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Pseudo-high-pressure electrochemical reactions in a single-walled carbon nanotube

Research Project

Project/Area Number 26410238
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionNagoya Institute of Technology

Principal Investigator

Kawasaki Shinji  名古屋工業大学, 工学(系)研究科(研究院), 教授 (40241294)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsカーボンナノチューブ / 二次電池 / キャパシタ / 透明導電膜 / 電気化学反応 / 電気化学 / 高圧力
Outline of Final Research Achievements

A variety of foreign molecules have been inserted into single-walled carbon nanotubes (SWCNTs). The SWCNT encapsulation systems have attracted much attention mainly due to their unique structures. However, the properties of the SWCNT encapsulation systems as functional materials have not been fully investigated. In the present study, iodine, sulphur, phosphorus, and 9,10-phenanthrene quinone (PhQ) molecules were inserted into SWCNTs. It was elucidated by the present study that the SWCNT encapsulation systems have high potentials as next generation battery electrode materials. It was found that PhQ@SWCNT can work as Na ion battery electrode. The undesired capacity fading, which comes from the dissolution of quinone molecules into the electrolyte, was suppressed by the encapsulation. In the case of I@SWCNT, it was found that the electric conductivity of SWCNTs is improved very much by the encapsulation of iodine molecules. New transparent conductive film can be prepared with I@SWCNT.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (25 results)

All 2017 2016 2015 2014 Other

All Journal Article (6 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 4 results,  Open Access: 2 results) Presentation (15 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] カーボンナノチューブの内部空間を活用した高性能蓄電デバイスの開発2017

    • Author(s)
      石井陽祐, 川崎晋司
    • Journal Title

      ケミカルエンジニヤリング

      Volume: 62 Pages: 6-12

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Low-Temperature Phase Transformation Accompanied With Charge-Transfer Reaction of Polyiodide Ions Encapsulated in Single-Walled Carbon Nanotubes2016

    • Author(s)
      Y. Yoshida, Y. Ishii, N. Kato, C. Li, S. Kawasaki
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 36 Pages: 20454-20461

    • DOI

      10.1021/acs.jpcc.6b07819

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical lithium-ion storage properties of quinone molecules encapsulated in single-walled carbon nanotubes2016

    • Author(s)
      Yosuke Ishii, Kosuke Tashiro, Kento Hosoe, Ayar Al-zubaidi, and Shinji Kawasaki
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 15 Pages: 10411-10418

    • DOI

      10.1039/c6cp01103a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Alkali metal ion storage properties of sulphur and phosphorous molecules encapsulated in nanometer size carbon cylindrical pores2016

    • Author(s)
      Yosuke Ishii, Yuki Sakamoto, Hayong Song, Kosuke Tashiro, Yoshiki Nishiwaki, Ayar Al-zubaidi and Shinji Kawasaki
    • Journal Title

      AIP Adv.

      Volume: 6 Issue: 3 Pages: 035112-035112

    • DOI

      10.1063/1.4944580

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] New type of pseudo-capacitor using redox reaction of electrolyte in single-walled carbon nanotubes2016

    • Author(s)
      Yoshimitsu Taniguchi, Yosuke Ishii, Ayar Al-zubaidi, and Shinji Kawasaki
    • Journal Title

      J. Nanosci. Nanotechnol

      Volume: in press

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ヨウ素を内包した単層カーボンナノチューブの透明導電膜2015

    • Author(s)
      川崎晋司、Song Hayong、谷口慶充、石井陽祐
    • Journal Title

      化学工業

      Volume: 3 Pages: 54-59

    • Related Report
      2014 Research-status Report
  • [Presentation] ナノカーボン電極を利用した電解液レドックスキャパシタ2016

    • Author(s)
      Utkarsh Prakash, 谷口慶充, 吉田征弘, 石井陽祐, 川崎晋司
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋
    • Year and Date
      2016-11-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] アルカリ金属イオンと単層カーボンナノチューブに内包されたヨウ素との電気化学反応2016

    • Author(s)
      加藤尚, 吉田征弘, 阪本悠紀, 石井陽祐, 川崎晋司
    • Organizer
      第47回中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      豊橋
    • Year and Date
      2016-11-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] 機能性分子内包カーボンナノチューブの物性2016

    • Author(s)
      川崎晋司
    • Organizer
      第119回黒鉛化合物研究会
    • Place of Presentation
      京都
    • Year and Date
      2016-10-28
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Alkali metal ion storage properties of single-walled carbon nanotube encapsulation systems2016

    • Author(s)
      Y. Sakamoto, C. Li, Y. Ishii, S. Kawasaki
    • Organizer
      PRiME2016
    • Place of Presentation
      ハワイ
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
  • [Presentation] Structural and electrode properties of iodine molecules encapsulated in single-walled carbon nanotubes2016

    • Author(s)
      Y. Yoshida, N. Kato, Y. Ishii, S. Kawasaki
    • Organizer
      PRiME2016
    • Place of Presentation
      ハワイ
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
  • [Presentation] 単層カーボンナノチューブ内包系の電池電極への応用2016

    • Author(s)
      川崎晋司, 石井陽祐
    • Organizer
      第65回高分子討論会
    • Place of Presentation
      横浜
    • Year and Date
      2016-09-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Functional molecules encapasulated in single-walled carbon nanotubes for post Li ion batteries2016

    • Author(s)
      S. Kawasaki
    • Organizer
      ISAMR2016
    • Place of Presentation
      台湾
    • Year and Date
      2016-08-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Encapsulations of functional molecules in single-walled carbon nanotubes for energy storage devices2016

    • Author(s)
      S. Kawasaki, Y. Takeuchi, Y. Taniguchi, K. Hosoe, Y. Ishii
    • Organizer
      ICAC2016
    • Place of Presentation
      大津
    • Year and Date
      2016-05-23
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organic and elemental molecules encapsulated in single-walled carbon nanotubes as Na and Li ion battery electrodes2015

    • Author(s)
      S. KAWASAKI, Y. Sakamoto, K. Tashiro, Y. Ishii
    • Organizer
      Pacifichem
    • Place of Presentation
      ハワイ
    • Year and Date
      2015-12-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] カーボンナノチューブに内包させた機能性分子の二次電池電極性能2015

    • Author(s)
      川崎 晋司、宋 河容、田代 広祐、阪本 悠紀
    • Organizer
      第41回炭素材料学会年会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-12-08 – 2015-12-10
    • Related Report
      2014 Research-status Report
  • [Presentation] 機能性分子内包カーボンナノチューブの合成と電池電極特性評価2015

    • Author(s)
      川崎晋司、阪本悠紀、石井陽祐
    • Organizer
      2015年東海地区ヤングエレクトロケミスト研究会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2015-09-25
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 単層カーボンナノチューブの細孔内におけるカチオンとアニオンの吸着挙動の差異2015

    • Author(s)
      石井陽祐,竹内裕,谷口慶充, 吉田征弘, 川崎晋司
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Presentation] カーボンナノチューブへの電気化学ヨウ素導入とキャパシタへの応用2015

    • Author(s)
      谷口慶充,川崎晋司,石井陽祐,山田真之,吉田征弘
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学
    • Year and Date
      2015-09-11
    • Related Report
      2015 Research-status Report
  • [Presentation] Na and Li ion storage properties of Phosphorus molecules inserted in SWCNT hollow cores2015

    • Author(s)
      Shinji Kawasaki, Hayong Song, Yuki Sakamoto, Yosuke Ishii
    • Organizer
      Carbon2015
    • Place of Presentation
      ドイツ・ドレスデン
    • Year and Date
      2015-07-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 機能性分子の単層カーボンナノチューブへの内包及びその電気化学特性2014

    • Author(s)
      田代広祐、細江健斗、川崎晋司
    • Organizer
      第45回中連秋季大会
    • Place of Presentation
      中部大
    • Year and Date
      2014-11-29 – 2014-11-30
    • Related Report
      2014 Research-status Report
  • [Book] カーボンナノチューブ・グラフェンの応用研究最前線2016

    • Author(s)
      川崎晋司
    • Total Pages
      480
    • Publisher
      エヌティーエス
    • Related Report
      2016 Annual Research Report
  • [Remarks]

    • URL

      http://kawasaki.web.nitech.ac.jp/jp/

    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] アルカリハライド内包カーボンナノチューブ、全固体電池2017

    • Inventor(s)
      石井陽祐、川崎晋司
    • Industrial Property Rights Holder
      石井陽祐、川崎晋司
    • Industrial Property Rights Type
      特許
    • Filing Date
      2017-03-30
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 多価イオン電池電極2015

    • Inventor(s)
      石井陽祐, 川崎晋司
    • Industrial Property Rights Holder
      石井陽祐, 川崎晋司
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-088389
    • Filing Date
      2015-04-23
    • Related Report
      2015 Research-status Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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