| Project/Area Number |
26410060
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Tokyo Institute of Technology (2015-2016)
Okayama University of Science (2014) |
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Principal Investigator |
TOYOTA SHINJI 東京工業大学, 理学院, 教授 (80207646)
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| Co-Investigator(Renkei-kenkyūsha) |
IWANAGA Tetsuo 岡山理科大学, 理学部, 講師 (40454805)
WAKAMATSU Kan 岡山理科大学, 理学部, 准教授 (60271425)
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| Research Collaborator |
INOUE Masataka
OKI Tomohiro
SAIBARA Toyoaki
IKEDA Hiroshi
YAMAMOTO Yuta
NAGAOKA Maiko
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | パイ共役系 / アントラセン / 環状構造 / アセチレン / ビニレン / 理論計算 / クロスカップリング / ひずみエネルギー / クロスカップリング反応 / NMR / DFT計算 / 動的挙動 |
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| Outline of Final Research Achievements |
To create pi-conjugated anthracene compounds with novel cyclic structures, cyclic oligomers having acetylene or vinylene linkers were studied.
For compounds with rigid cyclic structures, anthracene cyclic dimers with inside alkyl groups were synthesized to evaluate the flexibility of the alkyl groups and the molecular strain. For vinylene-bridged compounds, anthracene cyclic dimers to tetramers were synthesized by repeated cross couplings. For face-to-face type macrocyclic compounds, structures of macrocyclic compounds with diacetylene linkers were investigated. Features of this anthracene-based molecular design are revealed from the relation between molecular structures of properties of the above cyclic compounds.
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