Construction of supramolecular structures based on the stepwise radial complexation
| Project/Area Number |
26410128
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Keywords | 樹状高分子 / 超分子ポリマー / フェニルアゾメチン / トリフェニルメチリウム |
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| Outline of Final Research Achievements |
In this research, we have developed a supramolecular structures that have additional coordination sites for Lewis acid binding. A linear molecule that has triphenylmethylium cation (Lewis acid) at both ends were synthesized and used as a linker to bind the dendrimers. By mixing 2-substituted 4th generation phenylazomethine dendrimer and the linker, a liner supramolecular structure was obtained. On the other hand, by mixing four substituted phenylazomethine with the linker, a 2-dimensional sheet-like suparamolecular structure was obtained. There supramolecular structures could bind additional Lewis acid such as SnCl2 to its excess binding sites.
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Report
(4 results)
Research Products
(19 results)
