Development of molecular units based on grid type molecules with switching properties
| Project/Area Number |
26410065
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | University of Tsukuba |
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Principal Investigator |
SHIGA Takuya 筑波大学, 数理物質系, 助教 (00375411)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 分子素子 / 磁気化学 / 電気化学 / 超分子化学 / 多核錯体 / 混合原子価錯体 / グリッド型分子 / 双安定性 / 異種金属多核錯体 / 電気化学的性質 / 磁性 / 銅イオン / 鉄イオン / コバルトイオン |
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| Outline of Final Research Achievements |
Development of molecular units, which shows multistable electronic states controlled by electrochemical and magnetic field, is very important for future molecular electronics. In this work, [3x3] type grid molecules including copper and iron ions were synthesized and their magnetic and electrochemical properties were investigated. These complexes showed five-step reversible redox processes. Oxdized and reduced spieces were isolated and their optical and magnetic properties were studied.
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Report
(4 results)
Research Products
(64 results)
