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Development of PEDOT/sugar pendant polymer as heat absorbing films

Research Project

Project/Area Number 26410203
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Green/Environmental chemistry
Research InstitutionKumamoto Industrial Research Institute

Principal Investigator

Horikawa Maki  熊本県産業技術センター(ものづくり室、材料・地域資源室、食品加工室), その他部局等, 研究主任 (50588465)

Co-Investigator(Kenkyū-buntansha) 永岡 昭二  熊本県産業技術センター(ものづくり室、材料・地域資源室、食品加工室), その他部局等, 研究主幹 (10227994)
Co-Investigator(Renkei-kenkyūsha) IHARA Hirotaka  熊本大学, 大学院自然科学研究科, 教授 (10151648)
Research Collaborator SUNATA Kazunari  
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywords熱線吸収 / PEDOT / 糖ポリマー / 糖鎖ポリマー / 熱線吸収材 / 導電性高分子 / 硫酸化糖 / 透過性 / 断熱性 / セルロース / セロビオース / 導電性
Outline of Final Research Achievements

We prepared sulfated sugar pendant polymer with various molecular weight, which we used as poly(3,4-ethylenedioxythiophene) (PEDOT) dopants. PEDOT/ sulfated sugar pendant polymer films were prepared via in situ chemical oxidative polymerization of 3,4-ethylenedioxythiophene (EDOT) in an aqueous solution of sulfated sugar pendant polymer, followed by spin-coating. We investigated the heat ray absorption of the PEDOT/ sulfated sugar pendant polymer films as a function of their molecular weight. The PEDOT film fabricated using sulfated sugar pendant polymer (Mw = 28000) showed the highest heat-ray absorption.
The enhancement of heat ray absorption of PEDOT film was attributed to the decrease of molecular weight of sulfated sugar pendant polymer.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (12 results)

All 2016 2015 2014

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Cellulose/boron nitride core/shell microbeads providing high thermal conductivity for thermally conductive composite sheets2016

    • Author(s)
      Shoji Nagaoka, Takuma Jodai, Yoshihiro Kameyama, Maki Horikawa, Tomohiro Shirosaki, Naoya Ryu, Makoto Takafuji, Hideo Sakurai and Hirotaka Ihara
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 39 Pages: 33036-33042

    • DOI

      10.1039/c6ra02950g

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 硫酸化セルロースを用いた高導電性PEDOT薄膜の調製およびキャラクタリゼーション2016

    • Author(s)
      堀川真希、城崎智洋、永岡昭二
    • Journal Title

      セルロース学会誌

      Volume: 23 Pages: 16-18

    • Related Report
      2015 Research-status Report
  • [Journal Article] The development of a highly conductive PEDOT system by doping with partially crystalline sulfated cellulose and its electric conductivity2015

    • Author(s)
      M. Horikawa, T. Fujiki, T. Shirosaki, N. Ryu, H. Sakurai, S. Nagaoka, H. Ihara
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 3 Issue: 34 Pages: 8881-8887

    • DOI

      10.1039/c5tc02074c

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chemical Mechanical Polishing of Transparent Conductive Layers Using Spherical Cationic Polymer Microbeads2015

    • Author(s)
      Shoji Nagaoka, Naoya Ryu, Aikinori Yamanouchi, Tomohiro Shirosaki, Maki Horikawa, Hideo Sakurai, Makoto Takafuji, Hirotaka Ihara
    • Journal Title

      Thin Solid Films

      Volume: 576 Pages: 31-37

    • DOI

      10.1016/j.tsf.2014.12.028

    • NAID

      40021154281

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] 硫酸化セルロースナノファイバーを用いた高導電性PEDOT薄膜の開発2016

    • Author(s)
      堀川真希、城崎智洋、龍直哉、永岡昭二、伊原博隆
    • Organizer
      セルロース学会第23回年次大会
    • Place of Presentation
      つくばカピオ
    • Year and Date
      2016-07-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] High conductivation of PEDOT thin film using sulfated cellulose nanofiber as a dopant2016

    • Author(s)
      Maki Horikawa, Ryota Sumi, Tomohiro Shirosaki, Naoya Ryu, Shoji Nagaoka, Hirotaka Ihara
    • Organizer
      The Society of Polymer Science
    • Place of Presentation
      Fukuoka International Congress Center
    • Year and Date
      2016-07-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] Fabrication and characterization of PEDOT-PSS composite thin films2015

    • Author(s)
      Kazunari Sunata, Maki Horikawa, Tomohiro Shirosaki , Hideo Sakurai, Shoji Nagaoka, Hirotaka Ihara
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)
    • Place of Presentation
      米国ハワイ州、ホノルル、ハワイコンベンションセンター
    • Year and Date
      2015-12-15
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Preparation of PEDOT thin films using partially crystalline sulfated cellulose as dopant and their characterization2015

    • Author(s)
      Maki Horikawa, Kazunari Sunata, Tomohiro Shirosaki, Hideo Sakurai, Shoji Nagaoka, Hirotaka Ihara
    • Organizer
      The 11th International Conference on Advanced Polymers via Macromolecular Engineering (APME 2015)
    • Place of Presentation
      神奈川県横浜市、パシフィコ横浜
    • Year and Date
      2015-10-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Development of high transparent conductive polymer thin film: PEDOT thin film based on cellulose sulfate2014

    • Author(s)
      M. Horikawa, S. Nagaoka, T. Fujiki, T. Shirosaki, K. Yamamoto, H. Sakurai, M. Takafuji, H. Ihara
    • Organizer
      IPC2014~第10回高分子学会高分子国際会議~
    • Place of Presentation
      つくば国際会議場(茨城県)
    • Year and Date
      2014-12-02 – 2014-12-06
    • Related Report
      2014 Research-status Report
  • [Presentation] 多糖類を骨格とした高導電性PEDOT薄膜の開発2014

    • Author(s)
      堀川真希
    • Organizer
      セルロース学会西部支部セミナー2014
    • Place of Presentation
      熊本大学(熊本県)
    • Year and Date
      2014-11-28
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 硫酸化セルロースをドーパントに用いたPEDOT薄膜の高導電化2014

    • Author(s)
      砂田 一成,藤木 孝憲,堀川 真希,永岡 昭二,城崎 智洋,山本 勝政,高藤 誠,伊原 博隆
    • Organizer
      セルロース学会第21回年次大会
    • Place of Presentation
      鹿児島大学(鹿児島県)
    • Year and Date
      2014-07-17 – 2014-07-18
    • Related Report
      2014 Research-status Report
  • [Presentation] 硫酸化セルロースをドーパントに用いた高導電性PEDOT 薄膜の開発2014

    • Author(s)
      堀川真希、永岡昭二、藤木孝憲、城崎智洋、山本勝政、櫻井英夫、高藤誠、伊原博隆
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場(愛知県)
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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