Development of metallic nanoparticle catalysts with dynamic molecular interface
| Project/Area Number |
26410118
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 金クラスター / 触媒 / デンドリマー / 反応場 / 動的挙動 / 金属ナノ粒子 |
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| Outline of Final Research Achievements |
We synthesized surface-functionalized gold clusters with precise molecular formula using peptide dendron thiolates as surface protecting agents which construct multiple hydrogen bond-based reaction field. The peptide dendron thiolate-functionalized gold clusters was found to facilitate several photocatalytic oxidation reactions through the reaction field effect of peptide dendrons by visible light irradiation.
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Report
(4 results)
Research Products
(31 results)
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[Journal Article] Investigation of Organoiron Catalysis in Kumada-Tamao-Corriu-Type Cross-Coupling Reaction Assisted by Solution-Phase X-ray Absorption Spectroscopy2015
Author(s)
Takaya, H.; Nakajima, S.; Nakagawa, N.; Isozaki, K.; Iwamoto, T.; Imayoshi, R.; Gower, N.; Adak, L.; Hatakeyama, T.; Honma, T.; Takagi, M.; Sunada, Y.; Nagashima, H.; Hashizume, D.; Takahashi, O.; Nakamura, M.
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Journal Title
Bull. Chem. Soc. Jpn.
Volume: 88
Issue: 3
Pages: 410-418
DOI
NAID
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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[Journal Article] Square-centimeter-scale 2D-arrays of Au@Ag core-shell nanoparticles towards practical SERS substrates with enhancement factor of 10^72014
Author(s)
Francesca Pincella, Yeji Song, Takao Ochiai, Katsuhiro Isozaki, Kenji Sakamoto, and Kazushi Miki
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Journal Title
Francesca Pincella, Yeji Song, Takao Ochiai, Katsuhiro Isozaki, Kenji Sakamoto, and Kazushi Miki
Volume: 605-606
Pages: 115-120
DOI
Related Report
Peer Reviewed / Open Access / Acknowledgement Compliant
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