Synthesis of electron donors containing fluorine atoms aimed to develop organic conducting materials
| Project/Area Number |
26410095
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Ehime University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
MISAKI Yohji 愛媛大学, 大学院理工学研究科, 教授 (90202340)
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| Research Collaborator |
MORI Shigeki
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 電気・磁気的機能 / 有機電子材料 / 電子供与体 / 分子性導体 / 超分子化学 / 双極子相互作用 / ハロゲン結合 |
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| Outline of Final Research Achievements |
Electron donors, in which functional groups with fluorine atoms are contained, were successfully synthesized. X-ray structure analysis revealed that the donor with strong F---F halogen bonds adopts planar structure due to effect on the lattice energy. These results demonstrated that the utilization of halogen bonds like F---F interactions strengthens the intermolecular interactions of molecular conductors.
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Report
(4 results)
Research Products
(90 results)
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[Journal Article] ynthesis, Structure, Optical, and Electrochemical Properties of Triple- and Quadruple-decker Co-facial Tetrathiafulvalene Arrays2016
Author(s)
Masashi Hasegawa, Ken-ichi Nakamura, Saki Tokunaga, Yumi Baba, Ryota Shiba, Takashi Shirahata, Yasuhiro Mazaki, Yohji Misaki
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Journal Title
Chemistry - A European Journal
Volume: 22
Issue: 29
Pages: 10090-10101
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Presentation] 環状型高次TTPオリゴマーの合成と性質2015
Author(s)
佐々木 彰紀, 木村 晴佳, 白旗 崇, 御崎 洋二
Organizer
第26回基礎有機化学討論会
Place of Presentation
愛媛大学城北キャンパス、松山大学カルフールホール（愛媛県松山市）
Year and Date
2015-09-24
Related Report
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[Presentation] Thermally induced mechanical effects in molecular conductors2015
Author(s)
Takashi Shirahata, Tetsuya Ito, Shinya Toki, Keita Shiratori, Shouhei Kumeta, Tadashi Kawamoto, Takehiko Mori, Yoshiaki Nakano, Hideki Yamochi, Yohji Misaki
Organizer
the 22nd International Conference on the Chemistry of the Organic Solid State
Place of Presentation
朱鷺メッセ（新潟、日本）
Year and Date
2015-07-12 – 2015-07-17
Related Report
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[Presentation] Thermally induced mechanical effects in molecular conductors2015
Author(s)
Takashi Shirahata, Tetsuya Ito, Shinya Toki, Keita Shiratori, Shouhei Kumeta, Tadashi Kawamoto, Takehiko Mori, Yoshiaki Nakano, Hideki Yamochi, Yohji Misaki
Organizer
The 22nd International Conference on the Chemistry of the Organic Solid State (ICCOSS XXII)
Place of Presentation
朱鷺メッセ（新潟県新潟市、日本）
Year and Date
2015-07-11
Related Report
Int'l Joint Research
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[Presentation] 高次TTPオリゴマーの合成と性質2015
Author(s)
佐々木 彰紀, 木村 晴佳, 白旗 崇, 御崎 洋二
Organizer
第82回日本分析化学会有機微量分析研究懇談会、第98回計測自動制御学会力学計測部会、第32回合同シンポジウム
Place of Presentation
愛媛大学南加記念ホール（愛媛県松山市）
Year and Date
2015-05-28
Related Report
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[Presentation] 高次融合型TTFダイマーの合成と性質2014
Author(s)
天野 祐介, 佐々木 彰紀, 木村 晴佳, 白旗 崇, 御崎 洋二
Organizer
第8回有機π電子系シンポジウム
Place of Presentation
ホテル龍登園（佐賀市）
Year and Date
2014-11-21 – 2014-11-22
Related Report
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