Development of High-Dimensional Argentivorous Molecules
Project/Area Number |
26410100
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Multi-year Fund |
Section | 一般 |
Research Field |
Functional solid state chemistry
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Research Institution | Toho University |
Principal Investigator |
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Research Collaborator |
IKEDA Mari
KUWAHARA Shunsuke
LEE Shim Sung
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Project Period (FY) |
2014-04-01 – 2017-03-31
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Project Status |
Completed (Fiscal Year 2016)
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Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
|
Keywords | サイクレン / 銀食い分子 / 銀イオン / 銀ーパイ相互作用 / アロステリック効果 / 不斉誘起 / アロステリック / クリプタンド / 超分子 |
Outline of Final Research Achievements |
To develop high-dimensional argentivorous molecules, three kinds of molecules have been prepared. (1) Bis(tetra-armed cyclen)s were prepared, and the thermodynamic parameters of their Ag+ complexes were measured.(2) A mixture system of chiral and achiral argentivorous molecules showed asymmetric inductions.(3) Cyclen-based cylindrical cryptand which has dietyleneoxy linkers showed an allosteric effect.
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Report
(4 results)
Research Products
(58 results)
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[Journal Article] A Ditopic O4S2-Macrocycle and Its Hard, Soft, and Hard/Soft Metal Complexes Exhibiting Endo-, Exo-, or Endo/Exocyclic Coordination: Synthesis, Crystal Structures, NMR Titration, and Physical Properties2014
Author(s)
H. Ryu, K. Park, M. Ikeda, Y. Habata, and S. S. Lee
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Journal Title
Inorg. Chem.
Volume: 53
Issue: 8
Pages: 40294038-40294038
DOI
Related Report
Peer Reviewed
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[Presentation] Dynamics of Bis(tetra-armed cyclen)2017
Author(s)
M. Iwase, M. Ikeda, C. Kachi-Terajima, S. Kuwahara, Y. Habata
Organizer
2017 GNU-Toho Joint Symposium on Advanced Chemical Science
Place of Presentation
Gyeongsang National Unviersity (Jinju, Korea)
Year and Date
2017-03-10
Related Report
Int'l Joint Research / Invited
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