| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Outline of Final Research Achievements |
There are urgent and strong demands for the development of useful kinetic analysis method in a variety of research fields. The aim of this research program is the construction of “extended” capillary electrophoretic reactor (CER), which is based on the basic concept using capillary electrophoretic separation process as “reactor” for the reaction of complexes. Zone-passing mode CER (ZP-CER) was developed as a novel methodology for the kinetic analysis of the formation reaction of a metal complex. The scope of the application of ZP-CER was extended to the kinetic analysis of the formation reaction of a nonmetal complex, and hydrolysis of a dye. A temperature variable type ZP-CER was also developed, and was successfully applied to the acquisition of the activation parameters of the formation reaction of a nonmetal complex.
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