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Preparation of highly functionalized nanomaterials using micellar solution of functional molecules

Research Project

Project/Area Number 26410096
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionKagoshima University

Principal Investigator

Okamura Hiroaki  鹿児島大学, 理工学域理学系, 教授 (30244221)

Co-Investigator(Kenkyū-buntansha) 蔵脇 淳一  鹿児島大学, 理工学域理学系, 教授 (10170078)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywordsナノ粒子 / 機能性材料 / 金ナノ粒子 / 銀ナノ粒子 / 有機-無機複合材料
Outline of Final Research Achievements

A new preparation method of functionalized gold- or silver nanoparticles that are constructed with two or more different functionalized organic molecules has been achieved. The functionalized gold- or silver nanoparticels were obtained from a spontaneous reaction of mixed micelles of ω-functionalized alkylsulfanylaniline and a solution of chloroauric acid or silver nitrate. The size and stability of resulting nanoparticles were controlled by pH of the reaction media and chain length of alkysulfanylaniline, respectively.
The ratios of immobilized organic molecules on nanoparticles were determined by NMR studies, although the information about alignment of molecules on nanoparticles is not yet obtained.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (8 results)

All 2017 2015 2014

All Journal Article (2 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results,  Open Access: 1 results) Presentation (6 results)

  • [Journal Article] Total Synthesis of the Claimed Structure of (±)-Hyptinin and Structural Revision of Natural Hyptinin2017

    • Author(s)
      Kazuto Maeda, Toshiyuki Hamada, Satoaki Onitsuka, and Hiroaki Okamura
    • Journal Title

      Journal of Natural Products

      Volume: 80 Issue: 5 Pages: 1446-1449

    • DOI

      10.1021/acs.jnatprod.6b01116

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Asymmetric Synthesis of Ampelomin A and <i>ent</i>-Epiampelomin A2015

    • Author(s)
      Yuji Koyanagi, Toshiyuki Hamada, Tetsuo Iwagawa, and Hiroaki Okamura
    • Journal Title

      Journal of Oleo Science

      Volume: 64 Issue: 4 Pages: 449-454

    • DOI

      10.5650/jos.ess14212

    • NAID

      130005061329

    • ISSN
      1345-8957, 1347-3352
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] 抗ATL活性を有するリグナンhyptosideの全合成研究2017

    • Author(s)
      前田和人, 鬼束聡明, 濱田季之, 岡村浩昭
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶應大学(神奈川県・横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] アミノ基を集積した金ナノ粒子の調製法の開発2015

    • Author(s)
      脇田 薫, 濵田 季之, 鬼束 聡明, 蔵脇 淳一, 岡村 浩昭
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県・鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 樹状分子で修飾された金ナノ粒子の簡便な調製法の開発2015

    • Author(s)
      吉海 直志, 鬼束 聡明, 濵田 季之, 蔵脇 淳一, 岡村 浩昭
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県・鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 糖を集積化した金ナノ粒子の簡便調製法の開発2015

    • Author(s)
      森山 洋平, 濱田 季之, 鬼束 聡明, 蔵脇 淳一, 岡村 浩昭
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県・鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 両親媒性アルキルスルファニルアニリン誘導体を用いた金属ナノ粒子の調製法の開発2015

    • Author(s)
      竹之下 優斗, 濵田 季之, 鬼束 聡明, 蔵脇 淳一, 岡村 浩昭
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学(鹿児島県・鹿児島市)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Research-status Report
  • [Presentation] pontaneous Formation of Gold Glyconanoparticles by Direct Reaction of ω-Glycosilated Alkylsulfanylanilines and HAuCl42014

    • Author(s)
      Ryuich Takegawa, Satoaki Onitsuka, Toshiyuki Hamada, Jun-ich Kurawaki, Hiroaki Okamura
    • Organizer
      17th International Symposium on Small Particles and Inorganic Clusters
    • Place of Presentation
      九州大学(福岡県・福岡市)
    • Year and Date
      2014-09-07 – 2014-09-12
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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