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Study of Hybrid film of lithium battery cathode and piezo substrate

Research Project

Project/Area Number 26410239
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionNagoya Institute of Technology

Principal Investigator

Sonoyama Noriyuki  名古屋工業大学, 工学(系)研究科(研究院), 准教授 (50272696)

Co-Investigator(Kenkyū-buntansha) 今西 誠之  三重大学, 工学研究科, 教授 (20223331)
Co-Investigator(Renkei-kenkyūsha) HIRAYAMA Masaaki  東京工業大学, 大学院理工学研究科, 准教授 (30531165)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2016: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2015: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2014: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Keywordsリチウム電池 / ピエゾ基板 / エピタキシャル膜 / 活性化エネルギー / エピタキシャル薄膜 / 圧電体 / リチウムイオン電池
Outline of Final Research Achievements

We have studied aiming to clarify the correlation between lattice size change and activation energy of charge transfer process by hybridizing expandable piezoelectric element by voltage application with lithium battery material epitaxial thin film.
111 - oriented LiMn2O4 epitaxial thin film was fabricated on LiNbO3(LNO) substrate and mica substrates and piezoelectric properties by sol-gel method. The electrochemical characteristics of the obtained thin film were evaluated, and it was confirmed that charge - discharge performance was confirmed with the film on LNO substrate. The activation energy of the charge transfer resistance decreased by applying voltage to the piezoelectric substrate. These results suggeststhat the activation energy is lowered due to the distortion generated in the film with the expansion of the substrate.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (6 results)

All 2017 2016 2014 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (1 results) (of which Int'l Joint Research: 1 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Preparation of Nano-size Crystalline LiCoO2 Thin Film on the Carbon Substrate with the Three Dimensional Surface by the Electro-Deposition Method2016

    • Author(s)
      N. Sonoyama, H. Tanimura, T. Mizuno, Z. Quan
    • Journal Title

      Solid State Ionics

      Volume: 285 Pages: 106-111

    • DOI

      10.1016/j.ssi.2015.09.026

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nano Size Multiple Metal Oxide Anode Electrodes Synthesized from Layered Double Hydroxides – Electrochemical Reaction Mechanism and Surface Morphology Change during Reaction with Lithium Ion2014

    • Author(s)
      Z. Quan, E. Ni, Y. Ogasawara, N. Sonoyama
    • Journal Title

      Solid State Ionics

      Volume: 268B

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Properties of Nano Size Binary Metal Oxides as Anode Electrode Materials Synthesized from Layered Double Hydroxides2014

    • Author(s)
      Z. Quan, E. Ni, Y. Ogasawara, N. Sonoyama
    • Journal Title

      Solid State Ionics

      Volume: 62

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Synthesis of LiCoO2 Thin Film on the Solid Electrolyte By Electro-Deposition Method -for the Fabrication of All-Solid Lithium Ion Battery2016

    • Author(s)
      N. Sonoyama, Y. Yoshida, T. Mizuno
    • Organizer
      Prime 2016
    • Place of Presentation
      ホノルル
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Book] 技術情報協会2017

    • Author(s)
      園山範之
    • Total Pages
      10
    • Publisher
      「全固体電池のイオン伝導性向上技術と材料、製造プロセスの開発」
    • Related Report
      2016 Annual Research Report
  • [Remarks] 園山研究室ー化学の力でエネルギーをー

    • URL

      http://www.ach.nitech.ac.jp/~inorg/sonoyama/Site/Home.html

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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