Development of extended capillary electrophoretic reactor as novel methodology for kinetic analysis of chemical reactions in solution
| Project/Area Number |
26410146
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | University of Fukui |
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Principal Investigator |
TAKAKAHSI Toru 福井大学, 学術研究院工学系部門, 准教授 (30361166)
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| Co-Investigator(Kenkyū-buntansha) |
壹岐 伸彦 東北大学, 環境科学研究科, 教授 (50282108)
星野 仁 東北大学, 環境科学研究科, 教授 (20124620)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 反応速度解析法 / キャピラリー電気泳動 / 生成反応速度定数 / 活性化パラメーター / 金属錯体 / 反応速度論解析 / 錯体 / 生成反応速度解析 / フタレイン系色素 / 非金属錯体 / キャピラリー電気泳動反応器 / 配位子置換反応速度定数 |
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| Outline of Final Research Achievements |
There are urgent and strong demands for the development of useful kinetic analysis method in a variety of research fields. The aim of this research program is the construction of “extended” capillary electrophoretic reactor (CER), which is based on the basic concept using capillary electrophoretic separation process as “reactor” for the reaction of complexes. Zone-passing mode CER (ZP-CER) was developed as a novel methodology for the kinetic analysis of the formation reaction of a metal complex. The scope of the application of ZP-CER was extended to the kinetic analysis of the formation reaction of a nonmetal complex, and hydrolysis of a dye. A temperature variable type ZP-CER was also developed, and was successfully applied to the acquisition of the activation parameters of the formation reaction of a nonmetal complex.
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Report
(4 results)
Research Products
(9 results)
