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Deformation mechanism of semicrystalline polymers under high strains probed by in situ spectroscopic techniques

Research Project

Project/Area Number 26410221
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionKanazawa University

Principal Investigator

Hiejima Yusuke  金沢大学, 自然システム学系, 助教 (10415789)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords高分子材料物性 / ポリオレフィン / 延伸 / 結晶化 / 配向 / ラマン分光 / その場分光 / 変形 / コンホメーション / ラマン分光法 / 結晶性高分子 / 蛍光分光 / 一軸延伸
Outline of Final Research Achievements

In situ Raman apparatus was developed to observe the microscopic deformation and melting/crystallization behavior of semi-crystalline polymers such as polyethylene and polypropylene. During the uniaxial stretching of these semi-crystalline polymeric solids, it was found that the molecular chains orient toward a direction tilt from the stretching axis in the yielding region, and that compression stress was applied perpendicular to the polymer chains. These peculiar deformation suggests that the rotational motions of the lamellar cluster units which is formed by the collapse of the spherulites are the origin of the orientation after the yielding.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (25 results)

All 2017 2016 2015 2014

All Journal Article (7 results) (of which Peer Reviewed: 6 results,  Acknowledgement Compliant: 7 results,  Open Access: 3 results) Presentation (16 results) (of which Int'l Joint Research: 3 results,  Invited: 2 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Rheo-Raman Study of Isotactic Polypropylene under Tensile Deformation2017

    • Author(s)
      Takumitsu Kida, Yusuke Hiejima and Koh-hei Nitta
    • Journal Title

      Macromolecular Symposia

      Volume: 印刷中

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Molecular orientation behavior of isotactic polypropylene under uniaxial stretching by rheo-Raman spectroscopy2016

    • Author(s)
      Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta
    • Journal Title

      Express Polymer Letters

      Volume: 10 Issue: 8 Pages: 701-709

    • DOI

      10.3144/expresspolymlett.2016.63

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Raman spectroscopic study of high-density polyethylene during tensile deformation2016

    • Author(s)
      Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta
    • Journal Title

      Int. J. Exp. Spectrosc. Tech.

      Volume: 1 Pages: 1-6

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Molecular orientation behavior of isotactic polypropylene under uniaxial stretching by rheo-Raman spectroscopy2015

    • Author(s)
      Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta,
    • Journal Title

      Express. Polym. Lett.

      Volume: in press

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Rheo-optical Raman study of microscopic deformation in high-density polyethylene under hot drawing2015

    • Author(s)
      Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta,
    • Journal Title

      Polym. Test.

      Volume: 44 Pages: 30-36

    • DOI

      10.1016/j.polymertesting.2015.03.018

    • NAID

      120005613967

    • Related Report
      2015 Research-status Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Deformation mechanism of high-density polyethylene probed by in situ Raman spectroscopy2015

    • Author(s)
      Takumitsu Kida, Tatsuya Oku, Yusuke Hiejima, Koh-hei Nitta
    • Journal Title

      Polymer

      Volume: 58 Pages: 88-95

    • DOI

      10.1016/j.polymer.2014.12.030

    • NAID

      120005537886

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ラマン分光から見た高密度ポリエチレンの構造変化2014

    • Author(s)
      比江嶋祐介, 木田拓充, 新田晃平
    • Journal Title

      次世代ポリオレフィン総合研究

      Volume: 8 Pages: 77-80

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] Orientation distribution functions of polyethylene and polypropylene during tensile stretching determined by rheo-Raman spectroscopy2016

    • Author(s)
      Yusuke Hiejima, Takumitsu Kida and Koh-hei Nitta
    • Organizer
      International Conference on Polyolefin Characterization
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2016-11-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Rheo-Raman study of uniaxial deformation of polyethylene solids2016

    • Author(s)
      Yusuke Hiejima, Takumitsu Kida and Koh-hei Nitta
    • Organizer
      International Congress on Rheology
    • Place of Presentation
      Kyoto Terrsa, Kyoto, Japan
    • Year and Date
      2016-08-08
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Rheo-Raman study of deformation in polyethylene and isotactic polypropylene2015

    • Author(s)
      Yusuke Hiejima, Takumitsu Kida, and Koh-hei Nitta,
    • Organizer
      World Polyolefin Congress (WPOC2015)
    • Place of Presentation
      Tokyo Metropolitan University
    • Year and Date
      2015-11-23
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 分光学的手法を用いた 高分子物性評価2015

    • Author(s)
      比江嶋祐介
    • Organizer
      第13回高分子物性研究会
    • Place of Presentation
      石川県能美市
    • Year and Date
      2015-08-07
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] In-situラマン分光法を用いたイソタクチックポリプロピレンの延伸過程における分子配向挙動の解析2015

    • Author(s)
      木田拓充、比江嶋祐介、新田晃平
    • Organizer
      第26回プラスチック成形加工学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2015-06-03 – 2015-06-04
    • Related Report
      2014 Research-status Report
  • [Presentation] ラマン分光法によるイソタクチックポリプロピレンの結晶化挙動に関する研究2015

    • Author(s)
      竹田健人、比江嶋祐介、新田晃平
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      北大(札幌市)
    • Year and Date
      2015-05-27 – 2015-05-29
    • Related Report
      2014 Research-status Report
  • [Presentation] In-situラマン分光測定による分岐状態が異なるポリエチレンの延伸過程における変形機構の解明2015

    • Author(s)
      木田拓充、比江嶋祐介、新田晃平
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      北大(札幌市)
    • Year and Date
      2015-05-27 – 2015-05-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 蛍光プローブを添加したポリエチレンの破損状態と蛍光スペクトルの関係2015

    • Author(s)
      地引徹、比江嶋祐介、新田晃平
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      北大(札幌市)
    • Year and Date
      2015-05-27 – 2015-05-29
    • Related Report
      2014 Research-status Report
  • [Presentation] In-Situ Raman Spectroscopic Study of Deformation Mechanism of Polyethylene under Hot Drawing2015

    • Author(s)
      Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta
    • Organizer
      The 10th International Workshop for East Asian Young Rheologists (IWEAYR-10)
    • Place of Presentation
      九州大学筑紫野キャンパス
    • Year and Date
      2015-02-04 – 2015-02-07
    • Related Report
      2014 Research-status Report
  • [Presentation] 蛍光プローブを利用した一軸延伸下における結晶性高分子の構造変化の研究2014

    • Author(s)
      地引徹、比江嶋祐介、新田晃平
    • Organizer
      第37回溶液化学シンポジウム
    • Place of Presentation
      アバンセ(佐賀市)
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] その場ラマン分光法を用いたポリエチレンの延伸過程における変形機構の解明2014

    • Author(s)
      木田拓充、比江嶋祐介、新田晃平
    • Organizer
      第62回レオロジー討論会
    • Place of Presentation
      福井市交流プラザ
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Research-status Report
  • [Presentation] その場ラマン分光測定によるイソタクチックポリプロピレンのα分散領域における変形挙動に関する研究2014

    • Author(s)
      竹田健人、木田拓充、比江嶋祐介、新田晃平
    • Organizer
      第62回レオロジー討論会
    • Place of Presentation
      福井市交流プラザ
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Research-status Report
  • [Presentation] In-situラマン分光測定によるポリエチレンの延伸過程における変形メカニズムの解明2014

    • Author(s)
      木田拓充、比江嶋祐介、新田晃平
    • Organizer
      第12回高分子物性研究発表会
    • Place of Presentation
      石川県青少年研修センター
    • Year and Date
      2014-09-16 – 2014-09-17
    • Related Report
      2014 Research-status Report
  • [Presentation] ラマン分光から見たポリオレフィンの構造変化2014

    • Author(s)
      比江嶋祐介、木田拓充、新田晃平
    • Organizer
      第9回次世代ポリオレフィン総合研究会
    • Place of Presentation
      首都大学東京秋葉原サテライトキャンパス
    • Year and Date
      2014-08-07 – 2014-08-08
    • Related Report
      2014 Research-status Report
  • [Presentation] ラマン分光法を用いた分岐状態が異なるポリエチレンの延伸過程における微視的構造変化のその場観察2014

    • Author(s)
      木田拓充、比江嶋祐介、新田晃平
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report
  • [Presentation] In-situラマン分光測定による高密度ポリエチレンの冷延伸挙動の解析2014

    • Author(s)
      木田拓充、比江嶋祐介、新田晃平
    • Organizer
      第41回レオロジー年次大会
    • Place of Presentation
      東京大学生産技術研究所コンベンションホール
    • Year and Date
      2014-05-15 – 2014-05-16
    • Related Report
      2014 Research-status Report
  • [Book] Advances in Materials Science Reseach Volume 202015

    • Author(s)
      Maryann C. Wythers (Eds.), Yusuke Hiejima, Takumitsu Kida, Koh-hei Nitta et al.
    • Total Pages
      270
    • Publisher
      Nova Science Publishers
    • Related Report
      2015 Research-status Report
  • [Patent(Industrial Property Rights)] 結晶性高分子の劣化測定方法2016

    • Inventor(s)
      新田晃平, 比江嶋祐介, 五十嵐敏郎, 木田拓充, 竹田健人
    • Industrial Property Rights Holder
      新田晃平, 比江嶋祐介, 五十嵐敏郎, 木田拓充, 竹田健人
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-248326
    • Filing Date
      2016-12-21
    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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