• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Synthesis of silicon-containing nanosize molecules and their application to functional materials

Research Project

Project/Area Number 26410061
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic chemistry
Research InstitutionKurashiki University of Science and the Arts

Principal Investigator

Naka Akinobu  倉敷芸術科学大学, 生命科学部, 教授 (00289232)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsケイ素 / ナノサイズ分子 / 星型化合物 / 色素増感太陽電池 / 機能材料 / ナノサイズ / 紫外可視吸収スペクトル / 蛍光発光スペクトル
Outline of Final Research Achievements

In this report, we aimed to synthesize star-shaped compounds having regularly and alternately silicon-silicon bonds and various π-electron systems, and to apply them to functional materials, especially dye-sensitized solar cells. we could establish a synthesis method of a star compound having triazine as a core and a benzothiadiazole derivative in three directions. Dye-sensitized solar cells using it as a dye was prepared and its photoelectric conversion efficiency was measured. As a result, the power conversion efficiency was low, but it was able to clarify that it functions as a dye sensitized solar cell.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (15 results)

All 2017 2016 2015 2014

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Acknowledgement Compliant: 4 results) Presentation (7 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Fabrication and Microstructure Tuning of a Pyrimidine-bridged Organoalkoxysilane Membrane for CO2 Separation2017

    • Author(s)
      Liang Yu, Masakoto Kanezashi, Hiroki Nagasawa, Joji Oshita, Akinobu Naka, Toshinori Tsuru
    • Journal Title

      Industrial & Engineering Chemistry Research

      Volume: 56 Issue: 5 Pages: 1316-1326

    • DOI

      10.1021/acs.iecr.6b04460

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Platinum-catalyzed reactions of 2,3-bis(diethylsilyl)thiophene with alkynes2016

    • Author(s)
      Akinobu Naka, Takashi Mihara, Hisayoshi Kobayashi, Mitsuo Ishikawa
    • Journal Title

      Journal of Organometallic Chemistry

      Volume: 822 Pages: 221-227

    • DOI

      10.1016/j.jorganchem.2016.09.004

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of pentamethyldisilanyl-substituted starlike molecule with triazine core and its application to dye-sensitized solar cells2016

    • Author(s)
      Akinobu Naka, Kiyoshi Fujishima, Erika Okada, Mao Noguchi, Joji Ohshita, Yohei Adachi, Yousuke Ooyama, Mitsuo Ishikawa
    • Journal Title

      Journal of Organometallic Chemistry

      Volume: 825-826 Pages: 63-68

    • DOI

      10.1016/j.jorganchem.2016.10.022

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thermal behavior of benzobis(tetraethyldisilacyclobutene)2016

    • Author(s)
      Akinobu Naka, Kazunari Yoshizawa, Mitsuo Ishikawa
    • Journal Title

      Z. Naturforsch.

      Volume: 71b Issue: 3 Pages: 227-230

    • DOI

      10.1515/znb-2015-0155

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and optical properties of silyl-bridged H-shaped multi-thiophenes2015

    • Author(s)
      Akinobu Naka, Kazuki Neishi, Munemasa Nishimoto, Mitsuo Ishikawa
    • Journal Title

      Journal of Organometallic Chemistry

      Volume: 791 Pages: 169-174

    • DOI

      10.1016/j.jorganchem.2015.05.025

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Insight of pore tuning of Triazine-based nitrogen-rich organoalkoxysilanes membrane for water desalination2014

    • Author(s)
      Suhaina M. Ibrahim, Rong Xu, Hiroki Nagasawa, Akinobu Naka, Joji Ohshita, Tomohisa Yoshioka, Masakoto Kanezashi, and Toshinori Tsuru
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 45 Pages: 23759-23769

    • DOI

      10.1039/c4ra02772h

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Thermal reactions of pivaloyl- and adamantoyl(tert-butylethynyl)bis(trimethylsilyl)silane with 2,3-dimethylbutadiene and diphenylacetylene2014

    • Author(s)
      Akinobu Naka, Yusuke Hinada, Miho Nakata, Mitsuo Ishikawa
    • Journal Title

      Journal of Organometallic Chemistry

      Volume: 765 Pages: 53-58

    • DOI

      10.1016/j.jorganchem.2014.05.004

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] A closer look at the development and performance of organic-inorganic membranes using 2,4,6-tris[3-(triethoxysilyl)-1-propoxyl]-1,3,5-triazine (TTESPT)2014

    • Author(s)
      Suhaina M. Ibrahim, Rong Xu, Hiroki Nagasawa, Akinobu Naka, Joji Ohshita, Tomohisa Yoshioka, Masakoto Kanezashi, Toshinori Tsuru
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 24 Pages: 12404-12407

    • DOI

      10.1039/c3ra47736c

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] トリアジンをコアとしたペンタメチルジシラニル置換星型分子の合成と色素増2017

    • Author(s)
      野口 真央・仲 章伸
    • Organizer
      日本化学会春季年会(第97回)
    • Place of Presentation
      慶応大学日吉キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] 2,3-ビス(ジエチルシリル)チオフェンとアルキンの白金錯体触媒反応2017

    • Author(s)
      三原 貴司・仲 章伸
    • Organizer
      日本化学会春季年会(第97回)
    • Place of Presentation
      慶応大学日吉キャンパス
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis and Optical Properties of Silyl-bridged H-shaped Multi Thiophenes2015

    • Author(s)
      Akinobu Naka, Kazuki Neishi, Munemasa Nishimoto
    • Organizer
      The 5th Asian Silicon Symposium
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-10-19
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and Some Properties of Pentamethyldisilanyl-substituted Bis(bithienyl)benzothiadiazole2015

    • Author(s)
      藤島聖士・仲 章伸・大下浄治・大山陽介
    • Organizer
      第62回有機金属化学討論会
    • Place of Presentation
      関西大学千里山キャンパス(大阪府吹田市山手町3丁目3番35号
    • Year and Date
      2015-09-08
    • Related Report
      2015 Research-status Report
  • [Presentation] ペンタメチルジシラニル置換ビス(ビチエニル)ベンゾチアジアゾールの合成と性質2015

    • Author(s)
      藤島 聖士・仲 章伸
    • Organizer
      日本化学会春季年会(第95回)
    • Place of Presentation
      日本大学船橋キャンパス(千葉県・船橋市)
    • Year and Date
      2015-03-27
    • Related Report
      2014 Research-status Report
  • [Presentation] ケイ素置換H型化合物の合成とその光学的性質2014

    • Author(s)
      仲 章伸・大下 浄治
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス(長崎県・長崎市)
    • Year and Date
      2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Thermal Reactions of cis- and trans-3,4-Benzo-1,2-diisopropyl-1,2-dimethyl-1,2-disilacyclobut-3-ene2014

    • Author(s)
      Akinobu Naka, Junnai Ikadai, Jun Sakata, Mitsuo Ishikawa
    • Organizer
      The 17th International Symposium on Organosilicon Chemistry
    • Place of Presentation
      ベルリン工科大学(ドイツ)
    • Year and Date
      2014-08-06
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi