Synthesis of molecule-based magnetic compounds based on the intermediate spin states
Project/Area Number |
26410080
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Kwansei Gakuin University |
Principal Investigator |
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Research Collaborator |
HANDA Makoto
SAKIYAMA Hiroshi
LUNEAU Dominique
GILLON Beatrice
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Project Period (FY) |
2014-04-01 – 2017-03-31
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Project Status |
Completed (Fiscal Year 2016)
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Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
|
Keywords | 金属錯体 / 磁性 / 超分子化学 / 分子性固体 / 磁気的性質 / 磁気異方性 / ルテニウム錯体 / コバルト錯体 / ニッケル錯体 / 二核錯体 / 四核錯体 / 多核錯体 / スピン状態 / ルテニウム二核錯体 / 鎖状錯体 |
Outline of Final Research Achievements |
New mononuclear, dinuclear, oligonuclear, and polynuclear metal complexes were prepared by the use of various organic chelate ligands for the first and second transition metal ions. The magnetic properties were investigated to observe the magnetic interactions and anisotropy effect. In cobalt systems, polarized neutron diffraction method was applied for mononuclear and dinuclear complex to elucidate the anisotropic effect on the magnetic properties. In nickel systems, dinuclear nickel complexes showing a ferromagnetic behavior and structural change with possible magnetic switching. In iron system, intermediate- and high-spin states were observed. In dinuclear ruthenium systems containing metal-metal bonding, a ferrimagnetic compound with Curie temperature of 80 K was found. In one-dimensional chain compounds of rhodium and molybdenum, adsorption properties were examined for nitrogen gas and the correlation with the crystal structures was investigated.
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Report
(4 results)
Research Products
(163 results)
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[Journal Article] Preparation, structure, and dynamic and electrochemical behaviors of dinuclear rhodium(I) complexes with bridging formamidinato ligands2016
Author(s)
Yuki Ide, Takahisa Ikeue, Yusuke Kataoka, Ryoko Inoue, Mikio Nakamura, Daisuke Yoshioka, Masahiro Mikuriya, Tatsuya Kawamoto, Makoto Handa
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Journal Title
J. Organomet. Chem.
Volume: 803
Pages: 92-103
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Journal Article] Polarized Neutron Diffraction as a tool for mapping the molecular magnetic anisotropy: local susceptibility tensors in Co2+ complexes2016
Author(s)
Karl Ridier, Beatrice Gillon, Arsen Gukasov, Gregory Chaboussant, Alain Cousson, Dominique Luneau, Ana Borta, Jean-Francois Jacquot, Ruben Checa, Yukako Chiba, Hiroshi Sakiyama, Masahiro Mikuriya
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Journal Title
Chem. Eur. J.
Volume: 22
Issue: 2
Pages: 724-735
DOI
Related Report
Peer Reviewed / Open Access / Int'l Joint Research
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[Journal Article] Double azido-bridged and mixed-bridged binuclear copper(II) and nickel(II) compounds with N,N, O-donor Schiff bases: Synthesis, structure, magnetic and DFT study2015
Author(s)
Partha Pratim Chakrabarty, Sanjib Giri, Dieter Schollmeyer, Hiroshi Sakiyama, Masahiro Mikuriya, Ananda Sarker, Sandip Saha
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Journal Title
Polyhedron
Volume: 89
Pages: 49-54
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC PROPERTY, AND N2-GAS-ADSORPTION PROPERTY OF CHAIN COMPOUNDS OF DINUCLEAR COPPER(II) PIVALATE WITH N,N’-BIDENTATE LIGANDS2015
Author(s)
Masahiro Mikuriya, Mari Yano, Naoya Takahashi, Daisuke Yoshioka, Hidekazu Tanaka, and Makoto Handa
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Journal Title
The Proceedings of the 2nd International Porous and Powder Materials Symposium and Exhibition PPM 2015, ed. by Sevgi Kilic Ozdemir, Mehmet Polat, and Metin Tanoglu, Uc Adim Printing House, Izmir
Volume: 2015
Pages: 72-76
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Journal Article] HYDROPHOBIC MICROPORE IN A CHAIN COMPOUND OF DINUCLEAR COPPER(II) BENZOATE WITH PYRAZINE―ADSORPTION PROPERTIES FOR N2, CCl4, H2O, CO2, AND CH3CN2015
Author(s)
Ryoji Nukada, Masahiro Mikuriya, Makoto Handa, and Hiromitsu Naono
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Journal Title
The Proceedings of the 2nd International Porous and Powder Materials Symposium and Exhibition PPM 2015, ed. by Sevgi Kilic Ozdemir, Mehmet Polat, and Metin Tanoglu, Uc Adim Printing House, Izmir
Volume: 2015
Pages: 77-81
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Journal Article] SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONANE2015
Author(s)
Masahiro Mikuriya, Mayu Hamagawa, Natsuki Tomioka, Daisuke Yoshioka, Naoko Uehara, Rika Fujimori, HirokiYamamoto, Yoshinari Ando, Shoichi Hori, Taro Kuriyama, Ryoji Mitsuhashi, and Makoto Handa, Daisuke Yoshioka, Ryoji Mitsuhashi, and Makoto Handa
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Journal Title
Chem. J. Moldova
Volume: 10(2)
Pages: 40-47
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Synthesis, structures, and properties of lantern-type dinuclear ruthenium(II,III) complexes cis-[Ru2{3,5-(CF3)2-pf}2(O2CMe)2Cl] and [Ru2{3,5-(CF3)2-pf}3(O2CMe)Cl], 3,5-(CF3)2-pf- = N,N'-bis[3,5-bis(trifluoromethyl)phenyl]formamidinate anion2015
Author(s)
Yasuko Harada, Takahisa Ikeue, Yuki Ide, Yuko Kimura, Ichiro Hiromitsu, Daisuke Yoshioka, Masahiro Mikuriya, Yusuke Kataoka, and Makoto Handa
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Journal Title
Inorg. Chim. Acta
Volume: 424
Pages: 186-193
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Journal Article] Dinuclear Cobalt(II) Complex with N,N,N’,N’-Tetrakis(3,5-dimethyl-1-pyrazolyl)methyl-1,4-phenylenediamine Having a Tetrahedral Coordination Geometry2015
Author(s)
Jongwan LIM, Young SON, Gimoon Gu, Sanghoon RYU, Daisuke YOSHIOKA, and Masahiro MIKURIYA
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Journal Title
X-ray Struc. Anal. Online
Volume: 31
Pages: 25-26
NAID
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] MIXED-VALENT TETRANUCLEAR MnIIMnIII3 COMPLEX WITH 1,3-DIAMINO-2-HYDROXYPROPANE-N,N’,N”,N”’-TETRAACETIC ACID2014
Author(s)
Masahiro Mikuriya, Nobuyuki Nagao, Satoshi Kurahashi, Atsushi Tabuchi, Seiki Tomohara, Motohiro Tsuboi, Daisuke Yoshioka, Hiroshi Sakiyama, and Akira Fuyuhiro
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Journal Title
Chem. J. Moldova
Volume: 9(1)
Pages: 100-105
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Synthesis and magnetic properties of an annulated dinuclear copper(II) phthalocyanine peripherally having 2,6-dimethylphenoxy substituents2014
Author(s)
Takahisa Ikeue, Naoko Sawada Naomi Matsumoto, Ayaka Miyazaki, Tamotsu Sugimori, Masayuki Koikawa, Ichiro Hiromitsu, Katsumi Yoshino, Masahiro Mikuriya, Yusuke Kataoka, Makoto Handa
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Journal Title
Journal of Porphyrins and Phthalocyanines
Volume: 18
Issue: 08n09
Pages: 708-714
DOI
Related Report
Peer Reviewed / Open Access
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[Presentation] Copper(II) benzoates with trimethoxy group2017
Author(s)
Masahiro Mikuriya, Chihiro Yamakawa, Daisuke Yoshioka, Ryoji Mitsuhashi, Hidekazu Tanaka, and Makoto Handa
Organizer
Fifth International Conference on Multifunctional, Hybrid and Nanomaterials
Place of Presentation
Lisbon (Portugal)
Year and Date
2017-03-06
Related Report
Int'l Joint Research
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[Presentation] Synthesis and Crystal Structures of Tetranuclear Oxidovanadium(IV) Complexes with 2,6-Bis(hydroxymethyl)-4-methylphenol2016
Author(s)
Masahiro Mikuriya, Masataka Omote, Masami Fukutani, Daisuke Yoshioka, Ryoji Mitsuhashi, Hidekazu Tanaka, Makoto Handa
Organizer
RIIS Symposium, Cooperative Symposium among Universities of Toulouse, Copenhagen, and Okayama
Place of Presentation
岡山大学理学部 (岡山県・岡山市)
Year and Date
2016-09-02
Related Report
Int'l Joint Research
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[Presentation] Some Cobalt Complexes with N,N’-Bis(2-hydroxy-3,5-dimethylbenzyl)-N,N’-dimethyl-1,2-ethanediamine2015
Author(s)
Masahiro Mikuriya, Miho Kiyohara, Yuki Katayama, Sinbi Inoue, Aki Sakaguchi, Daisuke Yoshioka, Naomi Kawata, Tsutomu Mizuta, Akira Fuyuhiro, Hiroshi Sakiyama, and Ryoji Mitsuhashi
Organizer
2015年日本化学会中国四国支部大会
Place of Presentation
岡山大学(岡山県岡山市)
Year and Date
2015-11-14
Related Report
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[Presentation] SYNTHESIS, CRYSTAL STRUCTURE, AND PROPERTIES OF COPPER(II) COMPLEXES WITH 1,4,7-TRIS(2-AMINOETHYL)-1,4,7-TRIAZACYCLONONADECANE2015
Author(s)
Masahiro Mikuriya, Mayu Hamagawa, Natsuki Tomioka, Daisuke Yoshioka, Naoko Uehara, Rika Fujimori, Hiroki Yamamoto, Yoshinari Ando, Shoichi Hori, Taro Kuriyama, Ryoji Mitsuhashi, and Makoto Handa
Organizer
The XVIII-th International Conference "Physical Methods in Coordination and Supramolecular Chemistry"
Place of Presentation
Chisinau, Moldova
Year and Date
2015-10-09
Related Report
Int'l Joint Research
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[Presentation] SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC PROPERTY, AND N2-ADSORPTION PROPERTY OF CHAIN COMPOUNDS OF DINUCLEAR COPPER(II) PIVALATE WITH N,N’-BIDENTATE LIGANDS2015
Author(s)
Masahiro Mikuriya, Mari Yano, Naoya Takahashi, Daisuke Yoshioka, Hidekazu Tanaka, and Makoto Handa
Organizer
The 2nd International Porous and Powder Materials Symposium and Exhibition PPM 2015
Place of Presentation
Cesme Izmir, Turky
Year and Date
2015-09-16
Related Report
Int'l Joint Research
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[Presentation] Nickel(II) complex with 1,4,7-tris(2-aminoethyl)-1,4,7-triazacyclononane2015
Author(s)
M. Mikuriya, M. Hamagawa, N. Tomioka, R. Fujimori, D. Yoshioka, S. Hori, T. Kuriyama, H. Sakiyama, M. Handa
Organizer
XXV. International Conference on Coordination and Bioinorganic Chemistry
Place of Presentation
Smolenice, Slovakia
Year and Date
2015-06-01
Related Report
Int'l Joint Research
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[Presentation] Iron(III)-Hydrazone Spin-Crossover Molecular Materials2014
Author(s)
Musa Shongwe, Qater Al-Nada Al-Kamali, Fatema Al-Ruqaishi, Maryam Al-Mahrezi, Michael Morris, Masahiro Mikuriya
Organizer
41st International Conference on Coordination Chemistry
Place of Presentation
Suntec Singapore Convention & Exhibition Centre, Singapore
Year and Date
2014-07-23
Related Report
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[Presentation] Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by Unsymmetrical Aminoalcohol Ligands2014
Author(s)
Takayuki Nakajima, Keiko Seto, Fumihiro Hosokawa, Isao Shimizu, Andreas Scheurer, Bunsho Kure, Takashi Kajiwara, Tomoaki Tanase, Masahiro Mikuriya
Organizer
41st International Conference on Coordination Chemistry
Place of Presentation
Suntec Singapore Convention & Exhibition Centre, Singapore
Year and Date
2014-07-21
Related Report
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[Presentation] MAGNETIC ANISOTROPY TENSORS OF Co2+ MOLECULAR COMPLEXES DETERMINED BY POLARIZED NEUTRON DIFFRACTION2014
Author(s)
Karl Ridier, Beatrice Gillon, Gregory Chaboussant, Dominique Luneau, Ana Borta, Olga Iasco, Arsen Gukasov, Yukako Ciba, Hiroshi Sakiyama, Masahiro Mikuriya, and Makoto Handa
Organizer
The 14th International Conference on Molecule-Based Magnets
Place of Presentation
Saint Petersburg, Russia
Year and Date
2014-07-07
Related Report
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[Presentation] Structural Characterization of Iron Complexes with Octakis(4-tert-butylphenyl)porphyrazine and Octakis(4-tert-butylphenyl)corrolazine2014
Author(s)
Satoshi Kurahashi, Takahisa Ikeue, Akira Fuyuhiro, Akira Ikezaki, Tamotsu Sugimori, Masashi Takahashi, Makoto Handa, Mikio Nakamura, Daisuke Yoshioka, Masahiro Mikuriya
Organizer
Eighth International Conference on Porphyrins and Phthalocyanines
Place of Presentation
Istanbul, Turkey
Year and Date
2014-06-24
Related Report
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[Presentation] MIXED-VALENT TETRANUCLEAR MANGANESE COMPLEX WITH 1,3-DIAMINO-2-HYDROXYPROPANE-N,N’,N”,N”’-TETRAACETIC ACID2014
Author(s)
Masahiro Mikuriya, Nobuyuki Nagao, Satoshi Kurahashi, Atsushi Tabuchi, Seiki Tomohara, Motohiro Tsuboi, Daisuke Yoshioka, Hiroshi Sakiyama, and Akira Fuyuhiro
Organizer
The International Conference dedicated to the 55th anniversary from the foundation of the Institute of Chemistry of the Academy of Sciences of Moldova
Place of Presentation
Chisinau, Moldova
Year and Date
2014-05-30
Related Report
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