| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Outline of Final Research Achievements |
Recently, much attention has been paid to the development of the functional polymer materials. In this study, we have introduced the new class of functional polymers by the use of spiroborate molecular connecting modules. Successive guest-containing tubular polymer was prepared by the olefin metathesis polymerization of tris(spiroborate) twin bowl bearing homoallyl groups after the formation of supramolecular polymer. The cationic iridium(III) complexes were topologically fixed inside the polymer to form a peapod-like structure. The structure of obtained peapod polymer was evaluated by SEC, ICP-AES, DLS analyses, and AFM observation.
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