• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of gadolinium(III) complexes with novel photo-functions

Research Project

Project/Area Number 26410074
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionKindai University (2016)
Kyushu University (2014-2015)

Principal Investigator

NAKAI Hidetaka  近畿大学, 理工学部, 准教授 (70377399)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords合成化学 / 光物性 / ランタニド
Outline of Final Research Achievements

In order to explore novel photo-functions of gadolinium(III) complexes, we have focused on the design and synthesis of new gadolinium(III) complexes. As a result, it was found that a gadolinium(III) complex with phenyl units shows room temperature phosphorescence in the crystalline state. We also clarified that the luminescence color can be controlled by doping trace amounts of organic compound at the time of crystal preparation. In addition, we have succeeded in developing new luminescent lanthanide(III) complexes with excellent oxygen response function by using the findings of photo-physical properties of newly synthesized gadolinium(III) complexes.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (13 results)

All 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 4 results) Presentation (8 results) (of which Int'l Joint Research: 1 results,  Invited: 2 results)

  • [Journal Article] An Oxygen-Sensitive Luminescent Dy(III) Complex2016

    • Author(s)
      Nakai, Hidetaka; Seo, Juncheol; Kitagawa, Kazuhiro; Goto, Takahiro; Matsumoto, Takahiro; Ogo, Seiji
    • Journal Title

      Dalton Trans.

      Volume: 45(23) Issue: 23 Pages: 9492-9496

    • DOI

      10.1039/c6dt01057a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Control of Lanthanide Coordination Environment: Synthesis, Structure, and Oxygen-Sensitive Luminescence Properties of an Eight-Coordinate Tb(III) Complex2016

    • Author(s)
      Nakai, Hidetaka; Seo, Juncheol; Kitagawa, Kazuhiro; Goto, Takahiro; Nonaka, Kyoshiro; Matsumoto, Takahiro; Ogo, Seiji
    • Journal Title

      Inorg. Chem.

      Volume: 55(13) Issue: 13 Pages: 6609-6615

    • DOI

      10.1021/acs.inorgchem.6b00800

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Gadolinium(III) Complex That Shows Room-Temperature Phosphorescence in the Crystalline State2016

    • Author(s)
      Nakai, Hidetaka; Kitagawa, Kazuhiro; Seo, Juncheol; Matsumoto, Takahiro; Ogo, Seiji
    • Journal Title

      Dalton Trans.

      Volume: 45(29) Issue: 29 Pages: 11620-11623

    • DOI

      10.1039/c6dt01303a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Macrocyclic Tetraamine bearing Four Phenol Groups: A New Class of Heptadentate Ligands To Provide an Oxygen-Sensitive Luminescent Tb(III) Complex with an Extendable Phenol Pendant Arm.2015

    • Author(s)
      Nakai, Hidetaka; Nonaka, Kyoshiro; Goto, Takahiro; Seo, Juncheol; Matsumoto, Takahiro; Ogo, Seiji
    • Journal Title

      Dalton Trans.

      Volume: 44 Issue: 24 Pages: 10923-10927

    • DOI

      10.1039/c5dt00816f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Highly Luminescent and Highly Oxygen-Sensitive Tb(III) Complex with a Tris-Aryloxide Functionalised 1,4,7-Triazacyclononane Ligand2014

    • Author(s)
      Nakai, Hidetaka; Goto, Takahiro; Kitagawa, Kazuhiro; Nonaka, Kyoshiro; Matsumoto, Takahiro; Ogo, Seiji
    • Journal Title

      Chem. Commun.

      Volume: 50 Issue: 99 Pages: 15737-15739

    • DOI

      10.1039/c4cc07717b

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Oxygen-Responsive Luminescent Lanthanide Complexes2016

    • Author(s)
      Nakai, Hidetaka; Ogo, Seiji
    • Organizer
      The 4th International Symposium for Young Chemists on Stimuli-Responsive Chemical Species for the Creation of Functional Molecules
    • Place of Presentation
      大阪大学(大阪府・吹田市)
    • Year and Date
      2016-12-12
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 刺激に応答する発光性ランタニド錯体2016

    • Author(s)
      中井 英隆
    • Organizer
      錯体化学若手の会 第55回近畿支部勉強会
    • Place of Presentation
      奈良女子大学(奈良県・奈良市)
    • Year and Date
      2016-11-19
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] An Oxygen Sensitive Luminescent Dysprosium(III) Complex2016

    • Author(s)
      Seo, Juncheol; Matsumoto, Takahiro; Ogo, Seiji; Nakai, Hidetaka
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都・目黒区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] A Gadolinium(III) Complex That Shows Room-temperature Phosphorescence in the Crystalline State2016

    • Author(s)
      Kitagawa, Kazuhiro; Matsumoto, Takahiro; Ogo, Seiji; Nakai, Hidetaka
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都・目黒区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] High-performance Oxygen Sensors based on Luminescent Lanthanide(III)2016

    • Author(s)
      Kuyama, Masafumi; Matsumoto, Takahiro; Ogo, Seiji; Nakai, Hidetaka
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都・目黒区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 酸素に応答する発光性テルビウム錯体の構造制御2015

    • Author(s)
      ソ ジュンチョル、野中 鏡士朗、谷田部 剛史、松本 崇弘、中井 英隆、小江 誠司
    • Organizer
      第65回錯体化学会討論会
    • Place of Presentation
      奈良女子大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] A Highly Luminescent and Highly Oxygen-Sensitive Terbium Complex2015

    • Author(s)
      Nakai, Hidetaka; Goto, Takahiro; Yatabe, Takeshi; Matsumoto; Ogo, Seiji
    • Organizer
      第65回錯体化学会討論会
    • Place of Presentation
      奈良女子大学
    • Year and Date
      2015-09-21
    • Related Report
      2015 Research-status Report
  • [Presentation] ガドリニウム錯体の発光性フォトクロミズム2014

    • Author(s)
      北川 和宏、松本 崇弘、野崎 浩一、小江 誠司、中井 英隆
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2020-01-20  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi