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Synergistic photo-functions of integrated materials composed of enzymes and inorganic layered semiconductors

Research Project

Project/Area Number 26410244
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Inorganic industrial materials
Research InstitutionNagasaki University

Principal Investigator

KAMADA Kai  長崎大学, 工学研究科, 准教授 (90315284)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords無機ーバイオ複合材料 / ナノシート / 半導体 / 光触媒 / 酸化還元酵素 / 酵素 / タンパク質 / 発光反応 / 酸化物半導体 / 光電気化学 / 酸化還元酵素反応 / 層状半導体 / 金属酸化物
Outline of Final Research Achievements

We investigated synergistic functions of hybrid materials consisting of inorganic layered semiconductors and biomolecules. It was revealed that redox enzymes as biomolecules are intercalated into interlayer space of layered semiconductors with a narrow band gap, then enzymatic activity can be manipulated by visible light irradiation to the hybrids. On the other hand, binding of photoproteins to semiconductors achieved excitation of the semiconductor with bioluminescence, implying that photoproteins can be employed as an internal light source for semiconductor photocatalytic reaction systems without any external one.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (31 results)

All 2017 2016 2015 2014

All Journal Article (11 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 10 results,  Open Access: 1 results) Presentation (19 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Preface2017

    • Author(s)
      K. Kamada, K. Takeyama, E. Yoshida, N. Soh
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 125 Issue: 4 Pages: P4-1-P4-4

    • DOI

      10.2109/jcersj2.125.P4-1

    • NAID

      130005530283

    • ISSN
      1348-6535, 1882-0743
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synergistic functions of enzymes bound to semiconducting layers2016

    • Author(s)
      K. Kamada, A. Yamada, M. Kamiuchi, M. Tokunaga, D. Ito, N.Soh
    • Journal Title

      Methods in Enzymology

      Volume: 571 Pages: 113-134

    • DOI

      10.1016/bs.mie.2016.03.002

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synergistic Functions of Enzymes Bound to Semiconducting Layers2016

    • Author(s)
      Kai Kamada, Akane Yamada, Misato Kamiuchi, Motoko Tokunaga, Daiki Ito, Nobuaki Soh
    • Journal Title

      Methods in Enzymology

      Volume: 571

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Multicolour Photochromism of Colloidal Solutions of Niobate Nanosheets Intercalated with Several Kinds of Metal Ions2016

    • Author(s)
      Kai Kamada, Yosuke Tanaka, Motoko Tokunaga, Taro Ueda, Takeo Hyodo, Yasuhiro Shimizu
    • Journal Title

      Chemical Communications

      Volume: 52 Issue: 16 Pages: 3308-3311

    • DOI

      10.1039/c5cc09270a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Visible-light-induced activity control of peroxidase bound to Fe-doped titanate nanosheets with nanometric lateral dimensions2015

    • Author(s)
      Kai Kamada, Daiki Ito, Nobuaki Soh
    • Journal Title

      Bioconjugate Chem.

      Volume: 26 Issue: 10 Pages: 2161-2166

    • DOI

      10.1021/acs.bioconjchem.5b00464

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhanced Catalytic Activity of Enzymes Interacting with Nanometric Titanate Nanosheets2015

    • Author(s)
      Kai Kamada, Akane Yamada, Nobuaki Soh
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 104 Pages: 85511-85516

    • DOI

      10.1039/c5ra14848k

    • NAID

      120006986846

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] セリアおよびセリウム含有ナノ粒子の酵素模倣活性2015

    • Author(s)
      鎌田海
    • Journal Title

      化学工業

      Volume: 66(9) Pages: 23-26

    • Related Report
      2015 Research-status Report
  • [Journal Article] セリアナノ材料の電気化学合成2015

    • Author(s)
      鎌田海
    • Journal Title

      希土類

      Volume: 67 Pages: 1-5

    • NAID

      40020650886

    • Related Report
      2015 Research-status Report
    • Acknowledgement Compliant
  • [Journal Article] Enhanced visible-light-induced photocatalytic activity of alpha-Fe2O3 adsorbing redox enzymes2015

    • Author(s)
      Kai Kamada, Nobuaki Soh
    • Journal Title

      J. Asian Ceram. Soc.

      Volume: 3 Issue: 1 Pages: 18-21

    • DOI

      10.1016/j.jascer.2014.10.004

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Enzyme-mimetic activity of Ce-intercalated titanate nanosheets2015

    • Author(s)
      Kai Kamada, Nobuaki Soh
    • Journal Title

      The Journal of Physical Chemistry B

      Volume: 119 Issue: 16 Pages: 5309-5314

    • DOI

      10.1021/jp512038x

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Intense emissions from photoproteins interacting with titanate nanosheets2014

    • Author(s)
      Kai Kamada
    • Journal Title

      RSC Advances

      Volume: 4 Issue: 81 Pages: 43052-43056

    • DOI

      10.1039/c4ra05665e

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Photoelectrochemical reaction of oxide semiconductors Induced by bioluminescence2017

    • Author(s)
      K. Kamada, K. Takeyama
    • Organizer
      The 18th International Symposium on Eco-materials Processing and Design
    • Place of Presentation
      沖縄自治会館(那覇市)
    • Year and Date
      2017-02-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Enzyme-mimetic activity of inorganic nanosheets including cerium ions2016

    • Author(s)
      K. Kamada
    • Organizer
      Rare Earths 2016
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2016-06-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] バイオルミネセンスを励起源とする光電気化学セル2016

    • Author(s)
      鎌田 海、上田太郎、兵頭健生、清水康博
    • Organizer
      日本セラミックス協会平成28年度九州支部秋季合同研究発表会
    • Place of Presentation
      長崎大学(長崎市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Photochemical Activity Control of Redox Enzyme Bound to Semiconducting Layers2015

    • Author(s)
      Kai Kamada, Taro Ueda, Takeo Hyodo, Yasuhiro Shimizu, Nobuaki Soh
    • Organizer
      The 14th International Union of Materials Research Societies-International Conference on Advanced Materials (IUMRS-ICAM2015)
    • Place of Presentation
      Jeju Convention Center, Jeju, Korea
    • Year and Date
      2015-10-26
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Novel Coating Methods Retarding Biofilm Formation on Medical Devices2015

    • Author(s)
      Eri Yoshida, Kai Kamada
    • Organizer
      第1回理工系女性研究者国際シンポジウム&若手研究者との交流セミナー
    • Place of Presentation
      西の雅常盤(山口市)
    • Year and Date
      2015-07-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 酸化物ナノシートとの結合による酸化還元酵素の活性向上2015

    • Author(s)
      山田あかね、鎌田海、上田太郎、兵頭健生、清水康博
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2015-06-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 酸化物ナノシートへの抗がん剤分子の挿入と放出特性2015

    • Author(s)
      神内美知、鎌田海、上田太郎、兵頭健生、清水康博
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2015-06-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 酸化物ナノシートコロイド溶液のフォトクロミズム2015

    • Author(s)
      田中洋介、鎌田海、上田太郎、兵頭健生、清水康博
    • Organizer
      第52回化学関連支部合同九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2015-06-27
    • Related Report
      2015 Research-status Report
  • [Presentation] 希土類酸化物ナノ材料の合成手法の開拓と生化学的応用2015

    • Author(s)
      鎌田海
    • Organizer
      第32回希土類討論会
    • Place of Presentation
      かごしま県民交流センター(鹿児島市)
    • Year and Date
      2015-05-23
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 蛍光性チタン酸ナノシートを用いた特定細胞認識2015

    • Author(s)
      徳永素子、鎌田海、宗伸明
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山市、岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 層状鉄チタン酸と結合したペルオキシダーゼの可視光誘起酵素反応2015

    • Author(s)
      伊藤大樹、鎌田海、宗伸明
    • Organizer
      日本セラミックス協会2015年年会
    • Place of Presentation
      岡山市、岡山大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 層状酸化物ナノ粒子の分散安定性に及ぼす温度の影響2015

    • Author(s)
      鎌田海、上田太郎、兵頭健生、清水康博
    • Organizer
      第53回セラミックス基礎科学討論会
    • Place of Presentation
      京都市、京都テルサ
    • Year and Date
      2015-01-08 – 2015-01-09
    • Related Report
      2014 Research-status Report
  • [Presentation] セリウムをドープした層状酸化物ナノ粒子の酵素模倣活性2015

    • Author(s)
      小林寿範、鎌田海、上田太郎、清水康博
    • Organizer
      第53回セラミックス基礎科学討論会
    • Place of Presentation
      京都市、京都テルサ
    • Year and Date
      2015-01-08 – 2015-01-09
    • Related Report
      2014 Research-status Report
  • [Presentation] Enzyme-mimetic activity of Ce-doped titanate nanosheets2014

    • Author(s)
      Kai Kamada, Hisanori Kobayashi, Taro Ueda, Takeo Hyodo, Yasuhiro Shimizu
    • Organizer
      The 31st Korea-Japan Seminar on Ceramics
    • Place of Presentation
      Changwon, Korea
    • Year and Date
      2014-11-26 – 2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Visible-light-induced enzymatic reaction of peroxidase hybridized with layered iron-titanate2014

    • Author(s)
      Daiki Ito, Kai Kamada, Taro Ueda, Takeo Hyodo, Yasuhiro Shimizu
    • Organizer
      The 31st Korea-Japan Seminar on Ceramics
    • Place of Presentation
      Changwon, Korea
    • Year and Date
      2014-11-26 – 2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] Targeting of specific cell using fluorescent titanate nanosheets2014

    • Author(s)
      Motoko Tokunaga, Kai Kamada, Taro Ueda, Takeo Hyodo, Yasuhiro Shimizu
    • Organizer
      The 31st Korea-Japan Seminar on Ceramics
    • Place of Presentation
      Changwon, Korea
    • Year and Date
      2014-11-26 – 2014-11-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 生体分子とセラミックスの融合による協奏機能2014

    • Author(s)
      鎌田海
    • Organizer
      トークシャワー・イン・九州2014
    • Place of Presentation
      宮崎市、ホテル浜荘
    • Year and Date
      2014-09-01 – 2014-09-02
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] A novel functional nanohybrid consisting of semiconducting layers and biomolecules2014

    • Author(s)
      Kai Kamada
    • Organizer
      The Annual Meeting of the Korean Clay Science Society
    • Place of Presentation
      Wonju, Korea
    • Year and Date
      2014-07-04 – 2014-07-05
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] セリウムをドープした層状酸化物ナノ粒子の活性酸素消去能2014

    • Author(s)
      小林寿範、鎌田海
    • Organizer
      第31回希土類討論会
    • Place of Presentation
      東京都江戸川区、タワーホール船掘
    • Year and Date
      2014-05-22 – 2014-05-23
    • Related Report
      2014 Research-status Report
  • [Patent(Industrial Property Rights)] 無機アニオン伝導体2015

    • Inventor(s)
      鎌田海、渡辺伸、柳裕之
    • Industrial Property Rights Holder
      鎌田海、渡辺伸、柳裕之
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-10-01
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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