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Fabrication of lithium ion conductive polymer nanofibers based on organic nanoionics

Research Project

Project/Area Number 26410225
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo Metropolitan University

Principal Investigator

Tanaka Manabu  首都大学東京, 都市環境科学研究科, 助教 (00531831)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsナノファイバー / エレクトロスピニング / 高分子電解質 / イオン伝導 / リチウムイオン / 電池 / リチウムイオン伝導 / 二次電池
Outline of Final Research Achievements

Based on our proposed phenomenon, "organic nanoionics", lithium ion conductive polymer nanofibers were fabricated, and their ion conductive characteristics were revealed. We demonstrated that the nanofibers showed higher lithium ion conductivity than the corresponding membranes at low temperature, and revealed that such high ion conductivity were derived from unique characteristics of the nanofibers. The nanofiber composite membranes were also prepared to apply for polymer electrolyte membranes for future secondary batteries.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (28 results)

All 2017 2016 2015 2014 Other

All Journal Article (12 results) (of which Peer Reviewed: 10 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (12 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Remarks (1 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] Anion conductive polymer nanofiber composite membrane: Effects of nanofibers on polymer electrolyte characteristics2017

    • Author(s)
      Tsukasa Watanabe, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Polymer International

      Volume: 66 Issue: 3 Pages: 382-387

    • DOI

      10.1002/pi.5270

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Acid-doped polymer nanofiber framework: Three-dimensional proton conductive network for high-performance fuel cellsAcid-doped polymer nanofiber framework: Three-dimensional proton conductive network for high-performance fuel cells2017

    • Author(s)
      Manabu Tanaka, Yasushi Takeda, Takeru Wakiya, Yuta Wakamoto, Kaori Harigaya, Tatsunori Ito, Takashi Tarao, Hiroyoshi Kawakami
    • Journal Title

      Journal of Power Sources

      Volume: 342 Pages: 125-134

    • DOI

      10.1016/j.jpowsour.2016.12.018

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Improvement in characteristics of a Nafion membrane by proton conductive nanofibers for fuel cell applications2017

    • Author(s)
      Takahito Makinouchi, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Journal of Membrane Science

      Volume: 530 Pages: 65-72

    • DOI

      10.1016/j.memsci.2017.02.018

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Polymer Electrolyte Characteristics of Sulfonated Block-graft Polyimide Membranes: Influence of Block Ratio2016

    • Author(s)
      Gang Wang, Kota Yamazaki, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 29 Issue: 2 Pages: 259-263

    • DOI

      10.2494/photopolymer.29.259

    • NAID

      130005256580

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fabrication and electrolyte characterization of uniaxially-aligned anion conductive polymer nanofibers2016

    • Author(s)
      Tsukasa Watanabe, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 47 Pages: 19614-19619

    • DOI

      10.1039/c6nr07828a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Development of ion conductive nanofibers for polymer electrolyte fuel cells2016

    • Author(s)
      Manabu Tanaka
    • Journal Title

      Polymer Journal

      Volume: 48 Issue: 1 Pages: 51-58

    • DOI

      10.1038/pj.2015.76

    • NAID

      40020685231

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Preparation and characterization of sulfonated block-graft copolyimide/sulfonated polybenzimidazole blend membranes for fuel cell application2015

    • Author(s)
      Kota Yamazaki, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Polymer International

      Volume: 64 Issue: 9 Pages: 1079-1085

    • DOI

      10.1002/pi.4936

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of Phosphoric Acid-doped Blend Membrane Composed of Sulfonated Poly(arylene ether sulfone) and Polybenzimidazole for Fuel Cell Application2015

    • Author(s)
      Dong Liu, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 28 Issue: 2 Pages: 181-186

    • DOI

      10.2494/photopolymer.28.181

    • NAID

      130005093843

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] <i>The Intrinsic Mechanical and Material Transport Properties of Electrospun Polymer Nanofibers</i>2015

    • Author(s)
      田中 学
    • Journal Title

      Sen'i Gakkaishi

      Volume: 71 Issue: 10 Pages: P-491-P-494

    • DOI

      10.2115/fiber.71.P-491

    • NAID

      130005102600

    • ISSN
      0037-9875, 1884-2259
    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Core/shell-like structured ultrafine branched nanofibers created by electrospinning2014

    • Author(s)
      Makoto Konno, Yuuko Kishi, Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Polymer Journal

      Volume: 46 Issue: 11 Pages: 792-799

    • DOI

      10.1038/pj.2014.74

    • NAID

      40020248133

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ultra-High Proton Conduction in Electrospun Sulfonated Polyimide Nanofibers2014

    • Author(s)
      Ryouhei Takemori,Genki Ito, Manabu Tanaka, and Hiroyoshi Kawakami
    • Journal Title

      RSC Advances

      Volume: 未定 Issue: 38 Pages: 20005-20009

    • DOI

      10.1039/c4ra02155j

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Design and Synthesis of Ion Conductive Polymer Nanofibers for Fuel Cell Applications2014

    • Author(s)
      Manabu Tanaka, Hiroyoshi Kawakami
    • Journal Title

      Kobunshi

      Volume: 63 Pages: 710-710

    • Related Report
      2014 Research-status Report
  • [Presentation] 固体高分子電解質ナノファイバーフレームワークの作製と次世代型二次電池応用2016

    • Author(s)
      島根 拓志, 稲船 勇太, 渡辺 司, 田中 学, 川上 浩良
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ(千葉県千葉市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] リチウムイオン伝導性ナノファイバーフレームワーク電解質を用いた全固体型二次電池の作製とその特性評価2016

    • Author(s)
      渡辺 司, 田中 学, 川上 浩良
    • Organizer
      第57回電池討論会
    • Place of Presentation
      幕張メッセ(千葉県千葉市)
    • Year and Date
      2016-11-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] 連続的なプロトン伝導パスを有するナノファイバーフレームワークの構築と燃料電池応用2016

    • Author(s)
      田中 学, 脇屋 健, 牧之内 貴仁, 小椋 隆廣, 川上 浩良
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      神奈川大学(神奈川県横浜市)
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Ion Condutive Polymer Nanofibers: Fabrication, Characterization, and Fuel Cell Applications2016

    • Author(s)
      Manabu Tanaka
    • Organizer
      International Symposium on Polymer Chemistry 2016
    • Place of Presentation
      中国科学院長春応用化学研究所(Changchun, China)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Proton Conductive Nanofiber Frameworks for Polymer Electrolyte Fuel Cells2016

    • Author(s)
      Takahito Makinouchi, Manabu Tanaka, Hiroyoshi Kawakami
    • Organizer
      The 10th Conference of Aseanian Membrane Society
    • Place of Presentation
      奈良春日野国際フォーラム甍(奈良県奈良市)
    • Year and Date
      2016-07-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] リチウムシングルイオン伝導性高分子のナノファイバー化と電解質特性評価2015

    • Author(s)
      原 一哲, 田中 学, 川上 浩良
    • Organizer
      第53回高分子と水に関する討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2015-12-11
    • Related Report
      2015 Research-status Report
  • [Presentation] リチウムイオン伝導性と二次電池特性に与えるリチウムイオン伝導性ナノファイバー形態の影響2015

    • Author(s)
      渡辺 司, 田中 学, 望月 康正, 松本 太, 川上 浩良
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学 川内キャンパス
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] グラフト型ポリイミドのナノファイバー化とその力学特性評価2015

    • Author(s)
      田中 学, 佐藤 共喜, 川上 浩良
    • Organizer
      平成27年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2015-06-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 高リチウムイオン伝導性高分子ナノファイバーの電解質評価と二次電池応用2015

    • Author(s)
      渡辺 司, 田中 学, 望月 康正, 松本 太, 川上 浩良
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Presentation] PEO 側鎖を有するグラフトポリマーのナノファイバー化とリチウムイオン伝導性評価2015

    • Author(s)
      渡辺 司, 田中 学, 川上 浩良
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2015-05-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 全固体型リチウムイオン電池の電解質応用を目指したイオン伝導性高分子ナノファイバーの作製2014

    • Author(s)
      渡辺 司, 田中 学, 望月 康正, 松本 太, 川上 浩良
    • Organizer
      第55回電池討論会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2014-11-19 – 2014-11-21
    • Related Report
      2014 Research-status Report
  • [Presentation] ポリイミドナノファイバー1 本の力学特性評価2014

    • Author(s)
      田中 学, 佐藤 共喜, 川上 浩良
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Remarks] 首都大学東京 大学院都市環境科学研究科 分子応用化学域 助教 田中 学のホームページ

    • URL

      http://www.comp.tmu.ac.jp/m-tanaka/

    • Related Report
      2016 Annual Research Report 2015 Research-status Report 2014 Research-status Report
  • [Patent(Industrial Property Rights)] 複合ナノファイバーおよび該ナノファイバーを含む電解質膜2016

    • Inventor(s)
      川上浩良, 田中学, 坂口梨紗
    • Industrial Property Rights Holder
      川上浩良, 田中学, 坂口梨紗
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-110367
    • Filing Date
      2016-06-01
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 電池材料の製造方法、電解質膜の製造方法及び電池材料2016

    • Inventor(s)
      川上浩良, 田中学, 渡辺司
    • Industrial Property Rights Holder
      川上浩良, 田中学, 渡辺司
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-162456
    • Filing Date
      2016-08-23
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 表面修飾ナノファイバー、電解質膜、電解質膜の製造方法、膜電極接合体及び固体高分子形燃料電池2016

    • Inventor(s)
      川上浩良, 田中学, 牧之内貴仁
    • Industrial Property Rights Holder
      川上浩良, 田中学, 牧之内貴仁
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-162455
    • Filing Date
      2016-08-23
    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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