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Synthesis of ionic liquid-type two dimensional supramolecules and their evaluation as solid electrolytes

Research Project

Project/Area Number 26410140
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer chemistry
Research InstitutionSophia University

Principal Investigator

FUJITA Masahiro  上智大学, 理工学部, 准教授 (50433793)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords高分子電解質 / イオン液体 / 双性イオン / リチウムイオン電池 / 機能性高分子 / 導電性高分子 / 固体電解質 / リチウムイオン伝導体
Outline of Final Research Achievements

We prepared supramolecular electrolytes composed of boroxine compounds synthesized by dehydration condensation of 1,4-benzenediboronic acid in the presence of oligo-ether electrolytes with diamines on the chain ends. Lithium salts were mixed with the supramolecular electrolytes, and basic and electrochemical properties of complexes were evaluated. Supramolecular complexes were superior to formability and were obtained as transparent films. We confirmed that supramolecular electrolytes act as lithium-ion conductors. New solid polymer electrolytes were developed.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (42 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (6 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 6 results,  Acknowledgement Compliant: 6 results) Presentation (32 results) (of which Int'l Joint Research: 7 results,  Invited: 6 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] Deakin University(Australia)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Deakin University(Australia)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Synthesis and evaluation of a novel pyrrolidinium-based zwitterionic additive with an ether side chain for ionic liquid electrolytes in high-voltage lithium-ion batteries2017

    • Author(s)
      S. Horiuchi, H. Zhu, M. Fosyth, Y. Takeoka, M. Rikukawa, M. Yoshizawa-Fujita
    • Journal Title

      Electrochimica Acta

      Volume: 241 Pages: 272-280

    • DOI

      10.1016/j.electacta.2017.04.165

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of a pyrrolidinium zwitterion on charge/discharge cycle properties of Li/LiCoO2 and graphite/Li cells containing an ionic liquid electrolyte2016

    • Author(s)
      S. Yamaguchi, M. Yoshizawa-Fujita, Y. Takeoka, M. Rikukawa
    • Journal Title

      Journal of Power Sources

      Volume: 331 Pages: 308-314

    • DOI

      10.1016/j.jpowsour.2016.09.058

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Physicochemical and electrochemical properties of N-methyl-N-methoxymethylpyrrolidinium bis(fluorosulfonyl)amide and its lithium salt composites2016

    • Author(s)
      S. Horiuchi, M. Yoshizawa-Fujita, Y. Takeoka, M. Rikukawa
    • Journal Title

      Journal of Power Sources

      Volume: 325 Pages: 637-640

    • DOI

      10.1016/j.jpowsour.2016.06.087

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Improvement of charge/discharge properties of oligoether electrolytes by zwitterions with an attached cyano group for use in lithium-ion secondary batteries2015

    • Author(s)
      S. Yamaguchi, M. Yoshizawa-Fujita, H. Zhu, M. Forsyth, Y. Takeoka, M. Rikukawa
    • Journal Title

      Electrochimica Acta

      Volume: 186 Pages: 471-477

    • DOI

      10.1016/j.electacta.2015.11.018

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of Random Copolymers Containing Zwitterions and Their Evaluation as Electrolyte Materials2015

    • Author(s)
      藤田正博,島田健佑,竹岡裕子,陸川政弘
    • Journal Title

      KOBUNSHI RONBUNSHU

      Volume: 72 Issue: 10 Pages: 624-629

    • DOI

      10.1295/koron.2015-0028

    • NAID

      130005104175

    • ISSN
      0386-2186, 1881-5685
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of zwitterions on electrochemical properties of oligoether-based electrolytes2015

    • Author(s)
      M. Suematsu, M. Yoshizawa-Fujita, H. Zhu, M. Forsyth, Y. Takeoka, M. Rikukawa
    • Journal Title

      Electrochimica Acta

      Volume: 印刷中 Pages: 209-213

    • DOI

      10.1016/j.electacta.2014.12.067

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ポリベタイン型高分子電解質の合成と評価(I)-ジブロック共重合体の合成-2017

    • Author(s)
      石井順、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第66回高分子学会年次大会
    • Place of Presentation
      幕張メッセ(千葉県・千葉市美浜区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] イオン液体/双性イオン複合体を用いたLiイオン伝導体の開発(I)-双性イオンのスペーサー長の効果-2017

    • Author(s)
      山田大雅、福間大介、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京・南大沢キャンパス(東京都・八王子市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 二次電池用電解質としてのイオン液体の合成と評価(VI)-充放電特性への双性イオンの添加効果-2016

    • Author(s)
      堀内俊輔、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学吹田キャンパス
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] 二次電池用電解質としてのイオン液体の合成と評価(VII)-高電圧下における双性イオンの効果-2016

    • Author(s)
      堀内俊輔、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第7回イオン液体討論会
    • Place of Presentation
      金沢文化ホール(石川県・金沢市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] ボロキシンを架橋点とする超分子電解質の合成と評価(I)-ジアミン誘導体を用いたゲルの作製-2016

    • Author(s)
      堀内俊輔、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学・横浜キャンパス(神奈川県・横浜市神奈川区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Improvement of charge/discharge properties of cells with various electrolyte materials by zwitterion additives2016

    • Author(s)
      Masahiro Yoshizawa-Fujita
    • Organizer
      15th International Symposium on Polymer Electrolytes
    • Place of Presentation
      Uppsala Concert & Congress in Uppsala, Sweden
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポリベタイン型イオンゲル電解質の合成と評価(I)-オリゴエーテル共重合体のイオン伝導性-2016

    • Author(s)
      石井順、藤田正博、竹岡裕子、陸川正博
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都・江戸川区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Improvement of electrochemical properties of electrolyte materials by addition of liquid zwitterions2015

    • Author(s)
      M. Yoshizawa-Fujita, S. Yamaguchi, Y. Takeoka, M. Rikukawa
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and characterization of ionic liquids as electrolytes for battery applications (III)-Investigation of charge and discharge characteristics-2015

    • Author(s)
      S. Horiuchi, M. Yoshizawa-Fujita, Y. Takeoka, M. Rikukawa
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 双性イオンの合成と電解質としての評価(IX)-イオン液体系電解質のサイクル特性-2015

    • Author(s)
      山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜情報文化センター
    • Year and Date
      2015-12-08
    • Related Report
      2015 Research-status Report
  • [Presentation] 双性イオンの合成と電解質としての評価(VIII)-正極/電解質界面の検討-2015

    • Author(s)
      山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県産業労働センター
    • Year and Date
      2015-11-13
    • Related Report
      2015 Research-status Report
  • [Presentation] 二次電池用電解質としてのイオン液体の合成と評価(V)-双性イオンの添加効果-2015

    • Author(s)
      堀内俊輔、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス
    • Year and Date
      2015-10-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 双性イオンの合成と電解質としての評価(VII)-グラファイト負極への適用-2015

    • Author(s)
      山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学今出川キャンパス
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
  • [Presentation] 二次電池用電解質としてのイオン液体の合成と評価(IV)-Li塩の解離状態-2015

    • Author(s)
      堀内俊輔、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Presentation] 双性イオンの合成と電解質としての評価(VI)-有機電解液への添加効果-2015

    • Author(s)
      山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      電気化学秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Presentation] Synthesis of zwitterions and evaluation as electrolyte (V)-Improvement of cycle stability-2015

    • Author(s)
      S. Yamaguchi, M. Yoshizawa-Fujita, Y. Takeoka, M. Rikukawa
    • Organizer
      6th International Congress on Ionic Liquids
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-06-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Synthesis and characterization of ionic liquids as electrolytes for battery applications (II)-Investigation of electrochemical stability-2015

    • Author(s)
      S. Horiuchi, M. Yoshizawa-Fujita, Y. Takeoka, M. Rikukawa
    • Organizer
      6th International Congress on Ionic Liquids
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-06-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Liquid zwitterion effect in oligoether-based electrolytes2015

    • Author(s)
      M. Yoshizawa-Fujita
    • Organizer
      6th International Congress on Ionic Liquids
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-06-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of ionic-liquid derivatives for battery applications2015

    • Author(s)
      M. Yoshizawa-Fujita
    • Organizer
      International Conference on Frontiers in Materials Processing Applications, Research & Tehcnology
    • Place of Presentation
      Hyderabad, India
    • Year and Date
      2015-06-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] リチウムイオン電池用電解質としてのイオン液体の合成と評価(I)-側鎖構造の効果-2015

    • Author(s)
      堀内俊輔、末松三豪、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-29
    • Related Report
      2015 Research-status Report
  • [Presentation] 双性イオンの合成と電解質としての評価(Ⅳ)-充放電特性の評価-2015

    • Author(s)
      山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第82回電気化学会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-15
    • Related Report
      2014 Research-status Report
  • [Presentation] イオン液体と高分子からなるフレキシブル固体電解質の創出2014

    • Author(s)
      藤田正博
    • Organizer
      第87回千葉地域活動高分子研究交流講演会
    • Place of Presentation
      日本大学生産工学部津田沼校舎
    • Year and Date
      2014-11-11
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Development of functional ionic liquids for biomass processing and battery research2014

    • Author(s)
      M. Yoshizawa-Fujita
    • Organizer
      Sophia Symposium on Ionic Liquids
    • Place of Presentation
      上智大学四谷キャンパス
    • Year and Date
      2014-11-01
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 双性イオンの合成と電解質としての評価(XI)-電気化学的安定性への効果-2014

    • Author(s)
      末松三豪、山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第5回イオン液体討論会
    • Place of Presentation
      横浜シンポジア
    • Year and Date
      2014-10-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 双性イオンの合成と評価(Ⅲ)-カチオン構造の影響 -カチオン構造の影響 -2014

    • Author(s)
      山口征太郎、末松三豪、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第5回イオン液体討論会
    • Place of Presentation
      横浜シンポジア
    • Year and Date
      2014-10-28
    • Related Report
      2014 Research-status Report
  • [Presentation] 双性イオンの合成と電解質としての評価(VIII)-正極材の検討-2014

    • Author(s)
      末松三豪、山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 双性イオンの合成と電解質としての評価(VII)-リチウム伝導性の評価-2014

    • Author(s)
      末松三豪、山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 双性イオンの合成と電解質としての評価(Ⅱ)-エーテル鎖の効果-2014

    • Author(s)
      山口征太郎、藤田正博、竹岡裕子、陸川政弘
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学文教キャンパス
    • Year and Date
      2014-09-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Design of soft electrolytes as lithium ion transport materials2014

    • Author(s)
      M. Yoshizawa-Fujita
    • Organizer
      14th International Symposium on Polymer Electrolytes
    • Place of Presentation
      Geelong, Australia
    • Year and Date
      2014-08-26
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Liquid zwitterion effect in PEO-based electrolytes-electrochemical properties and conduction mechanism-2014

    • Author(s)
      M. Suematsu, M. Yoshizawa-Fujita, Y. Takeoka, M. Rikukawa
    • Organizer
      14th International Symposium on Polymer Electrolytes
    • Place of Presentation
      Geelong, Australia
    • Year and Date
      2014-08-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Zwitterions with cyano-group as new electrolyte materials2014

    • Author(s)
      S. Yamaguchi, M. Yoshizawa-Fujita, Y. Takeoka, M. Rikukawa
    • Organizer
      14th International Symposium on Polymer Electrolytes
    • Place of Presentation
      Geelong, Australia
    • Year and Date
      2014-08-24
    • Related Report
      2014 Research-status Report
  • [Presentation] Liquid zwitterion as a new electrolyte material2014

    • Author(s)
      M. Yoshizawa-Fujita
    • Organizer
      1st JAIST Japan-India Symposium on Automotive Technologies
    • Place of Presentation
      北陸先端科学技術大学院大学
    • Year and Date
      2014-08-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Patent(Industrial Property Rights)] 超分子複合体の製造方法、超分子複合体及び電解質2017

    • Inventor(s)
      藤田正博、陸川政弘、堀内俊輔
    • Industrial Property Rights Holder
      上智学院
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-022226
    • Filing Date
      2017-02-09
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 電解質組成物、二次電池、及び二次電池の使用方法2015

    • Inventor(s)
      山口征太郎、宮田壮、藤田正博、陸川政弘
    • Industrial Property Rights Holder
      リンテック、上智学院
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-170273
    • Filing Date
      2015-08-15
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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