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Exclusion of impurity particles in charged colloidal crystals

Research Project

Project/Area Number 26410097
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionNagoya City University

Principal Investigator

Toyotama Akiko  名古屋市立大学, 大学院薬学研究科, 講師 (50453072)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsコロイド / コロイド結晶 / 結晶成長 / 不純物 / 金微粒子 / 荷電コロイド / 不純物排除 / その場観察
Outline of Final Research Achievements

Crystal defects have significant influence on properties of various materials such as melting point and electric conductivity. Therefore control the defect is quite important technique. The defect often caused by contamination due to impurity. Though many models of exclusion of impurity are proposed, it is difficult to observe that exclusion process directly.And, the colloidal crystallization has extensively been studied as models to study phase transition in general1 over the past few decades.
Here, we report the behavior of "impurity" particles, which were added to the charged colloidal crystals. In the case of the impurity particles are much smaller than the main component, they were present in the stable area around the particles which form the crystal structure. Despite impurities were excluded from the crystals during the homogeneous crystallization, crystal grain growth, and unidirectional crystallization processes when they have larger diameter.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (19 results)

All 2017 2016 2015

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Open Access: 2 results,  Acknowledgement Compliant: 1 results) Presentation (14 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Thermoreversible Crystallization of Charged Colloids due to Adsorption/Desorption of Ionic Surfactants2016

    • Author(s)
      A. Murakado, A. Toyotama, M. Yamamoto, R. Nagano, T. Okuzono, and J. Yamanaka
    • Journal Title

      J. Colloid Interf. Sci.

      Volume: 465 Pages: 200-207

    • DOI

      10.1016/j.jcis.2015.11.064

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spontaneous Formation of Eutectic Crystal Structures in Binary and Ternary Charged Colloids due to Depletion Attraction.2016

    • Author(s)
      A. Toyotama, T. Okuzono, and J. Yamanaka
    • Journal Title

      Sci. Rep.

      Volume: 6 Issue: 1 Pages: 23292-23292

    • DOI

      10.1038/srep23292

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Gelled colloidal crystals as tunable optical filters for spectrophotometers2016

    • Author(s)
      Y. Sugao, S. Onda, A. Toyotama, Y. Takiguchi, T. Sawada, S. Hara, S. Nishikawa, and J. Yamanaka
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55 Issue: 8 Pages: 087301-087301

    • DOI

      10.7567/jjap.55.087301

    • NAID

      210000146958

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption, Desorption, Surface Diffusion, Lattice Defect Formation, and Kink Incorporation Processes of Particles on Growth Interfaces of Colloidal Crystals with Attractive Interactions2016

    • Author(s)
      Yoshihisa Suzuki, Yoshiaki Hattori, Jun Nozawa, Satoshi Uda, Akiko Toyotama and Junpei Yamanaka
    • Journal Title

      Crystals

      Volume: 6 Issue: 7 Pages: 80-80

    • DOI

      10.3390/cryst6070080

    • NAID

      120006941117

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Numerical study of cluster formation in binary charged colloids.,2016

    • Author(s)
      J. NozaT. Okuzono, K. Odai, T. Masuda, A. Toyotama, and J. Yamanaka,
    • Journal Title

      Phys. Rev. E

      Volume: 94 Issue: 1 Pages: 012609-012609

    • DOI

      10.1103/physreve.94.012609

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Presentation] 不均一な濃度場中の荷電コロイドダイナミクス2017

    • Author(s)
      関友崇,奥薗透,豊玉彰子,山中淳平
    • Organizer
      日本物理学会 第72回年次大会
    • Place of Presentation
      大阪府
    • Related Report
      2016 Annual Research Report
  • [Presentation] Spontaneous Formation of Eutectic Crystal Structures in Binary and Ternary Charged Colloids due to Depletion Attraction2016

    • Author(s)
      A.TOYOTAMA, J. YAMANAKA, T. OKUZONO
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy(ICCGE-18)
    • Place of Presentation
      名古屋
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Gel immobilized colloidal crystals and their application for strain sensing2016

    • Author(s)
      S.Nishikawa, A.Toyotama,T.Okuzono, and J.Yamanaka
    • Organizer
      The 18th International Conference on Crystal Growth and Epitaxy(ICCGE-18)
    • Place of Presentation
      名古屋
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 枯渇引力によるコロイド共晶構造の形成2016

    • Author(s)
      豊玉彰子, 奥薗透, 山中淳平
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道
    • Related Report
      2016 Annual Research Report
  • [Presentation] 荷電コロイドの結晶化に対する粒子-壁面間の相互作用の影響2016

    • Author(s)
      西川 卓, 豊玉 彰子, 奥薗 透, 山中 淳平
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道
    • Related Report
      2016 Annual Research Report
  • [Presentation] 低誘電率媒体中での荷電コロイドの分散安定性2016

    • Author(s)
      深谷 奈央, 豊玉 彰子, 奥薗 透, 山中 淳平
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオン性界面活性剤の吸着挙動を利用した荷電コロイドの温度誘起結晶化2016

    • Author(s)
      青山 柚里奈, 富田 友紀, 豊玉 彰子, 奥薗 透, 山中 淳平
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道
    • Related Report
      2016 Annual Research Report
  • [Presentation] 荷電高分子ヒドロゲルへの同符号荷電コロイド粒子の吸着2016

    • Author(s)
      佐藤 直子, 豊玉 彰子, 奥薗 透, 山中 淳平
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道
    • Related Report
      2016 Annual Research Report
  • [Presentation] 塩基拡散中の荷電コロイドダイナミクス2016

    • Author(s)
      関友崇,奥薗透,豊玉彰子,山中淳平
    • Organizer
      第67回コロイドおよび界面化学討論会
    • Place of Presentation
      北海道
    • Related Report
      2016 Annual Research Report
  • [Presentation] 荷電コロイド結晶中の不純物粒子の拡散と欠陥2015

    • Author(s)
      菅生行紘,豊玉彰子,奥薗透,野澤純,藤原航三,宇田聡,山中淳平
    • Organizer
      第45回結晶成長国内会議
    • Place of Presentation
      北海道大学 (北海道)
    • Year and Date
      2015-10-20
    • Related Report
      2015 Research-status Report
  • [Presentation] 枯渇引力によるコロイド共晶構造の自発的形成2015

    • Author(s)
      豊玉彰子,松野宏美, 奥薗透,山中淳平
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学 (鹿児島)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Presentation] 不均一な塩基濃度場における荷電コロイドダイナミクス2015

    • Author(s)
      関友崇,奥薗透,豊玉彰子,山中淳平
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学 (鹿児島)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Presentation] 荷電コロイド粒子のクラスター形成と構造制御2015

    • Author(s)
      岡地真奈美・中村友紀・豊玉彰子・奥薗透・山中淳平
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学 (鹿児島)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report
  • [Presentation] 低誘電率媒体中での荷電コロイドの分散安定性2015

    • Author(s)
      深谷奈央・豊玉彰子・奥薗透・山中淳平
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学 (鹿児島)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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