Preparation of supramolecular peapod polymer composed of spiroborate molecular connecting modules
| Project/Area Number |
26410103
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Konan University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | ピーポッドポリマー / 超分子ポリマー / スピロボラート / 分子接合素子 / 超分子 / トポロジカルポリマー / 中空型ポリマー |
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| Outline of Final Research Achievements |
Recently, much attention has been paid to the development of the functional polymer materials. In this study, we have introduced the new class of functional polymers by the use of spiroborate molecular connecting modules. Successive guest-containing tubular polymer was prepared by the olefin metathesis polymerization of tris(spiroborate) twin bowl bearing homoallyl groups after the formation of supramolecular polymer. The cationic iridium(III) complexes were topologically fixed inside the polymer to form a peapod-like structure. The structure of obtained peapod polymer was evaluated by SEC, ICP-AES, DLS analyses, and AFM observation.
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Report
(4 results)
Research Products
(46 results)
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[Journal Article] Coordination structure and extraction behavior of a silver ion with N-substituted-9-aza-3,6,12,15-tetrathiaheptadecanes: significant effect of Ph-C-N framework on the extractability2016
Author(s)
Satoshi Iwatsuki, Atsushi Ichiyama, Syogo Tanooka, Mari Toyama, Kosuke Katagiri, Masatoshi Kawahata, Kentaro Yamaguchi, Hiroshi Danjo, Kenji Chayama
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Journal Title
Dalton Trans.
Volume: 45
Issue: 31
Pages: 12548-12558
DOI
Related Report
Peer Reviewed
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