-free organic batteries. The batteries performed remarkably charge/discharge processes over 100 cycles and showed high discharge capacity with great efficiencies.
Furthermore, various functional porphyrinoids and their hybrid molecules were synthesized through our research, and interesting properties of the molecule and application approaches were reported through conferences and research papers. Some of the publications were highly cited, selected as hot papers, and invited to the journal frontispieces.
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Report
(4 results)
Research Products
(15 results)
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[Journal Article] Stacked antiaromatic porphyrins2016
Author(s)
Ryo Nozawa, Hiroko Tanaka, Won-Young Cha, Yongseok Hong, Ichiro Hisaki, Soji Shimizu, Ji-Young Shin, Tim Kowalczyk, Stephan Irle, Dongho Kim, Hiroshi Shinokubo
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Journal Title
Nature Communications
Volume: 7
Issue: 1
Pages: 13620-13620
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Presentation] Anti aromatic Norcorrole Batteries2015
Author(s)
Ji-Young Shin, Tetsuya Yamada, Hirofumi Yoshikawa, Kunio Awaga, Hiroshi Shinokubo
Organizer
Pacifichem2015
Place of Presentation
Honolulu, Hawaii, USA
Year and Date
2015-12-15
Related Report
Int'l Joint Research
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[Presentation] Antiaromatic Norcorrole Batteries2014
Author(s)
J.-Y. Shin, T. Yamada, H. Yoshikawa, K. Awaga, H. Shinokubo,
Organizer
IGER Workshop on Molecular Electronics for Young Researchers
Place of Presentation
Nagoya University, Nagoya, Japan
Year and Date
2014-10-21 – 2014-10-22
Related Report
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