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Development of transparent dye-sensitized solar cell using unused infrared light

Research Project

Project/Area Number 26410213
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionGifu University

Principal Investigator

FUNABIKI Kazumasa  岐阜大学, 工学部, 教授 (50273123)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords色素増感太陽電池 / 近赤外吸収色素 / 有機色素 / 赤外光 / 色素増感型太陽電池 / 近赤外光吸収色素 / 耐熱性色素 / 耐光性色素 / 太陽光発電材料・素子
Outline of Final Research Achievements

This study aimed at improving the conversion efficiency and durability of a transparent dye-sensitized solar cell (DSSC), which is a visible light transmission type that conventionally converts unused infrared light. Research leader developed and announced the world's first colorless and transparent DSSC with organic dyes and a colorless transparent organic redox couple, attracted attention. However, since DSSC has insufficient conversion efficiency and durability, in this study, introducing a fluorine-containing substituent at a specific position for improvement of not only its efficiency but also their heat and light resistance was examined. As results, we showed the possibility of practical application due to increasing its durability, although the conversion efficiency was reduced.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (18 results)

All 2016 2015 2014

All Journal Article (3 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 2 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (13 results) (of which Invited: 3 results) Book (2 results)

  • [Journal Article] Rational Molecular Design and Synthesis of Highly Thermo- and Photostable Near-Infrared-Absorbing Heptamethine Cyanine Dyes with the Use of Fluorine Atoms2016

    • Author(s)
      K. Funabiki,* K. Yagi, M. Ueta, M. Nakajima, M. Horiuchi, Y. Kubota, M. Mastui
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 35 Pages: 12282-12285

    • DOI

      10.1002/chem.201602955

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of the thermal stability of near-infrared-absorbing heptamethinecyanine dyes by anion-exchange from an iodide to fluorine-containing anions2015

    • Author(s)
      K. Funabiki, K. Yagi, M. Nomoto, Y. Kubota, M. Matsui
    • Journal Title

      J. Fluorine Chem.

      Volume: 174 Pages: 132-136

    • DOI

      10.1016/j.jfluchem.2015.02.008

    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Open Access / Int'l Joint Research
  • [Journal Article] Tetrazole thiolate/disulfide organic redox couples carrying long alkyl groups in dye-sensitized solar cells with Pt-free electrodes2014

    • Author(s)
      K. Funabiki,Y. Saito, M. Doi, K. Yamada, Y. Yoshikawa, K. Manseki, Y. Kubota, M. Matsui
    • Journal Title

      Tetrahedron Symposia-in-Print, “Nanotek for Organic Synthesis and Organic Synthesis for Nanotek”,

      Volume: 70 Issue: 36 Pages: 6312-6317

    • DOI

      10.1016/j.tet.2014.04.071

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] オクタフルオロヘプタメチンシアニン色素の合成とその耐熱性・耐光性評価2016

    • Author(s)
      五藤舜也、船曳一正、窪田裕大、犬塚俊康、松居正樹
    • Organizer
      第39回フッ素化学討論会
    • Place of Presentation
      佐賀
    • Year and Date
      2016-09-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] ポリフッ素置換された近赤外吸収有機色素の耐熱性・耐光性評価2016

    • Author(s)
      船曳一正、五藤舜也、松居正樹、窪田裕大
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス
    • Year and Date
      2016-03-26
    • Related Report
      2015 Research-status Report
  • [Presentation] ポリフッ素化された近赤外吸収有機色素の耐熱性・耐光性評価2016

    • Author(s)
      五藤舜也、船曳一正、窪田裕大、犬塚俊康、松居正樹
    • Organizer
      第6回フッ素化学若手の会
    • Place of Presentation
      神奈川
    • Related Report
      2016 Annual Research Report
  • [Presentation] フッ素で有機色素を強くする2016

    • Author(s)
      船曳一正
    • Organizer
      第10回フッ素化学セミナー
    • Place of Presentation
      佐賀
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] カルボキシ基を有するヘプタメチンシアニン色素の耐熱性・耐光性評価2016

    • Author(s)
      上田正人、船曳一正、窪田裕大、犬塚俊康、松居正樹
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋
    • Related Report
      2016 Annual Research Report
  • [Presentation] 耐熱性・耐光性近赤外吸収有機色素の合成2015

    • Author(s)
      八木一高、船曳一正、窪田裕大、松居正樹
    • Organizer
      第46回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      三重大学
    • Year and Date
      2015-11-07
    • Related Report
      2015 Research-status Report
  • [Presentation] 含フッ素置換基導入による近赤外吸収有機色素の耐熱性おび耐光性改良2015

    • Author(s)
      八木 一高 、船曳 一正 、窪田 裕大 、松居 正樹
    • Organizer
      第 38 回 フッ素化学討論会
    • Place of Presentation
      中央区立日本橋公会堂
    • Year and Date
      2015-09-17
    • Related Report
      2015 Research-status Report
  • [Presentation] 有機フッ素化合物:選択的合成と物性値の改良2015

    • Author(s)
      船曳 一正
    • Organizer
      第5回フッ素化学若手の会
    • Place of Presentation
      滋賀
    • Year and Date
      2015-08-17
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 含フッ素アニオンを有する近赤外吸収有機色素の耐熱性評価2015

    • Author(s)
      船曳一正・八木一高・窪田裕大・松居正樹
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      千葉
    • Year and Date
      2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 長鎖アルキル基を有するヨウ素フリー有機レドックス対と有機色素を用いた色素増感型太陽電池2014

    • Author(s)
      船曳 一正・山田健太郎・齊藤恭輝・萬関一広・窪田裕大・松居正樹・三浦偉俊
    • Organizer
      第45回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      愛知
    • Year and Date
      2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 白色透明太陽電池2014

    • Author(s)
      船曳一正
    • Organizer
      第23回 ポリマー材料フォーラム
    • Place of Presentation
      奈良
    • Year and Date
      2014-11-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] フッ素原子導入による近赤外色素の耐熱性改良2014

    • Author(s)
      八木一高・船曳一正・窪田裕大・松居正樹
    • Organizer
      第4回CSJ化学フェスタ2014
    • Place of Presentation
      東京
    • Year and Date
      2014-10-15
    • Related Report
      2014 Research-status Report
  • [Presentation] Effect of Fluorine Atoms on Thermostability of Near-infrared Absorbing Organic Dyes2014

    • Author(s)
      K. Funabiki, K. Yagi, Y. Kubota, and M. Matsui
    • Organizer
      International Conference on Fluorine Chemistry 2014 Tokyo
    • Place of Presentation
      東京
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report
  • [Book] 機能性色素の新規合成・実用化動向2016

    • Author(s)
      船曳一正
    • Publisher
      シーエムシー出版
    • Related Report
      2016 Annual Research Report
  • [Book] フッ素化学入門 2015 -フッ素化合物の合成法2015

    • Author(s)
      船曳一正
    • Total Pages
      367
    • Publisher
      三共出版
    • Related Report
      2014 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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