| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Outline of Final Research Achievements |
In this research, we aimed at the establishment of the new transformation reactions based on understanding the specific features of silicon-containing unsaturated organic molecules by means of the mechanistic and experimental studies on the Lewis acid-catalyzed selective cycloaddition reactions using silicon-containing unsaturated organic molecules. As a result, we have developed some new selective synthetic methods using the effect of silicon substituents. The obtained insights on the effect of silicon substitution towards the synthetic utilities would cause further developments and applications of organic reactions using heteroatom-based unsaturated molecules.
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