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Development of peptide-grafted silica-based column for selective recovery of rare metal ions

Research Project

Project/Area Number 26410196
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionThe University of Shiga Prefecture

Principal Investigator

Tanimoto Satoshi  滋賀県立大学, 工学部, 准教授 (50303350)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsペプチド / 微粒子 / 貴金属 / レアメタル / イオン / 選択吸着 / カラム / 金属イオン / 選択捕集 / 吸着
Outline of Final Research Achievements

Peptides were immobilized on the surface of the silica particles for column packing material, and the peptide-modified particles were used as metal ions scavenger. The peptide used in this study were polylysine and polyglutamic acid, which have ionic side chain groups. Adsorption experiments of noble metal ions with the peptide-modified silica particles revealed that the particles showed high adsorption selectivity for gold ion. Therefore, the column filled with the peptide-modified silica particles may perform gold ion selectivity from a mixed ions solution. We also estimated desorption from the particles after the metal ion capturing, and the desorption efficiency was clarified to be practical enough.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (9 results)

All 2017 2016 2015 2014 Other

All Presentation (7 results) Remarks (2 results)

  • [Presentation] PGluとPLysを含むペプチド固定化シリカ粒子を用いた貴金属イオン選択捕集2017

    • Author(s)
      山田航平、伊田翔平、金岡鐘局、廣川能嗣、谷本智史
    • Organizer
      第66回高分子学会年次大会
    • Place of Presentation
      幕張メッセ(千葉県)
    • Year and Date
      2017-05-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリグルタミン酸やポリリジンを固定化したシリカ粒子を用いた貴金属イオンの選択的吸着2017

    • Author(s)
      山田航平、伊田翔平、金岡鐘局、廣川能嗣、谷本智史
    • Organizer
      第63回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館(兵庫県神戸市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] PGlu-b-PLys固定化シリカ粒子を用いたpH応答型選択的貴金属イオン捕集2016

    • Author(s)
      山田航平、伊田翔平、金岡鐘局、廣川能嗣、谷本智史
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] PGlu-b-PLys 固定化シリカ粒子を用いた貴金属イオン選択捕集2016

    • Author(s)
      山田航平、伊田翔平、廣川能嗣、谷本智史
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(兵庫県神戸市)
    • Year and Date
      2016-05-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] PGlu-b-PLys固定化シリカ粒子を用いた貴金属イオン選択捕集2016

    • Author(s)
      山田航平, 伊田翔平, 廣川能嗣, 谷本智史
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2016-05-25
    • Related Report
      2015 Research-status Report
  • [Presentation] ペプチド材料を用いた貴金属イオンの選択的回収2015

    • Author(s)
      谷本智史, 伊田翔平, 廣川能嗣
    • Organizer
      プラスチック成形加工学会第26回年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-06-03
    • Related Report
      2015 Research-status Report 2014 Research-status Report
  • [Presentation] ペプチド修飾シリカ粒子充填カラムを用いた混合溶液からの貴金属イオンの選択的捕集-速度論的解析-2014

    • Author(s)
      谷本智史
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report
  • [Remarks] 滋賀県立大学 高分子機能設計研究室

    • URL

      http://www.mat.usp.ac.jp/polymer-chemistry/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 滋賀県立大学 高分子機能設計研究室

    • URL

      http://www.mat.usp.ac.jp/polymer-chemistry/functional_particulates.html

    • Related Report
      2015 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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