| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Outline of Final Research Achievements |
A new type of Ir(III) metalloligands containing an unsaturated nitrogen coordination site, [Ir(H)2(PPh3)2(pprd)]BF4 (1), [Ir(H)2(PPh3)2(Me2bpm)]BF4 (2), {[Ir(H)2(PPh3)2(Me2bpm)]PF6}4 (3), [Ir(H)2(PPh3)2(biqz)]BF4 (4) and [Ir(H)2(PPh3)2(biqz)]PF6 (5), have been prepared by the reactions of [Ir(H)2(PPh3)2(Me2CO)2]X (X = BF4 and PF6) with 4-(2-pyridyl)pyrimidine (pprd), 6,6'-dimethyl-4,4'-bipyrimidine (Me2bpm) and 4,4'-biquinazoline (biqz). Subsequently, three novel heterometallic Ag(I)-Ir(III) hydride coordination polymers, {[Ir(H)2(μ-pprd)(PPh3)2Ag(η-CF3COO)]BF4 }n (6), {[Ir(H)2(μ-biqz)(PPh3)2Ag2(μ-CF3COO)3] }n (7) and {[Ir(H)2(μ-Me2bpm)(PPh3)2Ag2(μ-CF3COO)2]PF6}n (8) have been reasonably constructed by the reactions of Ir(III) metalloligands 1, 3 and 5 with AgCF3COO.
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