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Studies on photoinduced mass transport observed for azobenzene-based molecular materials and development of photo-driven micromachines

Research Project

Project/Area Number 26410211
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionMuroran Institute of Technology

Principal Investigator

NAKANO Hideyuki  室蘭工業大学, 工学研究科, 教授 (00222167)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsフォトメカニカル効果 / 光誘起物質移動 / アゾベンゼン / フォトクロミックアモルファス分子材料 / 相分離 / 寒天ゲル / 偏光
Outline of Final Research Achievements

In order to gain information about the mechanism of photoinduced mass transport, we investigated the photoinduced changes in phase-separated structures of the hybrid films of azobenzene-based amorphous molecular materials with poly(vinyl acetate) and inidazolium salts. We have found that the domain structures formed in the phase-separated films were changed upon irradiation with the polarized laser beam. In addition, we investigated photoinduced changes in the shape of particles of azobenzene-based amorphous molecular materials fixed in agar gel and found that the particles were elongated parallel to the polarization direction of the incident beams. Photoinduced structural changes of the films of azobenzene-based amorphous molecular materials prepared on the surface of the agar gel were also found. The present study provided valuable information regarding the mechanism of photoinduced mass transport and indicated potential for development of photo-driven micromachines.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (15 results)

All 2017 2016 2015 2014 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 1 results,  Open Access: 1 results) Presentation (10 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results) Remarks (1 results)

  • [Journal Article] Mechanochromic luminescence of 1-alkanoylaminopyrenes adsorbed onto cellulose papers2017

    • Author(s)
      E. Nagata, T. Ara, H. Nakano
    • Journal Title

      Dyes Pigm.

      Volume: 141 Pages: 48-52

    • DOI

      10.1016/j.dyepig.2017.02.003

    • NAID

      120006312482

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Modulation of Emission Intensities of Binary Films Composed of Fluorescent Amorphous Molecular Materials and p-Toluenesulfonic Acid in Response to Exhaled Breath2016

    • Author(s)
      H. Nakano, T. Nishimura, E. Nagata, and R. Ichikawa
    • Journal Title

      ChemistrySelect

      Volume: 1 Issue: 8 Pages: 1734-1740

    • DOI

      10.1002/slct.201600273

    • NAID

      120006329649

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photoinduced shape change of azobenzene-based molecular glass particles fixed in agar gel2016

    • Author(s)
      Ryota Ichikawa and Hideyuki Nakano
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 43 Pages: 36761-36765

    • DOI

      10.1039/c6ra05792f

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Phase Separation and Photo-induced Deformation of Domain Structures of Azobenzene-based Photochromic Amorphous Molecular Materials – Poly(vinyl acetate) Hybrid Films.2015

    • Author(s)
      R. Ichikawa and H. Nakano
    • Journal Title

      Lett. Appl. NanoBioSci.

      Volume: in press

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] アゾベンゼン系アモルファス分子材料を含む複合微粒子の寒天ゲル中における光変形2017

    • Author(s)
      市川亮太、中野英之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 寒天ゲル表面上に製膜したアゾベンゼン系アモルファス分子材料のフォトメカニカル挙動2017

    • Author(s)
      北野文萌、市川亮太、中野英之
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応大学(神奈川県横浜市)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] hotomechanical Behaviors Observed for Azobenzene-based Photochromic Amorphous Molecular Materials2016

    • Author(s)
      H. Nakano
    • Organizer
      The 12th IUPAC International Conference on Novel Materials and their Synthesis
    • Place of Presentation
      長沙(中国)
    • Year and Date
      2016-10-14
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アゾベンゼン系フォトクロミックアモルファス分子材料-イミダゾリウム塩ハイブリッド膜に形成される相分離構造の光変化2016

    • Author(s)
      岩下知央、中野英之
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都目黒区)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Photomechanical Effects Observed for Azobenzene-based Molecular Materials2015

    • Author(s)
      Hideyuki Nakano
    • Organizer
      The 5th East Asia Symposium on Functional Dyes and Advanced Materials
    • Place of Presentation
      Osaka Prefecture University, Sakai, Osaka, Japan
    • Year and Date
      2015-09-02
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 寒天ゲル中におけるアゾベンゼン系フォトクロミックアモルファス分子材料のフォトメカニカル挙動2015

    • Author(s)
      市川亮太、中野英之
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] アゾベンゼン系フォトクロミックアモルファス分子材料-ポリ酢酸ビニル複合膜の可逆的相分離とドメイン構造の光変形2015

    • Author(s)
      市川涼児、中野英之
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] アゾベンゼン系フォトクロミックアモルファス分子材料-ポリ酢酸ビニル複合膜の可逆的相分離とドメイン構造の光変形2014

    • Author(s)
      市川涼児、中野英之
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] さまざまな状況下におけるアゾベンゼン系フォトクロミックアモルファス分子材料の光変形2014

    • Author(s)
      中野英之、松井 陸、市川亮太、市川涼児
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Photoinduced Mass Transport Observed for Azobenzene-based Photochromic Amorphous Molecular Materials2014

    • Author(s)
      H. Nakano
    • Organizer
      EMN Open Access Week 2014
    • Place of Presentation
      Chengdu, China
    • Year and Date
      2014-09-22 – 2014-09-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Remarks] 中野研のホームページ

    • URL

      http://www3.muroran-it.ac.jp/nakano_lab/

    • Related Report
      2015 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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