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Reaction Analysis of Electro-Organic Chemistry by in situ Raman Spectroscopy and its Application to Organic Synthesis

Research Project

Project/Area Number 26410059
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionKindai University

Principal Investigator

MATSUMOTO Kouichi  近畿大学, 理工学部, 講師 (60581741)

Co-Investigator(Kenkyū-buntansha) 若林 知成  近畿大学, 理工学部, 教授 (30273428)
森澤 勇介  近畿大学, 理工学部, 准教授 (60510021)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords有機合成化学 / 有機電解合成 / ラマン分光法 / 有機活性種 / 反応速度 / リサイクル型フロー電解 / フロー電解 / 反応速度解析 / ジブロモ化反応 / 反応開発 / 反応中間体 / 反応機構
Outline of Final Research Achievements

We have develped new monitoring system in electro-oranic chemistry by Raman spectroscopy system, in which unstable organic reactive species were observed at low temperature. In addition, we have established the recycling flow system of electro-synthesis, in which in situ Raman spectroscopy was measured for kinetic analysis.
Thus, we have demonstrated that Raman spectroscopy is powerful tool for reaction design, kinetic analysis, and the detection of reactive species in electro-organic chemistry.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (18 results)

All 2017 2016 2015 2014

All Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Int'l Joint Research: 5 results,  Invited: 2 results)

  • [Journal Article] Esterification of Carboxylic Acids with Alkyl Halides Using Electroreduction2015

    • Author(s)
      Miyamoto, Y.; Yamada, Y.; Shimazaki, H.; Shimada, K.; Nokami, T.; Nishiwaki, K.; Kashimura, S.; Matsumoto, K.
    • Journal Title

      Electrochemistry

      Volume: 83 Pages: 161-164

    • NAID

      130004787086

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Low temperature in situ Raman spectroscopy of an electro-generated arylbis(arylthio)sulfonium ion2015

    • Author(s)
      Matsumoto, K.; Miyamoto, Y.; Shimada, K.; Morisawa, Y.; Zipse, H.; Suga, S.; Yoshida, J.; Kashimura, S.; Wakabayashi, T.
    • Journal Title

      Chem. Commun.

      Volume: 51 Issue: 66 Pages: 13106-13109

    • DOI

      10.1039/c5cc03585f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] ルイス酸を用いたPrins環化反応による含フッ素2環式化合物の合成2017

    • Author(s)
      松本 浩一・柳 里奈・山口航志・野上敏材・西脇敬二・柏村成史
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      横浜(慶応大学)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電解酸化を用いたPrins 環化反応による含フッ素2環式化合物の合成2016

    • Author(s)
      松本 浩一・柳 里奈・山口 航志・野上 敏材・西脇 敬二・柏村 成史
    • Organizer
      第6回CSJ化学フェスタ2016
    • Place of Presentation
      東京(タワーホール船堀)
    • Year and Date
      2016-11-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electrochemically Generated Cationic Intermediates As Studied by in situ Raman Spectroscopy2016

    • Author(s)
      Kouichi Matsumoto, Yu Miyamoto, Yusuke Morisawa, Hendrik Zipse, Seiji Suga, Jun-ichi Yoshida, Shigenori Kashimura, Tomonari Wakabayashi
    • Organizer
      Chemistry and Physics at Low Temperatures (CPLT 2016)
    • Place of Presentation
      Biarritz (France)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 両極から生じる活性種を用いた置換アリル化合物の効率合成2016

    • Author(s)
      松本浩一・伊丹紗代・壬生託人・宮本 侑・西脇敬二・柏村成史
    • Organizer
      第40回有機電子移動化学討論会
    • Place of Presentation
      新潟(新潟大学)
    • Year and Date
      2016-06-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電解酸化を用いたPrins環化反応による含フッ素2環式化合物の合成2016

    • Author(s)
      松本浩一・柳 里奈・山口航志・野上敏材・西脇敬二・柏村成史
    • Organizer
      第40回有機電子移動化学討論会
    • Place of Presentation
      新潟(新潟大学)
    • Year and Date
      2016-06-23
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of Fluorinated Tetrahydropyrans via Prins Cyclization of Aldehydes and Homoallylic Alcohols Using Electrochemical Oxidation2016

    • Author(s)
      Kouichi Matsumoto, Kouji Yamaguchi, Keita Miyasaka, Fumi Haga, Toshiki Nokami,Keiji Nishiwaki, and Shigenori Kashimura
    • Organizer
      The 12th International Symposium on Organic Reactions(ISOR-12)
    • Place of Presentation
      京都(京都テルサ)
    • Year and Date
      2016-04-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 電解酸化により発生・蓄積させたチイレニウムイオンの反応性2016

    • Author(s)
      堀内俊・林竜太朗・清水章弘・松本浩一・宮本侑・森澤勇介・若林知成・吉田潤一
    • Organizer
      日本化学会 第96春季年会
    • Place of Presentation
      同志社大学(京都府)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Research-status Report
  • [Presentation] アルキンのジブロモ化反応に対するフロー・ラマン測定2016

    • Author(s)
      松本 浩一・深田 陽司・山口航志・三谷尚也・遠藤あすか・佐多良介・畑中美穂・森澤勇介・柏村成史・若林知成
    • Organizer
      2016年度近大若手シンポジウム
    • Place of Presentation
      大阪(近畿大学)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電解酸を開始剤に用いたエポキシオレフィンのカチオン環化反応2016

    • Author(s)
      松本 浩一・嶋尾 浩輝・山本 寛子・島崎 勇人・柏村 成史
    • Organizer
      2016年度近大若手シンポジウム
    • Place of Presentation
      大阪(近畿大学)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電解酸化を用いたPrins環化反応による含フッ素2環式化合物の合成2016

    • Author(s)
      松本 浩一・柳 里奈・山口 航志・野上 敏材・西脇 敬二・柏村 成史
    • Organizer
      2016年度近大若手シンポジウム
    • Place of Presentation
      大阪(近畿大学)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of Oxazoline from Unsaturated Amides Using an Electrochemically Generated ArS(ArSSAr)+ Pool2015

    • Author(s)
      Yu Miyamoto 1, Kouichi Matsumoto, Seiji Suga, Shigenori Kashimura, Jun-ichi Yoshida
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ホノルル(アメリカ)
    • Year and Date
      2015-12-17
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis of Fluorinated Tetrahydropyrans via Prins Cyclization of Aldehydes and Homoallylic Alcohols Using Electrochemical Oxidation2015

    • Author(s)
      Kouichi Matsumoto, Kouji Yamaguchi, Keita Miyasaka, Fumi Haga, Toshiki Nokami, Keiji Nishiwaki, and Shigenori Kashimura
    • Organizer
      15th European Symposium on Organic Reactivity
    • Place of Presentation
      キール(ドイツ)
    • Year and Date
      2015-09-01
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Esterification of Carboxylic Acids with Alkyl Halides Using Electro-reduction2015

    • Author(s)
      Kouichi MATSUMOTO, Yu MIYAMOTO, Yuki YAMADA, Hayato SHIMAZAKI, Kazuaki SHIMADA, Toshiki NOKAMI, Keiji NISHIWAKI, Shigenori KASHIMURA
    • Organizer
      International Union of Pure and Applied Chemistry 2015(IUPAC-2015)
    • Place of Presentation
      プサン(韓国)
    • Year and Date
      2015-08-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 電解酸化を用いたPrins 環化反応による含フッ素化体の合成2015

    • Author(s)
      松本浩一・山口航志・宮阪敬太・葉賀 文・野上敏材・西脇敬二・柏村成史
    • Organizer
      第39回有機電子移動化学討論会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      2015-06-25
    • Related Report
      2015 Research-status Report
  • [Presentation] ラマン分光法によるジアリールジスルフィドの電解酸化のその場モニタリング2015

    • Author(s)
      松本 浩一,島田 和明,◯宮本 侑,森澤 勇介,若林 知成,菅 誠治,柏村 成史,吉田 潤一
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Research-status Report
  • [Presentation] 電解酸化反応による有機イオウカチオン種の発生と合成化学への利用2014

    • Author(s)
      ○松本浩一
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Research-status Report
    • Invited

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Published: 2014-04-04   Modified: 2020-01-20  

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