| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Outline of Final Research Achievements |
We studied the synthesis of semi-aromatic poleketones via Eaton reagent-mediated direct condensation between alicyclic dicarboxylic acids and electron-rich aromatic compounds. We disclosed the relationship between the structures of both monomers and the properties of the resulting polyketones. In particular, a.w-bis(2-anisyl)-substituted aromatic compounds, which were prepared via Suzuki-Miyaura cross coupling reactions of 2-anisyl boronic acid and aromatic dihalides, were suitable to obtain high-performance semi-aromatic polyketones with high organosolubility, high thermal stability, and transparency.
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