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The study of moleculer stacks of metal phthalocyanines with metal cunductivity as cathod catalyst for practical fuel cells.

Research Project

Project/Area Number 26410207
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Energy-related chemistry
Research InstitutionKyushu Institute of Technology

Principal Investigator

Takase Satoko  九州工業大学, 大学院工学研究院, 助教 (60239275)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords酸素還元触媒 / 金属錯体 / 分離積層 / 金属錯体触媒 / 燃料電池 / カソード触媒 / 白金代替触媒
Outline of Final Research Achievements

Polymer electrolyte membrane fuel cells (PEMFCs) have been expected for widely using in vehicles and houses but high cost of Pt catalyst for the sluggish oxygen reduction reaction (ORR) keeps away practical use. The catalysts for PEMFC need an acid resistance and electrical conductivity.
In this study, planar metal complexes with acid resistance were treated as electrode catalysts. The control method for the molecular stacking state was developed and the relation between the stacking states and the catalytic activities was revealed. The catalyst have a short distance between metals and higher catalytic activity. Moreover, a separated stacking with planar molecules and acceptor ions with metal conductivity shows high catalytic activity.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (9 results)

All 2017 2016 2015

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results)

  • [Journal Article] Processing of α-Phase Metal–Phthalocyanine Powders by Interface Neutralization Method2016

    • Author(s)
      Satoko Takase, Yuki Aoto, and Youichi Shimizu*
    • Journal Title

      Chemistry Letters

      Volume: 45 Issue: 9 Pages: 1066-1068

    • DOI

      10.1246/cl.160486

    • NAID

      130006837291

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] 界面析出法により作製した金属フタロシアニン系触媒の酸素還元特性2017

    • Author(s)
      高瀬 聡子・安藤 寿美・清水 陽一
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] 界面析出法により作製した金属フタロシアニン触媒の酸素還元特性2016

    • Author(s)
      高瀬 聡子・安藤 寿美・ 清水 陽一
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ 国際会議場
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Oxygen Reduction Properties of Structure-Controlled Metal Phthalocyanine Electrocatalysts in Acidic Condition2016

    • Author(s)
      Satoko Takase, Daiki Ikeda, Kotomi Ando, Youichi Shimizu
    • Organizer
      67th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      The Hague, the Netherland
    • Year and Date
      2016-08-21
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 層状マンガン酸化物の電気化学的合成と酸素電極触媒特性2016

    • Author(s)
      濱田 勝秀・高瀬 聡子・清水 陽一
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] 金属フタロシアニン系触媒の電気化学的炭酸ガス還元特性2016

    • Author(s)
      坂本 遥一郎・高瀬 聡子・清水 陽一
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-29
    • Related Report
      2015 Research-status Report
  • [Presentation] 復合系金属フタロシアニン触媒のアルカリ溶液中での酸素還元特性2016

    • Author(s)
      藤田隆亮・高瀬聡子・清水陽一
    • Organizer
      第53回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2016 Annual Research Report
  • [Presentation] Influence of crystalographic structure of phthalocyanine in catalytic property toward oxygen reduction reaction2015

    • Author(s)
      S. Takase, Y. Aoto and Y. Shimizu
    • Organizer
      第7回国際燃料電池ワークショップ 2015
    • Place of Presentation
      甲府富士屋ホテル
    • Year and Date
      2015-08-27
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金属フタロシアニン触媒の構造制御と酸性溶液中での酸素還元特性2015

    • Author(s)
      高瀬 聡子,脇田 英明,清水 陽一
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2015-03-17
    • Related Report
      2014 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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