Photo-activation of molecules by d10 metal complexes having a long excited-state lifetime.
| Project/Area Number |
26410077
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Seikei University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
西川 道弘 成蹊大学, 理工学部, 助教 (60711885)
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| Research Collaborator |
Nishi Tatsuya
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 銅錯体 / 光化学反応 / 励起状態 / 二酸化炭素 / 発光 / 金属錯体 / 光化学 |
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| Outline of Final Research Achievements |
A series of copper compounds, which have a long lifetime energetic state (excited state), has been synthesized. Some metal compounds show reversible oxidation/reduction reactions. The reactions of these metal complexes and some molecules have been studied. No reaction was observed between the copper(I) compounds and dichloromethane, which is one of the typical organic chlorides. However reduction of carbon dioxide occurs using a copper complex in the presence of sacrificial reductant to give carbon monoxide. More efficient reduction of carbon dioxide was observed using a combination of the copper complexes and a nickel complex.
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Report
(4 results)
Research Products
(22 results)
