| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Outline of Final Research Achievements |
Nickel(II) norcorrole (NiNC) which exhibits characteristic antiaromatic properties and a reasonable chemical-stabiltiy has been synthesised in our research group, and further investigated to study its interesting magnetic features created by molecular stacking. The molecular staking induces aromaticity on antiaromatic molecules was experimentally proved.
NiNC was also applied for an active electrode material of Li-organic and Li-free organic batteries. The batteries performed remarkably charge/discharge processes over 100 cycles and showed high discharge capacity with great efficiencies.
Furthermore, various functional porphyrinoids and their hybrid molecules were synthesized through our research, and interesting properties of the molecule and application approaches were reported through conferences and research papers. Some of the publications were highly cited, selected as hot papers, and invited to the journal frontispieces.
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